An engaging introduction to marine chemistry and the ocean's geochemical interactions with the solid earth and atmosphere, for students of oceanography.

In recent years, rapid scientific advances have been shattering classical concepts of oceanic trace metals concentrations. Most of the data gathered before the mid-1970s have had to be discarded. Possible associations of organic and inorganic ligands with the metals were throwing views of metal speciation into great uncertainty. Biological effects of metals need to be re-examined after recent revelations of unsuspected metal contaminations in methodology. The investigations appear chaotic, yet exciting. It implies that a new order is going to replace the past. Now, an opportunity opens its door to a brave new world for the young generation of scientists to put metal chemistries in the oceans into perspectiveo This N. AoToO. International Conference on "Trace Metals in Sea Water" hoped to catalyze this exciting process of unifying various aspects of trace metals in sea water in future years o The Conference, in the form of an Advanced Research Institute supported by the Scientific Affairs Division of NoAoT. O. supple mented by further assistance of the UoS. Office of Naval "Research, was held at the "Ettore Majorana" Center for Scientific Culture in the medieval town of Erice on the island of Sicily, Italy from March 30 to April 3, 1981. It was the first organized gathering of international scientists in this specialized field. Seventy scientists with various expertise in different aspects of the subject were present: including those from NoAoT. Oo countries (Canada, France, F. R. Germany, Greece, Iceland, Italy, U. K.

This book provides a detailed examination of the concentration, form and cycling of trace metals and metalloids through the aquatic biosphere, and has sections dealing with the atmosphere, the ocean, lakes and rivers. It discusses exchanges at the water interface (air/water and sediment/water) and the major drivers of the cycling, concentration and form of trace metals in aquatic systems. The initial chapters focus on the fundamental principles and modelling approaches needed to understand metal concentration, speciation and fate in the aquatic environment, while the later chapters focus on specific environments, with case studies and research highlights. Specific examples deal with metals that are of particular scientific interest, such as mercury, iron, arsenic and zinc, and the book deals with both pollutant and required (nutrient) metals and metalloids. The underlying chemical principles controlling toxicity and bioavailability of these elements to microorganisms and to the aquatic food chain are also discussed. Readership: Graduate students studying environmental chemistry and related topics, as well as scientists and managers interested in the cycling of trace substances in aqueous systems Additional resources for this book can be found at: www.wiley.com/go/mason/tracemetals.

Diet and Health examines the many complex issues concerning diet and its role in increasing or decreasing the risk of chronic disease. It proposes dietary recommendations for reducing the risk of the major diseases and causes of death today: atherosclerotic cardiovascular diseases (including heart attack and stroke), cancer, high blood pressure, obesity, osteoporosis, diabetes mellitus, liver disease, and dental caries.

The aim of this volume is to draw together state-of-the-art reviews of knowledge onlevels of heavy metals in marine environments (particularly in marine animals), the dynamicprocesses in these systems, toxic effects, and threats presented by heavy metals in foods ofmarine origin.All heavy metals, whether biologically essential or not, have the potential to be toxicto organisms at a threshold bioavailability. Such threshold concentrations vary betweenmetals, between species and with the physicochemical characteristics of the medium, somelike copper being particularly toxic even though essential in trace amounts. Responses ofanimals to metals in their medium or food depend to a large extent on the ability of speciesto regulate levels attained in their tissues. Higher animals have the capacity to regulate levelsof many metals, while marine invertebrates can regulate some within certain limits. Whereanimals cannot regulate physiological levels of metals, an alternative strategy is to detoxifyand store metals in relatively harmless forms. Knowledge of the manner in which animals deal with potentially toxic concentrations of heavy metals is of fundamental importance in the assessment of metal pollution by analysis of metal levels in biological samples. The interaction of heavy metals with biological materials is a key theme running through this volume. Toxic effects may be reflected at the individual, population, or ecosystem level, affecting species composition and production levels, or may be of direct dietary significance to man. The global cycling of metals through the marine environment is crucially affected by biological processes.

This book presents a comprehensive and detailed description of remediation techniques for metal-contaminated soils derived from both natural processes and anthropogenic activities. Using a methodical, step-by-step presentation, the book starts by overviewing the origin of toxicants and the correlated comparative extent of contamination to the environment. The legal provisions as proposed or applied in different countries are then discussed to explain the global regulatory situation regarding soil contamination and the extent of consequent concern. The core part of this publication describes the major techniques for in situ or ex situ treatment of the contaminated soil to meet the regulatory limits. Finally, risk evaluation is incorporated, giving special attention to possible impacts during or after implementation of the remediation strategies. The intrusion of metals in soils mostly occurs from various anthropogenic activities, e.g., agricultural practices, industrial activities, and municipal waste disposal. The volumes of metal-contaminated soil are becoming greater than before and are ever-increasing due to rapid urbanization, intensified industrialization, and/or population booms in certain parts of the world. Hence, the options previously proposed, such as isolation of the contaminated site or movement of the contaminated mass to a secure disposal site after excavation, are becoming unsuitable from the economic point of view, and instead, decontamination alternatives are preferred. This book will help readers such as scientists and regulators to understand the details of the remediation techniques available to deal with the soils contaminated by toxic metals.

This text presents the current knowledge of environmental colloids and includes reviews of the current understanding of structure, role and behaviour of environmental colloids and particles, whilst focussing directly on aquatic systems and soils. In addition, there is substantial critical assessment of the techniques employed for the sampling, size fractionation and characterisation of colloids and particles. Chemical, physical and biological processes and interactions involving colloids are described, and particular attention is paid to quantitative approaches that take account of particle heterogeneity and polydispersity. Presents critical reviews of the state-of-the-art knowledge of environmental colloids Critical assessment of techniques employed for the sampling, size fractionation and characterisation of colloids and particles are given Theoretical and experimental aspects of the methods as well as the required developments and possible recommendations are discussed Each chapter gives a brief introduction general enough for the non-specialist Written by a internationally recognized group of contributors

This research topic highlights the most recent accomplishments of a Scientific Committee on Oceanic Research (SCOR) Working Group, SCOR WG 139: Organic Ligands - A Key Control on Trace Metal Biogeochemistry in the Ocean.