Silicon Anode Systems for Lithium-Ion Batteries is an introduction to silicon anodes as an alternative to traditional graphite-based anodes. The book provides a comprehensive overview including abundance, system voltage, and capacity. It provides key insights into the basic challenges faced by the materials system such as new configurations and concepts for overcoming the expansion and contraction related problems. This book has been written for the practitioner, researcher or developer of commercial technologies. - Provides a thorough explanation of the advantages, challenge, materials science, and commercial prospects of silicon and related anode materials for lithium-ion batteries - Provides insights into practical issues including processing and performance of advanced Si-based materials in battery-relevant materials systems - Discusses suppressants in electrolytes to minimize adverse effects of solid electrolyte interphase (SEI) formation and safety limitations associated with this technology

Intro -- Silicon Anode Systems for Lithium-Ion Batteries -- Copyright -- Contents -- Contributors -- Preface -- Part I: Introduction and background -- Part II: Mechanical properties -- Part III: Electrolytes and surface electrolyte interphase issues -- Part IV: Achieving high(er) performance: Modeling and experimental perspectives -- Part V: Future directions: Novel devices and space applications -- Part I: Introduction and background -- Chapter 1: Silicon anode systems for lithium-ion batteries -- 1.1. Introduction -- 1.2. The SiLi alloy: A material perspective -- 1.3. The SiLi alloy: An electrode perspective -- 1.3.1.1. Volume expansion and material pulverization: The importance of size and nano-structuring -- 1.3.1.2. Pulverization and delamination: The importance of polymer composites and binders -- 1.3.1.3. The silicon/electrolyte interphase -- 1.4. Conclusions: Summary and perspective -- References -- Chapter 2: Recent advances in silicon materials for Li-ion batteries: Novel processing, alternative raw materials, and pr ... -- 2.1. Introduction -- 2.2. Hybrid and alloy-based silicon-containing materials -- 2.2.1. Carbon-silicon hybrid materials -- 2.2.2. Processing hybrid anodes: Fundamental vs. practical considerations -- 2.2.3. Silicon-metal alloy anodes -- 2.2.4. Oxide-containing anodes -- 2.3. Alternative raw materials and novel processing methods -- 2.3.1. Recycling of silicon-containing industrial sources -- 2.3.2. Silicon sourced from biomass and clays -- 2.3.3. Magnesiothermic and metallic melt processing -- 2.3.4. Nano-silicon derived from diatomite and inspired by nature -- 2.3.5. Other novel processing methods -- 2.4. Conclusions -- References -- Part II: Mechanical properties -- Chapter 3: Computational study on the effects of mechanical constraint on the performance of silicon nanosheets as anode ... -- 3.1. Introduction.

Batteries play a critical role in modern society and will only increase in importance as electric vehicles and grid-scale storage applications continue to grow. Silicon is a material of great interest as an anode for future battery applications, as it offers the possibility of greatly increased battery capacities and reduced weights. This work investigates two methods in which silicon may find use in batteries. First, silicon was shown to be a viable anode in primary battery systems using carbon monofluoride as a high-energy cathode for extremely high-temperature environments such as deep mineshafts. The temperatures achieved in these studies were some of the highest ever observed for a functioning lithium battery. In addition, the fundamental surface chemistry of silicon as a rechargeable anode for safer lithium-ion batteries was also investigated. Organosilicon-based electrolytes offer much higher flash points than the current generation of electrolytes, but the surface chemistry of their solid-electrolyte interphase formation on the silicon anode surface remains relatively unexplored until now. Finally, this work also presents a method for creation and subsequent functionalization of graphitic nanopillars. These nanopillars may serve as a route to well-ordered graphene nanoplatelets of monodisperse size and controllable chemistry.

Offers the first comprehensive account of this interesting and growing research field Printed Batteries: Materials, Technologies and Applications reviews the current state of the art for printed batteries, discussing the different types and materials, and describing the printing techniques. It addresses the main applications that are being developed for printed batteries as well as the major advantages and remaining challenges that exist in this rapidly evolving area of research. It is the first book on printed batteries that seeks to promote a deeper understanding of this increasingly relevant research and application area. It is written in a way so as to interest and motivate readers to tackle the many challenges that lie ahead so that the entire research community can provide the world with a bright, innovative future in the area of printed batteries. Topics covered in Printed Batteries include, Printed Batteries: Definition, Types and Advantages; Printing Techniques for Batteries, Including 3D Printing; Inks Formulation and Properties for Printing Techniques; Rheological Properties for Electrode Slurry; Solid Polymer Electrolytes for Printed Batteries; Printed Battery Design; and Printed Battery Applications. Covers everything readers need to know about the materials and techniques required for printed batteries Informs on the applications for printed batteries and what the benefits are Discusses the challenges that lie ahead as innovators continue with their research Printed Batteries: Materials, Technologies and Applications is a unique and informative book that will appeal to academic researchers, industrial scientists, and engineers working in the areas of sensors, actuators, energy storage, and printed electronics.

