Corrosion Chemistry details the scientific background of the corrosion process and contemporary applications for dealing with corrosion for engineers and scientists, covering the most recent breakthroughs and trends. Corrosion is in essence a chemical process, and it is crucial to understand the dynamics from a chemical perspective before proceeding with analyses, designs and solutions from an engineering aspect. This book can be used both as a textbook and a reference book both by academics and engineers and scientists in the field. As a reference for the engineer in the field, it is both a refresher for the veteran on the causes of corrosion and the methods, processes, and technologies to deal with it, over a variety of industries. It is the most up-to-date, comprehensive treatment of corrosion available, covering the most cutting-edge new processes and theories. For the freshman engineer just entering the field, it is a tremendous introduction to corrosion. As a textbook, it can be used for a single semester technical elective course in undergraduate and postgraduate education for disciplines such as chemistry, chemical engineering, petroleum engineering, civil engineering, material engineering, mechanical engineering, metallurgical engineering, mining engineering, agricultural engineering, and other related technical fields.

With its unique focus on specifically addressing the problems for societies and economies associated with corrosion and their solution, this book provides an up-to-date overview of the progress in corrosion chemistry and engineering. International experts actively involved in research and development place particular emphasis on how to counter the economic and environmental consequences of corrosion with the help of science and technology, making this a valuable resource for researchers as well as decision makers in industry and politics. Further major parts of the book are devoted to corrosion prevention in the naval and energy sector as well as to corrosion monitoring and waste management.

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ATMOSPHERIC CORROSION Presents a comprehensive look at atmospheric corrosion, combining expertise in corrosion science and atmospheric chemistry Atmospheric corrosion has been a subject of engineering study, largely empirical, for nearly a century. Scientists came to the field rather later on and had considerable difficulty bringing their arsenal of tools to bear on the problem. Atmospheric corrosion was traditionally studied by specialists in corrosion having little knowledge of atmospheric chemistry, history, or prospects. Atmospheric Corrosion provides a combined approach bringing together experimental corrosion and atmospheric chemistry. The second edition expands on this approach by including environmental aspects of corrosion, atmospheric corrosion modeling, and international corrosion exposure programs. The combination of specialties provides a more comprehensive coverage of the topic. These scientific insights into the corrosion process and its amelioration are the focus of this book. Key topics include the following: Basic principles of atmospheric corrosion chemistry Corrosion mechanisms in controlled and uncontrolled environments Degradation of materials in architectural, transport, and structural applications; electronic devices; and cultural artifacts Protection of existing materials and choosing new ones that resist corrosion Prediction of how and where atmospheric corrosion may evolve in the future Complete with appendices discussing experimental techniques, computer models, and the degradation of specific metals, Atmospheric Corrosion, Second Edition continues to be an invaluable resource for corrosion scientists, corrosion engineers, conservators, environmental scientists, and anyone interested in the theory and application of this evolving field. The book concerns primarily the atmospheric corrosion of metals and is written at a level suitable for advanced undergraduates or beginning graduate students in any of the physical or engineering sciences.

Corrosion due to water is one of the most significant and complex causes of damage to metallic products. Written from the viewpoint of physical chemistry, this authoritative and established text deals with the aqueous corrosion of metals. Available for the first time in English, Corrosion of Metal addressing engineers, metallurgists, physicists and chemists. This self-contained, valuable reference comprehensively organizes and makes readily accessible the accumulated wealth of fundamental and applied knowledge. The concentration is on the underlying essentials of corrosion and failure, and the material is consistently presented in relation to practical applications to corrosion protection. The first chapters introducing the physicochemical principles are ideal for students. The following chapters provide an overview of the state of research for those familiar with the fundamentals. An exhaustive bibliography and appendices conclude the volume.

This textbook is intended for a one-semester course in corrosion science at the graduate or advanced undergraduate level. The approach is that of a physical chemist or materials scientist, and the text is geared toward students of chemistry, materials science, and engineering. This textbook should also be useful to practicing corrosion engineers or materials engineers who wish to enhance their understanding of the fundamental principles of corrosion science. It is assumed that the student or reader does not have a background in electrochemistry. However, the student or reader should have taken at least an undergraduate course in materials science or physical chemistry. More material is presented in the textbook than can be covered in a one-semester course, so the book is intended for both the classroom and as a source book for further use. This book grew out of classroom lectures which the author presented between 1982 and the present while a professorial lecturer at George Washington University, Washington, DC, where he organized and taught a graduate course on “Environmental Effects on Materials.” Additional material has been provided by over 30 years of experience in corrosion research, largely at the Naval Research Laboratory, Washington, DC and also at the Bethlehem Steel Company, Bethlehem, PA and as a Robert A. Welch Postdoctoral Fellow at the University of Texas. The text emphasizes basic principles of corrosion science which underpin extensions to practice.

Humankind's use of zinc stretches back to antiquity, and it was a component in some of the earliest known alloy systems. Even though metallic zinc was not "discovered" in Europe until 1746 (by Marggral), zinc ores were used for making brass in biblical times, and an 87% zinc alloy was found in prehistoric ruins in Transylvania. Also, zinc (the metal) was produced in quantity in India as far back as the thirteenth century, well before it was recognized as being a separate element. The uses of zinc are manifold, ranging from galvanizing to die castings to electronics. It is a preferred anode material in high-energy-density batteries (e.g., Ni/Zn, Ag/Zn, ZnJair), so that its electrochemistry, particularly in alkaline media, has been extensively explored. In the passive state, zinc is photoelectrochemically active, with the passive film displaying n-type characteristics. For the same reason that zinc is considered to be an excellent battery anode, it has found extensive use as a sacrificial anode for the protection of ships and pipelines from corrosion. Indeed, aside from zinc's well-known attributes as an alloying element, its widespread use is principally due to its electrochemical properties, which include a well-placed position in the galvanic series for protecting iron and steel in natural aqueous environments and its reversible dissolution behavior in alkaline solutions.

Supramolecular chemistry, "the chemistry beyond the molecule", is a fascinating realm of modern science. The design of novel supramolecular structures, surfaces, and techniques are at the forefront of research in different application areas, including corrosion and biofouling protection. A team of international experts provide a comprehensive view of the applications and potential of supramolecular chemistry in corrosion and biofouling prevention. Chapter topics include types and fundamentals of supramolecules, supramolecular polymers and gels, host-guest inclusion compounds, organic-inorganic hybrid materials, metallo-assemblies, cyclodextrins, crown ethers, mesoporous silica and supramolecular structures of graphene and other advances. Additional Features include: Focuses on different aspects of supramolecular chemistry in corrosion and biofouling prevention. Comprehensively covers supramolecular interactions that can provide better corrosion and biofouling protection. Provides the latest developments in self-healing coatings. Explores recent research advancements in the suggested area. Includes case studies specific to industries. The different supramolecular approaches being investigated to control corrosion and biofouling are gathered in one well-organized reference to serve senior undergraduate and graduate students, research students, engineers, and researchers in the fields of corrosion science & engineering, biofouling, and protective coatings.

Covering the essential aspects of the corrosion behavior of metals in aqueous environments, this book is designed with the flexibility needed for use in courses for upper-level undergraduate and graduate students, for concentrated courses in industry, for individual study, and as a reference book.

The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.