Humankind's use of zinc stretches back to antiquity, and it was a component in some of the earliest known alloy systems. Even though metallic zinc was not "discovered" in Europe until 1746 (by Marggral), zinc ores were used for making brass in biblical times, and an 87% zinc alloy was found in prehistoric ruins in Transylvania. Also, zinc (the metal) was produced in quantity in India as far back as the thirteenth century, well before it was recognized as being a separate element. The uses of zinc are manifold, ranging from galvanizing to die castings to electronics. It is a preferred anode material in high-energy-density batteries (e.g., Ni/Zn, Ag/Zn, ZnJair), so that its electrochemistry, particularly in alkaline media, has been extensively explored. In the passive state, zinc is photoelectrochemically active, with the passive film displaying n-type characteristics. For the same reason that zinc is considered to be an excellent battery anode, it has found extensive use as a sacrificial anode for the protection of ships and pipelines from corrosion. Indeed, aside from zinc's well-known attributes as an alloying element, its widespread use is principally due to its electrochemical properties, which include a well-placed position in the galvanic series for protecting iron and steel in natural aqueous environments and its reversible dissolution behavior in alkaline solutions.

A cornerstone reference in the field, this work analyzes available information on the corrosion resistance of zinc and its alloys both as solid materials and as coatings on steel, detailing the corrosion resistance of zinc in atmospheric, aqueous, underground and chemical environments. Corrosion Resistance of Zinc and Zinc Alloys illustrates the nu

The Metallurgy of Zinc Coated Steels provides a comprehensive overview of the science and engineering of zinc coatings. Beginning with a look at new innovations made in the hot-dip coating methods (CGL), the book goes on to discuss phase equilibria, Zn bath phenomena and overlay coating formations. Both processing methods and controls are covered, as well as corrosion resistance and coating product properties. The book concludes with a discussion of future opportunities for zinc coatings. This book is a vital resource for both individuals new to this area while also serving as a handbook for users and producers of zinc coatings. - Presents a basic understanding of the science and engineering behind zinc coatings with a thorough and cutting-edge look at their processing methods, controls, properties, and applications - Discusses corrosion resistance, overlay coating formation, heat treatment, interface reactions, deposition processes, and more - Covers real-world applications of these coatings

ZINC SURFACES THE LEADING RESOURCE FOR ARCHITECTS, DESIGNERS, AND ARTISTS WORKING WITH ZINC Zinc Surfaces: A Guide to Alloys, Finishes, Fabrication and Maintenance in Architecture and Art combines the latest guidance and information about zinc surfaces into a single and comprehensive resource for architects and artists everywhere. The fifth book in the author’s authoritative Architectural Metals Series, Zinc Surfaces offers a highly visual, full-color guide to ensure architects and design professionals have the information they need to properly maintain and fabricate zinc surfaces. Numerous case studies illuminate and highlight the theoretical principles contained within. Full of concrete strategies and practical advice, Zinc Surfaces provides readers with complete information on topics including: The use of zinc in architecture The history of zinc’s use in design How to choose the right alloy for your purposes Surface and chemical finishes Corrosion resistance of various alloys This book is perfect for architecture professionals, metal fabricators and developers, architecture students and instructors, and designers and artists working with metals.

Corrosion is a huge issue for materials, mechanical, civil and petrochemical engineers. With comprehensive coverage of the principles of corrosion engineering, this book is a one-stop text and reference for students and practicing corrosion engineers. Highly illustrated, with worked examples and definitions, it covers basic corrosion principles, and more advanced information for postgraduate students and professionals. Basic principles of electrochemistry and chemical thermodynamics are incorporated to make the book accessible for students and engineers who do not have prior knowledge of this area. Each form of corrosion covered in the book has a definition, description, mechanism, examples and preventative methods. Case histories of failure are cited for each form. End of chapter questions are accompanied by an online solutions manual.* Comprehensively covers the principles of corrosion engineering, methods of corrosion protection and corrosion processes and control in selected engineering environments* Structured for corrosion science and engineering classes at senior undergraduate and graduate level, and is an ideal reference that readers will want to use in their professional work* Worked examples, extensive end of chapter exercises and accompanying online solutions and written by an expert from a key pretochemical university

Covering the essential aspects of the corrosion behavior of metals in aqueous environments, this book is designed with the flexibility needed for use in courses for upper-level undergraduate and graduate students, for concentrated courses in industry, for individual study, and as a reference book.