Lithium-Ion Batteries features an in-depth description of different lithium-ion applications, including important features such as safety and reliability. This title acquaints readers with the numerous and often consumer-oriented applications of this widespread battery type. Lithium-Ion Batteries also explores the concepts of nanostructured materials, as well as the importance of battery management systems. This handbook is an invaluable resource for electrochemical engineers and battery and fuel cell experts everywhere, from research institutions and universities to a worldwide array of professional industries. - Contains all applications of consumer and industrial lithium-ion batteries, including reviews, in a single volume - Features contributions from the world's leading industry and research experts - Presents executive summaries of specific case studies - Covers information on basic research and application approaches

The handbook focuses on a complete outline of lithium-ion batteries. Just before starting with an exposition of the fundamentals of this system, the book gives a short explanation of the newest cell generation. The most important elements are described as negative / positive electrode materials, electrolytes, seals and separators. The battery disconnect unit and the battery management system are important parts of modern lithium-ion batteries. An economical, faultless and efficient battery production is a must today and is represented with one chapter in the handbook. Cross-cutting issues like electrical, chemical, functional safety are further topics. Last but not least standards and transportation themes are the final chapters of the handbook. The different topics of the handbook provide a good knowledge base not only for those working daily on electrochemical energy storage, but also to scientists, engineers and students concerned in modern battery systems.

Gaining public attention due, in part, to their potential application as energy storage devices in cars, Lithium-ion batteries have encountered widespread demand, however, the understanding of lithium-ion technology has often lagged behind production. This book defines the most commonly encountered challenges from the perspective of a high-end lithium-ion manufacturer with two decades of experience with lithium-ion batteries and over six decades of experience with batteries of other chemistries. Authors with years of experience in the applied science and engineering of lithium-ion batteries gather to share their view on where lithium-ion technology stands now, what are the main challenges, and their possible solutions. The book contains real-life examples of how a subtle change in cell components can have a considerable effect on cell’s performance. Examples are supported with approachable basic science commentaries. Providing a unique combination of practical know-how with an in-depth perspective, this book will appeal to graduate students, young faculty members, or others interested in the current research and development trends in lithium-ion technology.

The increasing demand and expanding applications of lithium-ion batteries (LIBs) impose bigger requirements in terms of battery metrics. As a result, there has been a huge effort to develop the next-generation energy storage systems that possess high energy density, high cyclability, low cost, and increased safety. This work combines the benefits of silicon (Si) anode with very high theoretical capacity and ionic liquids (IL) with unique physicochemical properties, to achieve high energy density and safe LIBs. Electrochemical studies were carried out to investigate the performance of Si in highly concentrated IL electrolytes, which has hardly been investigated in the past. In conjunction with electrochemical cycling, interfacial studies were also carried out to investigate the solid electrolyte interphase (SEI) and near-electrode structures. The cycling data revealed that the nature and structure of the IL and the electrolyte salt content greatly influence the electrochemical behaviour of the Si anode, favoring the use of phosphonium-based IL and highly concentrated electrolytes. Ex situ surface characterization provided evidence of a more efficient SEI for the said systems. The investigation of near-electrode structuring of the IL components also gave insight into their decomposition pathway, pointing to the higher susceptibility of dilute systems and pyrrolidinium-based electrolytes to degradation. The performance of Si in the IL electrolytes was also successfully demonstrated in full-cell configuration, showing their feasibility for practical use. Finally, solid-state electrolytes were prepared to create allsolid and safe batteries, but further research is necessary to achieve successful cycling.

This book combines two areas of intense interest: nanotechnology, and energy conversion and storage devices. In particular, Li-ion batteries have enjoyed conspicuous success in many consumer electronic devices and their projected use in vehicles that will revolutionize the way we travel in the near future. For many applications, Li-ion batteries are the battery of choice. This book consolidates the scattered developments in all areas of research related to nanotechnology and lithium ion batteries.