Photochemical Processes in Polymer Chemistry-2 contains invited lectures presented at the Second IUPAC Symposium on Photochemical Processes in Polymer Chemistry held at Leuven, Belgium on June 2-4, 1976. This book contains 11 papers separated as chapters. Topics include energy transfer processes; photoinitiation of polymerization; solid-state polymerization mechanisms; photoinduced ionic polymerizations; and photoconductive polymers. This text also discusses energy transfer phenomena in high polymer systems; laser spectroscopical methods for the study of primary processes during the photodegradation; photooxidation of high polymers; and reaction selectivity and molecular association in photochemical reactions of nucleic acids and their constituents. New developments in photochromic polymers and related phenomena, as well as the design of photoreactive polymer systems for imaging processes are also explained.

The development of photosensitive materials in general and photoreactive polymers in particular is responsible for major advances in the information, imaging, and electronic industries. Computer parts manufacturing, information storage, and book and magazine publishing all depend on photoreactive polymer systems. The photo-and radiation-induced processes in polymers are also active areas of research. New information on the preparation and properties of com mercially available photosensitive systems is constantly being acquired. The recent demand for environmentally safe solvent-free and water-soluble materials also motivated changes in the composition of photopolymers and photoresists. The interest in holographic recording media for head-up displays, light scanners, and data recording stimulated development of reconfigurable and visible light sensitive materials. Photoconductive polymerizable coatings are being tested in electrostatic proofing and color printing. The list of available initiators, poly meric binders, and other coating ingredients is continually evolving to respond to the requirements of low component loss (low diffusivity) and the high rate of photochemical reactions.

S. Georgiou: Laser Cleaning Methodologies of Polymer Substrates; T. Lippert: Laser Application of Polymers; J. Krueger, W. Kautek: Ultrashort Pulse Laser Interactions with Polymers and Dielectrics; Y. Zhang: Synchrotron Radiation Direct Photo-Etching of Polymers.

Chemical Transformations of Polymers provides information pertinent to the fundamental structure and aspects of the chemical transformation of polymers. This book examines several experiments for the chemical transformation of polymers, which start from the assumption that the reactivity of a functional group in a macromolecule has to be similar as one in a low molecular compound. Organized into 19 chapters, this book begins with an overview of the various photochromic systems that have been used in polymer chemistry. This text then examines the three types of stable polymers with unpaired electrons, including polyradical ions, neutral polyradicals, and polymeric charge transfer complexes. Other chapters consider the kinetic laws and traits of migration mechanisms of free valence in the process of decay of free radicals in polymers. The final chapter deals with the complicated reaction of the degradation of polymers induced by the presence of metal compounds. This book is a valuable resource for chemists, scientists, and physiochemical researchers.

Continuous-flow photochemistry is an expanding field within chemistry. It unites the mass transfer enhancement of flow chemistry with the high energy field density of microscale geometries. Moreover, it provides means to scale photochemical reactions efficiently.This book gives an overview of both technological and chemical aspects associated with photochemical processes in microreactors. It provides analysis, the first of its kind, of these new technologies developed within the field of photochemical processes, with a description and case studies of practical implementation. It specifically looks at:By providing a deeper understanding of underlying concepts, coupled with numerous examples, this book is an essential reference for chemistry students, researchers and professionals working on photochemistry, photoredox catalysis, flow chemistry, process chemistry and reactor engineering.

Introduction to photochemistry and photophysics. Polymer structure and reactivity. Diffusion and permeability in polymers. Determination of scission and crosslinking in polymers. Photoprocesses in solid polymer matrices. Fluorescence. Excimers and exciplexes. Phosphorescence. Energy transfer and migration in polymers. Photochemistry of carbonyl-containing polymers. Photopolymerization. Photocyclization. Miscellaneous photoprocesses. Photo- and radiation chemistry of polymers.

The development of photosensitive materials in general and photoreactive polymers in particular is responsible for major advances in the information, imaging, and electronic industries. Computer parts manufacturing, information storage, and book and magazine publishing all depend on photoreactive polymer systems. The photo-and radiation-induced processes in polymers are also active areas of research. New information on the preparation and properties of com mercially available photosensitive systems is constantly being acquired. The recent demand for environmentally safe solvent-free and water-soluble materials also motivated changes in the composition of photopolymers and photoresists. The interest in holographic recording media for head-up displays, light scanners, and data recording stimulated development of reconfigurable and visible light sensitive materials. Photoconductive polymerizable coatings are being tested in electrostatic proofing and color printing. The list of available initiators, poly meric binders, and other coating ingredients is continually evolving to respond to the requirements of low component loss (low diffusivity) and the high rate of photochemical reactions.