This book presents a quantitative treatment of the theory and natural variations of light stable isotopes. It discusses isotope distribution in the context of fractionation processes, thermodynamics, mass conservation, exchange kinetics, and diffusion theory, and includes more than 100 original equations. The theoretical principles are illustrated with natural examples that emphasize oxygen and hydrogen isotope variations in natural waters, terrestrial and extraterrestrial rocks, and hydrothermal systems. New data on meteoric precipitation, rivers, springs, formation fluids, and hydrothermal systems are included in relation to various natural phenomena. Essentially, this book seeks to reconnect the diverse phenomenological observations of isotope distribution to the quantitative theories of physical chemistry and the language of differential equations. It may serve as a textbook for advanced students, as a research reference, or as a quick source of information. The book is organized into five chapters, each followed by suggested quantitative problems and a short reference list. The three theoretical chapters progress from an elementary review of the physical chemistry of stable isotopes, to the thermodynamics of isotopic compounds, and finally to the calculation of isotope distribution in dynamic systems. The third and fifth chapters emphasize oxygen and hydrogen isotope variations in Earth's hydrosphere and lithosphere, constituting the most important examples of the theoretical principles. Appendices provide data on atomic weights of light elements, physical constants, mathematical relationships, and isotopic fractionation factors.

This is the first dedicated book to cover the basics of a wide range of stable isotope applications in a manner appropriate for someone entering the field. At the same time, it offers sufficient detail - and numerous references and examples - to direct research for further inquiry. Discusses diverse topics such as hydrology, carbon in plants, meteorites, carbonates, metamorphic rocks, etc. Explores the theory and principles of isotope fractionation. Offers unique, up-to-date discussion of meteorite (extraterrestrial) isotope data. Presents the subject in an interesting historical context, with the classic papers noted. A useful reference for students taking the course and professionals entering the field of Geochemistry.

This book presents a quantitative treatment of the theory and natural variations of light stable isotopes. It discusses isotope distribution in the context of fractionation processes, thermodynamics, mass conservation, exchange kinetics, and diffusion theory, and includes more than 100 original equations. The theoretical principles are illustrated with natural examples that emphasize oxygen and hydrogen isotope variations in natural waters, terrestrial and extraterrestrial rocks, and hydrothermal systems. New data on meteoric precipitation, rivers, springs, formation fluids, and hydrothermal systems are included in relation to various natural phenomena. Essentially, this book seeks to reconnect the diverse phenomenological observations of isotope distribution to the quantitative theories of physical chemistry and the language of differential equations. It may serve as a textbook for advanced students, as a research reference, or as a quick source of information. The book is organized into five chapters, each followed by suggested quantitative problems and a short reference list. The three theoretical chapters progress from an elementary review of the physical chemistry of stable isotopes, to the thermodynamics of isotopic compounds, and finally to the calculation of isotope distribution in dynamic systems. The third and fifth chapters emphasize oxygen and hydrogen isotope variations in Earth's hydrosphere and lithosphere, constituting the most important examples of the theoretical principles. Appendices provide data on atomic weights of light elements, physical constants, mathematical relationships, and isotopic fractionation factors.

This book has a very strong practical orientation, telling readers what methodologies are available using stable isotopes, how studies should be designed and executed to maximise effectiveness and incisiveness in terms of data obtained and outcomes in terms of understanding events and processes in plant and ecosystem functioning. The readership is very much aimed toward postgraduates with good knowledge of general biological principles and underlying chemical and physical processes. Pre-existing knowledge of or experience in application and assay of stable isotopes is not required. The stable isotope research field is one of the most rapidly growing areas of ecophysiology and techniques using stable isotopes comprise an ever increasing component of research programs of university postgraduates and a wide range of agencies conducting environmental monitoring and rehabilitation programs. The book is tailor-made for such an audience.

This textbook is a complete rewrite, and expansion of Hugh Rollinson's highly successful 1993 book Using Geochemical Data: Evaluation, Presentation, Interpretation. Rollinson and Pease's new book covers the explosion in geochemical thinking over the past three decades, as new instruments and techniques have come online. It provides a comprehensive overview of how modern geochemical data are used in the understanding of geological and petrological processes. It covers major element, trace element, and radiogenic and stable isotope geochemistry. It explains the potential of many geochemical techniques, provides examples of their application, and emphasizes how to interpret the resulting data. Additional topics covered include the critical statistical analysis of geochemical data, current geochemical techniques, effective display of geochemical data, and the application of data in problem solving and identifying petrogenetic processes within a geological context. It will be invaluable for all graduate students, researchers, and professionals using geochemical techniques.

