Electrochemical Studies in Cyclic Esters
Author | : William Sidney Harris |
Publisher | : |
Total Pages | : 82 |
Release | : 1958 |
ISBN-10 | : UOM:39015077593773 |
ISBN-13 | : |
Rating | : 4/5 (73 Downloads) |
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Author | : William Sidney Harris |
Publisher | : |
Total Pages | : 82 |
Release | : 1958 |
ISBN-10 | : UOM:39015077593773 |
ISBN-13 | : |
Rating | : 4/5 (73 Downloads) |
Author | : |
Publisher | : |
Total Pages | : |
Release | : 1958 |
ISBN-10 | : OCLC:953400839 |
ISBN-13 | : |
Rating | : 4/5 (39 Downloads) |
Solubilities and conductivities of inorganic salts in the cyclic esters ethylene carbonate, propylene carbonate, gamma -butyrolactone, and gamma - valerolactone have been studied. A number of common inorganic salts were found to be highly soluble in all of these solvents. The variation of solubility with the physical properties of the solvents is discussed. Conductivity measurements have shown that a number of salts investigated behaved as strong electrolytes. Certain solutions of highly soluble inorganic salts were found to have high viscosities in these solvents. Such relatively low-melting covalent halides as AlCl/sub 3/, NbCl/sub 5/, and FeCl/sub 3/ were found to be quite soluble. The solubilities and conductivities characterizing these solutions conform to present- day concepts, and are explained in the light of modern solubility theory. Solutions of a variety of salts were electroreduced, providing further data for the characterization of these solvents. This study indicates that, in addition to those metals which may be obtained from aqueous solutions, some of the highly electropositive metals may also be electrodeposited. These solvents arc characterized by high dielectric constants, low vapor pressures, relatively low toxicity, and high chemical stability, and are relatively nonreactive with anodically liberated halogens. Such properties are desirable in an easily handled ionizing mediuun. (auth).
Author | : Warren Brian Jenkins |
Publisher | : |
Total Pages | : |
Release | : 1976 |
ISBN-10 | : OCLC:779039873 |
ISBN-13 | : |
Rating | : 4/5 (73 Downloads) |
Author | : Asfaw Negash |
Publisher | : LAP Lambert Academic Publishing |
Total Pages | : 60 |
Release | : 2012-06 |
ISBN-10 | : 3659155098 |
ISBN-13 | : 9783659155093 |
Rating | : 4/5 (98 Downloads) |
Electrochemistry provides very interesting and versatile means for the study of chemical reactions. Recently, the terms molecular electrochemistry have been used for that part of electrochemistry that studies the mechanistic events at or near an electrode on a molecular level. The main goal of the electrochemical studies is the elucidation of the sequence of electron transfer and chemical reactions that occur near the electrode surface and their applications to electrosynthesis of organic compounds. Among many electrochemical techniques presented for the study of chemical reactions, cyclic voltammetry has become a very popular technique for initial electrochemical studies of new systems, and has proven as very useful tool in obtaining information about fairly complicated electrode reactions. Cyclic voltammograms are frequently and routinely used today to define the redox properties of newly synthesized organic compounds, based the viewpoint of green chemistry. There fore this book is very important for the synthesis of electroorganic compounds with EC mechanism.
Author | : J. Grimshaw |
Publisher | : Elsevier |
Total Pages | : 415 |
Release | : 2000-12-01 |
ISBN-10 | : 9780080530727 |
ISBN-13 | : 0080530729 |
Rating | : 4/5 (27 Downloads) |
Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more "green" chemical synthesis. Over recent years, modern investigations have clarified the mechanisms of important organic electrochemical reactions. Progress has also been made in controlling the reactivity of intermediates through either radical or ionic pathways. Now is the time to gather all the electrochemical work into a textbook.As an essential addition to the armory of synthetic organic chemists, electrochemical reactions give results not easily achieved by many other chemical routes. This book presents a logical development of reactions and mechanisms in organic electrochemistry at a level suited to research scientists and final year graduate students. It forms an excellent starting point from which synthetic organic chemists, in both academia and industry, can appreciate uses for electrochemical methods in their own work. The book is also a reference guide to the literature.
