This report presents a cost analysis of Vinyl Chloride production from ethylene dichloride (EDC). The process examined is a typical thermal cracking process. In this process, ethylene dichloride is thermally cracked in pyrolysis furnaces to produce Vinyl Chloride. Hydrogen chloride is generated as a by-product in the process. This report was developed based essentially on the following reference(s): (1) "Chlorinated Hydrocarbons", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition (2) US Patent 7767869, issued to Vinnolit in 2010 Keywords: Chloroethene, 1,2-Dichloroethane, Vinnolit, OxyVinyls, Thermal Cracking

This report presents a cost analysis of Vinyl Chloride production from ethylene dichloride (EDC). The process examined is a typical thermal cracking process. In this process, ethylene dichloride is thermally cracked in pyrolysis furnaces to produce Vinyl Chloride. Hydrogen chloride is generated as a by-product in the process. This report examines one-time costs associated with the construction of a United States-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) This report was developed based essentially on the following reference(s): "Chlorinated Hydrocarbons", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Chloroethene, 1,2-Dichloroethane, Vinnolit, OxyVinyls, Thermal Cracking

This report presents a cost analysis of Ethylene Dichloride (EDC) production from ethylene and chlorine using a direct chlorination process. The process examined is similar to OxyVinyls process. This process consists in a liquid-phase high temperature chlorination (HTC). This report was developed based essentially on the following reference(s): EP Patent 0260650, originally issued to B.F. Goodrich Company (assigned to OxyVinyls in 2000) Keywords: Ethene, 1,2-Dichloroethane, Inovyl, European Vinyls Corporation, EVC

This report presents a cost analysis of Methyl Chloride production from methanol and hydrogen chloride. The process examined is a typical catalytic vapor phase process. In this process, methanol and anhydrous HCl are combined in vapor phase and passed through a catalyst bed. Reactor vapor outlet is quenched, dried by sulfuric acid scrubbing and then purified to generate high-purity Methyl Chloride. This report was developed based essentially on the following reference(s): (1) "Chloromethanes", Ullmann's Encyclopedia of Industrial Chemistry, 2012; (2) Handbook of Industrial Chemistry and Biotechnology, 2012 Keywords: Chloromethane, R-40, HCC-40, chlorosilanes production

This report presents a cost analysis of an early stage process for Hydroxymethylfurfural (HMF) production from glucose syrup. The process examined is similar to the one proposed by the University of Wisconsin-Madison. In this process, glucose is isomerized to fructose, which is then converted to Hydroxymethylfurfural (HMF). This report was developed based essentially on the following reference(s): US Patent 20080033188, issued to Wisconsin Alumni Research Institute in 2008 Keywords: Glucose Isomerization, Dehydration, Biphasic Reactor

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This report presents a cost analysis of Vinyl Chloride production from ethylene and chlorine via a balanced process. This typical balanced process combines two ethylene dichloride (EDC) production routes, direct chlorination and oxychlorination, for the production of Vinyl Chloride. By doing so, hydrogen chloride byproduct, produced in the thermal cracking unit, is used as raw material in the oxychlorination unit for additional production of EDC from ethylene. This report examines one-time costs associated with the construction of a United States-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) This report was developed based essentially on the following reference(s): (1) US Patent 7767869, issued to Vinnolit in 2010; (2) US Patent 6235953, issued to Vinnolit in 2001 Keywords: Chloroethene, 1,2-Dichloroethane, Hydrochlorination, INEOS, Vinnolit, Balanced Process

This report presents a cost analysis of Vinyl Chloride production from ethylene and ethylene dichloride (EDC). The process examined combines: (1) EDC production from ethylene via oxychlorination, and (2) Vinyl Chloride production via thermal cracking of EDC. The EDC cracking generates hydrogen chloride (HCl) used as raw material in the oxychlorination. The HCl requirement is balanced by purchasing additional EDC from the market. This report was developed based essentially on the following reference(s): Keywords: Chloroethene, 1,2-Dichloroethane, Vinnolit, OxyVinyls, Thermal Cracking, Oxychlorination

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