III . 2 Preparation of synthetic membranes 72 III . 3 Phase inversion membranes 75 III. 3. 1 Preparation by evaporation 76 III . 3. 2 Precipitation. from the vapour phase 76 III . 3. 3 Precipitation by controlled evaporation 76 Thermal precipitation 76 III . 3. 4 III . 3. 5 Immersion precipitation 77 Preparation techniques for immersion precipitation 77 III . 4 Flat membranes 77 III . 4. 1 78 III . 4. 2 Tubular membranes 81 III . 5 Preparation techniques for composite membranes 82 III. 5. 1 Interfacial polymerisation Dip-coating 83 III . 5. 2 III . 5. 3 Plasma polymerisation 86 III . 5. 4 Modification of homogeneous dense membranes 87 III . 6 Phase separation in polymer systems 89 III . 6. 1 Introduction 89 III . 6. 1. 1 Thermodynamics 89 III . 6. 2 Demixing processes 99 III . 6. 2. 1 Binary mixtures 99 III . 6. 2. 2 Ternary systems 102 III . 6. 3 Crystallisation 104 III . 6. 4 Gelation 106 III . 6. 5 Vitrification 108 III . 6. 6 Thermal precipitation 109 III . 6. 7 Immersion precipitation 110 III . 6. 8 Diffusional aspects 114 III . 6. 9 Mechanism of membrane formation 117 III. 7 Influence of various parameters on membrane morphology 123 III. 7. 1 Choice of solvent-nonsolvent system 123 III . 7. 2 Choice of the polymer 129 III . 7. 3 Polymer concentration 130 III . 7. 4 Composition of the coagulation bath 132 III . 7. 5 Composition of the casting solution 133 III . 7.

The field of synthetic membrane science and technology is an active, growing field involving an interdisciplinary mixture of polymer chemistry, physical chemistry, and chemical engineering. Some membrane processes are reasonably well understood, and have been commercialised for some period of time. Other membrane processes have only recently been employed in commercial applications, and still other processes are only in formative research stages. This volume gives a comprehensive compendium of the basic principles in the field of synthetic membranes. The following topics are covered: basic aspects of membrane processes; materials and material properties; membrane preparation and characterisation; membrane transport; concentration polarisation and fouling; process and module design. The second edition of this well-established text has been considerably expanded and updated, and many chapters now contain sections giving solved and unsolved problems. Audience: This book is recommended as a textbook for undergraduate and graduate students, as well as a comprehensive reference for engineers, scientists, and technical management.

Membranes playa central role in our daily life, or as indicated by one of my foreign colleagues, Richard Bowen, 'If you are tired of membranes, you are tired of life' . Biological membranes are hardly used in industrial applications, but separations with synthetic membranes have become increasingly important. Today, membrane processes are used in a wide range of applications and their numbers will certainly increase. Therefore, there is a need for well educated and qualified engineers, chemists, scientists and technicians who have been taught the basic principles of membrane technology. However, despite the growing importance of membrane processes, there are only a few universities that include membrane technology in their regular curricula. One of the reasons for this may be the lack of a comprehensive textbook. For me, this was one of the driving forces for writing a textbook on the basic principles of membrane technology which provides a broad view on the various aspects of membrane technology. I realise that membrane technology covers a broad field but nevertheless I have tried to describe the basic principles of the various disciplines. Although the book was written with the student in mind it can also serve as a first introduction for engineers, chemists, and technicians in all kind of industries who wish to learn the basics of membrane technology.

The field of membrane separation technology is presently in a state of rapid growth and innovation. Many different membrane separation processes have been developed during the past half century and new processes are constantly emerging from academic, industrial, and governmental laboratories. While new membrane separation processes are being conceived with remarkable frequency, existing processes are also being constantly improved in order to enhance their economic competitiveness. Significant improvements are currently being made in many aspects of membrane separation technology: in the development of new membrane materials with higher selectivity and/or permeability, in the fabrication methods for high-flux asymmetric or composite membranes, in membrane module construction and in process design. Membrane separation technology is presently being used in an impressive variety of applications and has generated businesses totalling over one billion U.S. dollars annually.The main objective of this book is to present the principles and applications of a variety of membrane separation processes from the unique perspectives of investigators who have made important contributions to their fields. Another objective is to provide the reader with an authoritative resource on various aspects of this rapidly growing technology. The text can be used by someone who wishes to learn about a general area of application as well as by the knowledgeable person seeking more detailed information.