Author | : |
Publisher | : Elsevier |
Total Pages | : 5674 |
Release | : 2024-09-16 |
ISBN-10 | : 9780323958226 |
ISBN-13 | : 0323958222 |
Rating | : 4/5 (26 Downloads) |
The Encyclopedia of Electrochemical Power Sources, Second Edition, is a comprehensive seven-volume set that serves as a vital interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With an increased focus on the environmental and economic impacts of electrochemical power sources, this work not only consolidates extensive coverage of the field but also serves as a gateway to the latest literature for professionals and students alike. The field of electrochemical power sources has experienced significant growth and development since the first edition was published in 2009. This is reflected in the exponential growth of the battery market, the improvement of many conventional systems, and the introduction of new systems and technologies. This completely revised second edition captures these advancements, providing updates on all scientific, technical, and economic developments over the past decade. Thematically arranged, this edition delves into crucial areas such as batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. It explores challenges and advancements in electrode and electrolyte materials, structural design, optimization, application of novel materials, and performance analysis. This comprehensive resource, with its focus on the future of electrochemical power sources, is an essential tool for navigating this rapidly evolving field. - Covers the main types of power sources, including their operating principles, systems, materials, and applications - Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers - Incorporates 365 articles, with timely coverage of environmental and sustainability aspects - Arranged thematically to facilitate easy navigation of topics and easy exploration of the field across its key branches - Follows a consistent structure and features elements such as key objective boxes, summaries, figures, references, and cross-references etc., to help students, faculty, and professionals alike
Author | : |
Publisher | : |
Total Pages | : 744 |
Release | : 1981 |
ISBN-10 | : UIUC:30112104412405 |
ISBN-13 | : |
Rating | : 4/5 (05 Downloads) |
Author | : M. Noel |
Publisher | : |
Total Pages | : 734 |
Release | : 1990 |
ISBN-10 | : STANFORD:36105030954676 |
ISBN-13 | : |
Rating | : 4/5 (76 Downloads) |
This text adopts an unique classification of electrochemical processes and introduces the subject in a stepwise fashion, from simple solution electrochemistry to photo-electrochemistry. The reader can thus obtain a comprehensive view of the recent trends in electrochemistry without serious difficulty.
Author | : Rajasekhar Balasubramanian |
Publisher | : Royal Society of Chemistry |
Total Pages | : 394 |
Release | : 2021-03-29 |
ISBN-10 | : 9781839163449 |
ISBN-13 | : 1839163445 |
Rating | : 4/5 (49 Downloads) |
With escalating global population, increased consumption of fossil fuels, spiralling energy demand, rapid environmental degradation and global climate change, energy and environmental issues are receiving considerable attention worldwide from the purview of sustainable development. In order to address these complex and interlinked challenges, the development of new materials for affordable green energy technologies (batteries, supercapacitors, fuel cells and solar cells) and environmental remediation methods (adsorption, photocatalysis, separation, and sensing) is essential. Three-dimensional graphene-based macrostructures (3D GBMs) are of great interest in these applications given their large surface area and adaptable surface chemistry. Graphene-based 3D Macrostructures for Clean Energy and Environmental Applications provides a critical and comprehensive account of the recent advances in the development and potential applications of high performance 3D GBMs for tackling global energy and environmental issues in a sustainable manner. Particular attention is paid to the fabrication schemes, modulation of physiochemical properties, and their integration into practical devices, and the roles of surface chemistry and pore morphology, as well as their interplay, on the overall performance of 3D GBMs are examined. With contributions from authors around the world this book is a useful resource for both environmental scientists interested in sustainable energy and remediation solutions and materials scientists interested in applications for 3D GMBs.
Author | : Lawrence Radiation Laboratory. Inorganic Materials Research Division |
Publisher | : |
Total Pages | : 180 |
Release | : 1964 |
ISBN-10 | : UOM:39015077325598 |
ISBN-13 | : |
Rating | : 4/5 (98 Downloads) |