Electrochemistry and Corrosion Science is a graduate level text/professional reference that describes the types of corrosion on metallic materials. The focus will be on modeling and engineering approximation schemes that describe the thermodynamics and kinetics of electrochemical systems. The principles of corrosion behavior and metal recovery are succinctly described with the aid of pictures, figures, graphs and schematic models, followed by derivation of equations to quantify relevant parameters. Example problems are included to illustrate the application of electrochemical concepts and mathematics for solving complex corrosion problems. This book differs from others in that the subject matter is organized around the modeling and predicating approaches that are used to determine detrimental and beneficial electrochemical events. Thus, this book will take a more practical approach and make it especially useful as a basic text and reference for professional engineers.

Corrosion, Volume 1: Metal/Environment Reactions is concerned with the subject of corrosion, with emphasis on the control of the environmental interactions of metals and alloys used as materials of construction. Corrosion is treated as a synthesis of corrosion science and corrosion engineering. This volume is comprised of nine chapters; the first of which provides an overview of the principles of corrosion and oxidation, with emphasis on the electrochemical mechanism of corrosion and how the kinetics of cathodic and anodic partial reactions control the rate of overall corrosion reaction. Attention then turns to the effects of environmental factors such as concentration, velocity, and temperature based on the assumption that either the anodic or cathodic reaction, but not both, is rate-controlling. The corrosion of ferrous and non-ferrous metals and alloys, as well as rarer and noble metals, is considered. The reader is also introduced to high-temperature corrosion and mechanical factors that affect corrosion. This book concludes with topics of electrochemistry and metallurgy relevant to corrosion, including the nature of the electrified interface between the metal and the solution; charge transfer across the interface under equilibrium and non-equilibrium conditions; overpotential and the rate of an electrode reaction; and the hydrogen evolution reaction and hydrogen absorption by ferrous alloys. This book will be of value to students as well as workers and engineers in the field of corrosion.

One of the main, ongoing challenges for any engineering enterprise is that systems are built of materials subject to environmental degradation. Whether working with an airframe, integrated circuit, bridge, prosthetic device, or implantable drug-delivery system, understanding the chemical stability of materials remains a key element in determining their useful life. Environmental Degradation of Advanced and Traditional Engineering Materials is a monumental work for the field, providing comprehensive coverage of the environmental impacts on the full breadth of materials used for engineering infrastructure, buildings, machines, and components. The book discusses fundamental degradation processes and presents examples of degradation under various environmental conditions. Each chapter presents the basic properties of the class of material, followed by detailed characteristics of degradation, guidelines on how to protect against corrosion, and a description of testing procedures. A complete, self-contained industrial reference guide, this valuable resource is designed for students and professionals interested in the development of deterioration-resistant technological systems constructed with metallurgical, polymeric, ceramic, and natural materials.

This textbook is intended for a one-semester course in corrosion science at the graduate or advanced undergraduate level. The approach is that of a physical chemist or materials scientist, and the text is geared toward students of chemistry, materials science, and engineering. This textbook should also be useful to practicing corrosion engineers or materials engineers who wish to enhance their understanding of the fundamental principles of corrosion science. It is assumed that the student or reader does not have a background in electrochemistry. However, the student or reader should have taken at least an undergraduate course in materials science or physical chemistry. More material is presented in the textbook than can be covered in a one-semester course, so the book is intended for both the classroom and as a source book for further use. This book grew out of classroom lectures which the author presented between 1982 and the present while a professorial lecturer at George Washington University, Washington, DC, where he organized and taught a graduate course on “Environmental Effects on Materials.” Additional material has been provided by over 30 years of experience in corrosion research, largely at the Naval Research Laboratory, Washington, DC and also at the Bethlehem Steel Company, Bethlehem, PA and as a Robert A. Welch Postdoctoral Fellow at the University of Texas. The text emphasizes basic principles of corrosion science which underpin extensions to practice.