Table of Contents Preface Acknowledgments for the first edition Acknowledgments for the second edition 1 Overview of Membrane Science and Technology 1 2 Membrane Transport Theory 15 3 Membranes and Modules 89 4 Concentration Polarization 161 5 Reverse Osmosis 191 6 Ultrafiltration 237 7 Microfiltration 275 8 Gas Separation 301 9 Pervaporation 355 10 Ion Exchange Membrane Processes - Electrodialysis 393 11 Carrier Facilitated Transport 425 12 Medical Applications of Membranes 465 13 Other Membrane Processes 491 Appendix 523 Index 535.

Separation of Functional Molecules in Food by Membrane Technology deals with an issue that is becoming a new research trend in the field of food and bioproducts processing. The book fills in the gap of transfer knowledge between academia and industry by highlighting membrane techniques and applications for the separation of food components in bioresources, discussing separation mechanisms, balancing advantages and disadvantages, and providing relevant applications. Edited by Charis Galanakis, the book is divided in 13 chapters written by experts from the meat science, food technology and engineering industries. - Covers the 13 most relevant topics of functional macro and micro molecules separation using membrane technology in the food industry - Brings the most recent advances in the field of membrane processing - Presents the sustainability principles of the food industry and the modern bioeconomy frame of our times

Membrane-Based Separation in Metallurgy: Principles and Applications begins with basic coverage of the basic principles of the topic and then explains how membrane technology helps in the development of new environmentally friendly and sustainable metallurgical processes. The book features the principles of metallurgical process and how widely the membrane-based technology has been applied in metallurgical industry, including the basic principles of membrane-based separation in terms of material science, membrane structure engineering, transport mechanisms, and module design, detailed metallurgical process flowcharts with emphasis on membrane separations, current process designs, and describes problems and provides possible solutions. In addition, the book includes specific membrane applications, molecular design of materials, fine tuning of membrane's multi-scale structure, module selection and process design, along with a final analysis of the environmental and economic benefits achieved by using these new processes.

Advanced membranes-from fundamentals and membrane chemistry to manufacturing and applications A hands-on reference for practicing professionals, Advanced Membrane Technology and Applications covers the fundamental principles and theories of separation and purification by membranes, the important membrane processes and systems, and major industrial applications. It goes far beyond the basics to address the formulation and industrial manufacture of membranes and applications. This practical guide: Includes coverage of all the major types of membranes: ultrafiltration; microfiltration; nanofiltration; reverse osmosis (including the recent high-flux and low-pressure membranes and anti-fouling membranes); membranes for gas separations; and membranes for fuel cell uses Addresses six major topics: membranes and applications in water and wastewater; membranes for biotechnology and chemical/biomedical applications; gas separations; membrane contractors and reactors; environmental and energy applications; and membrane materials and characterization Includes discussions of important strategic issues and the future of membrane technology With chapters contributed by leading experts in their specific areas and a practical focus, this is the definitive reference for professionals in industrial manufacturing and separations and research and development; practitioners in the manufacture and applications of membranes; scientists in water treatment, pharmaceutical, food, and fuel cell processing industries; process engineers; and others. It is also an excellent resource for researchers in industry and academia and graduate students taking courses in separations and membranes and related fields.

Written by a dedicated lecturer and leading membrane scientist, who has worked both in academia and industry, this advanced textbook provides an impressive overview of all aspects of membranes and their applications. Together with numerous industrial case studies, practical examples and questions, the book provides an excellent and comprehensive introduction to the topic. Advanced students as well as process and chemical engineers working in industry will profit from this resource. A significant feature of the book is the treatment of more recently developed membranes and their applications in energy conversion, biomedical components, controlled release devices and environmental engineering with an indication of the present and future commercial impact. The solutions to the questions in the book can be found under http://www.wiley-vch.de/publish/en/books/ISBN3-537-32451-8/ From the Contents: * Introduction * Fundamentals * Membrane Preparation and Characterization * Principles of Membrane Separation Processes * Membrane Modules and Concentration Polarization * Membrane Process Design and Operation

Membrane Separation Principles and Applications: From Material Selection to Mechanisms and Industrial Uses, the latest volume in the Handbooks in Separation Science series, is the first single resource to explore all aspects of this rapidly growing area of study. Membrane technology is now accepted as one of the most effective tools for separation and purification, primarily due to its simple operation. The result has been a proliferation of studies on this topic; however, the relationships between fundamental knowledge and applications are rarely discussed. This book acts as a guideline for those who are interested in exploring membranes at a more progressive level. Covering methods of pressure driving force, partial pressure driving force, concentration driving force, electrical potential driving force, hybrid processes, and more, this volume is more complete than any other known resource on membrane separations. - Covers membrane material selection, membrane fabrication, membrane characterization, separation mechanisms and applications in each chapter - Authored by contributors who are internationally recognized as experts in their respective fields - Organized by the driving force behind each type of membrane separation—a unique approach that more clearly links fundamental principles with their dominant applications