This is the first dedicated book to cover the basics of a wide range of stable isotope applications in a manner appropriate for someone entering the field. At the same time, it offers sufficient detail - and numerous references and examples - to direct research for further inquiry. Discusses diverse topics such as hydrology, carbon in plants, meteorites, carbonates, metamorphic rocks, etc. Explores the theory and principles of isotope fractionation. Offers unique, up-to-date discussion of meteorite (extraterrestrial) isotope data. Presents the subject in an interesting historical context, with the classic papers noted. A useful reference for students taking the course and professionals entering the field of Geochemistry.

Stable Isotope Geochemistry is an introduction to the use of stable isotopes in the fields of geoscience. It is subdivided into three parts: - theoretical and experimental principles; - fractionation mechanisms of light elements; - the natural variations of geologically important reservoirs. In this updated 4th edition many of the chapters have been expanded, especially those on techniques and environmental aspects. The main focus is on recent results and new developments. For students and scientists alike the book will be a primary reference with regard to how and where stable isotopes can be used to solve geological problems.

This book presents a quantitative treatment of the theory and natural variations of light stable isotopes. It discusses isotope distribution in the context of fractionation processes, thermodynamics, mass conservation, exchange kinetics, and diffusion theory, and includes more than 100 original equations. The theoretical principles are illustrated with natural examples that emphasize oxygen and hydrogen isotope variations in natural waters, terrestrial and extraterrestrial rocks, and hydrothermal systems. New data on meteoric precipitation, rivers, springs, formation fluids, and hydrothermal systems are included in relation to various natural phenomena. Essentially, this book seeks to reconnect the diverse phenomenological observations of isotope distribution to the quantitative theories of physical chemistry and the language of differential equations. It may serve as a textbook for advanced students, as a research reference, or as a quick source of information. The book is organized into five chapters, each followed by suggested quantitative problems and a short reference list. The three theoretical chapters progress from an elementary review of the physical chemistry of stable isotopes, to the thermodynamics of isotopic compounds, and finally to the calculation of isotope distribution in dynamic systems. The third and fifth chapters emphasize oxygen and hydrogen isotope variations in Earth's hydrosphere and lithosphere, constituting the most important examples of the theoretical principles. Appendices provide data on atomic weights of light elements, physical constants, mathematical relationships, and isotopic fractionation factors.

This book provides a comprehensive introduction to radiogenic and stable isotope geochemistry. Beginning with a brief overview of nuclear physics and nuclear origins, it then reviews radioactive decay schemes and their use in geochronology. A following chapter covers the closely related techniques such as fission-track and carbon-14 dating. Subsequent chapters cover nucleosynthetic anomalies in meteorites and early solar system chronology and the use of radiogenic isotopes in understanding the evolution of the Earth’s mantle, crust, and oceans. Attention then turns to stable isotopes and after reviewing the basic principles involved, the book explores their use in topics as diverse as mantle evolution, archeology and paleontology, ore formation, and, particularly, paleoclimatology. A following chapter explores recent developments including unconventional stable isotopes, mass-independent fractionation, and isotopic ‘clumping’. The final chapter reviews the isotopic variation in the noble gases, which result from both radioactive decay and chemical fractionations.

Volume 43 of Reviews in Mineralogy and Geochemistry follows the 1986 Reviews in Mineralogy (Vol. 16) in approach but reflects significant changes in the field of Stable Isotope Geochemistry. In terms of new technology, new sub-disciplines, and numbers of researchers, the field has changed more in the past decade than in any other since that of its birth. Unlike the 1986 volume, which was restricted to high temperature fields, this book covers a wider range of disciplines. However, it would not be possible to fit a comprehensive review into a single volume. Our goal is to provide state-of-the-art reviews in chosen subjects that have emerged or advanced greatly since 1986. This volume was prepared for Short Course on Stable Isotope Geochemistry presented November 2-4, 2001 in conjunction with the annual meetings of the Geological Society of America in Boston, Massachusetts.

This book is intended to serve as a text for an introductory course in geochemistry for undergraduate/graduate students with at least an elementary–level background in earth sciences, chemistry, and mathematics. The text, containing 83 tables and 181 figures, covers a wide variety of topics — ranging from atomic structure to chemical and isotopic equilibria to modern biogeochemical cycles — which are divided into four interrelated parts: Crystal Chemistry; Chemical Reactions (and biochemical reactions involving bacteria); Isotope Geochemistry (radiogenic and stable isotopes); and The Earth Supersystem, which includes discussions pertinent to the evolution of the solid Earth, the atmosphere, and the hydrosphere. In keeping with the modern trend in the field of geochemistry, the book emphasizes computational techniques by developing appropriate mathematical relations, solving a variety of problems to illustrate application of the mathematical relations, and leaving a set of questions at the end of each chapter to be solved by students. However, so as not to interrupt the flow of the text, involved chemical concepts and mathematical derivations are separated in the form of boxes. Supplementary materials are packaged into ten appendixes that include a standard–state (298.15 K, 1 bar) thermodynamic data table and a listing of answers to selected chapter–end questions. Additional resources for this book can be found at: www.wiley.com/go/misra/geochemistry.

This book has a very strong practical orientation, telling readers what methodologies are available using stable isotopes, how studies should be designed and executed to maximise effectiveness and incisiveness in terms of data obtained and outcomes in terms of understanding events and processes in plant and ecosystem functioning. The readership is very much aimed toward postgraduates with good knowledge of general biological principles and underlying chemical and physical processes. Pre-existing knowledge of or experience in application and assay of stable isotopes is not required. The stable isotope research field is one of the most rapidly growing areas of ecophysiology and techniques using stable isotopes comprise an ever increasing component of research programs of university postgraduates and a wide range of agencies conducting environmental monitoring and rehabilitation programs. The book is tailor-made for such an audience.

This book represents a new "earth systems" approach to catchments that encompasses the physical and biogeochemical interactions that control the hydrology and biogeochemistry of the system. The text provides a comprehensive treatment of the fundamentals of catchment hydrology, principles of isotope geochemistry, and the isotope variability in the hydrologic cycle -- but the main focus of the book is on case studies in isotope hydrology and isotope geochemistry that explore the applications of isotope techniques for investigating modern environmental problems. Isotope Tracers in Catchment Hydrology is the first synthesis of physical hydrology and isotope geochemistry with catchment focus, and is a valuable reference for professionals and students alike in the fields of hydrology, hydrochemistry, and environmental science. This important interdisciplinary text provides extensive guidelines for the application of isotope techniques for all investigatores facing the challenge of protecting precious water, soil, and ecological resources from the ever-increasing problems associated with population growth and environmental change, including those from urban development and agricultural land uses.

The development of multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) makes it possible to precisely measure non-traditional stable isotopes. This volume reviews the current status of non-traditional isotope geochemistry from analytical, theoretical, and experimental approaches to analysis of natural samples. In particular, important applications to cosmochemistry, high-temperature geochemistry, low-temperature geochemistry, and geobiology are discussed. This volume provides the most comprehensive review on non-traditional isotope geochemistry for students and researchers who are interested in both the theory and applications of non-traditional stable isotope geochemistry.