The development of multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) makes it possible to precisely measure non-traditional stable isotopes. This volume reviews the current status of non-traditional isotope geochemistry from analytical, theoretical, and experimental approaches to analysis of natural samples. In particular, important applications to cosmochemistry, high-temperature geochemistry, low-temperature geochemistry, and geobiology are discussed. This volume provides the most comprehensive review on non-traditional isotope geochemistry for students and researchers who are interested in both the theory and applications of non-traditional stable isotope geochemistry.

Volume 43 of Reviews in Mineralogy and Geochemistry follows the 1986 Reviews in Mineralogy (Vol. 16) in approach but reflects significant changes in the field of Stable Isotope Geochemistry. In terms of new technology, new sub-disciplines, and numbers of researchers, the field has changed more in the past decade than in any other since that of its birth. Unlike the 1986 volume, which was restricted to high temperature fields, this book covers a wider range of disciplines. However, it would not be possible to fit a comprehensive review into a single volume. Our goal is to provide state-of-the-art reviews in chosen subjects that have emerged or advanced greatly since 1986. This volume was prepared for Short Course on Stable Isotope Geochemistry presented November 2-4, 2001 in conjunction with the annual meetings of the Geological Society of America in Boston, Massachusetts.

Physiological plant ecology is primarily concerned with the function and performance of plants in their environment. Within this broad focus, attempts are made on one hand to understand the underlying physiological, biochemical and molecular attributes of plants with respect to performance under the constraints imposed by the environment. On the other hand physiological ecology is also concerned with a more synthetic view which attempts to under stand the distribution and success of plants measured in terms of the factors that promote long-term survival and reproduction in the environment. These concerns are not mutually exclusive but rather represent a continuum of research approaches. Osmond et al. (1980) have elegantly pointed this out in a space-time scale showing that the concerns of physiological ecology range from biochemical and organelle-scale events with time constants of a second or minutes to succession and evolutionary-scale events involving communities and ecosystems and thousands, if not millions, of years. The focus of physiological ecology is typically at the single leaf or root system level extending up to the whole plant. The time scale is on the order of minutes to a year. The activities of individual physiological ecologists extend in one direction or the other, but few if any are directly concerned with the whole space-time scale. In their work, however, they must be cognizant both of the underlying mechanisms as well as the consequences to ecological and evolutionary processes.

Stable Isotope Geochemistry is an introduction to the use of stable isotopes in the geosciences. For students and scientists alike the book will be a primary source of information with regard to how and where stable isotopes can be used to solve geological problems. It is subdivided into three parts: i) theoretical and experimental principles, ii) fractionation processes of light and heavy elements, iii) the natural variations of geologically important reservoirs. In the last decade, major advances in multicollector-ICP-mass-spectrometry enable the precise determination of a wide range of transition and heavy elements. Progress in analysing the rare isotopes of certain elements allows the distinction between mass-dependent and mass-independent fractionations. These major advances in analytical techniques make an extended new edition necessary. Special emphasis has been given to the growing field of “non-traditional” isotope systems. Many new references have been added, which will enable quick access to recent literature.

This book provides the first comprehensive, overview and guide to forensic isotope analysis, an exciting new application of stable isotope analytical techniques. Topics are introduced using examples and real-life case studies such as food quality control where isotope analysis has already had a major impact, in terms of consumer protection, These examples illustrate the underlying principles of isotope profiling or fingerprinting. A section comprising actual criminal case work is used to build a bridge between the introduction and the technical section to encourage students to engage with this novel departure for analytical sciences while at the same time providing hands-on examples for the experienced researcher and forensic practitioner to match problems and success stories encountered with the topics discussed in the technical section. What little information is available on the subject in book form so far, has been published as individual chapters in books dealing either with mass spectrometry, forensic geoscience or environmental forensics, this is the first book to focus on the entire spectrum of forensic isotope analysis and will be an invaluable reference to both researchers in the field and forensic practitioners.