The Chemistry of Clay Minerals

Introduction to Clay Minerals is designed to give a detailed, concise and clear introduction to clay mineralogy. Using the information presented here, one should be able to understand clays and their mineralogy, their uses and importance in modern life.

Surface and Interface Chemistry of Clay Minerals, Volume 9, delivers a fundamental understanding of the surface and interface chemistry of clay minerals, thus serving as a valuable resource for researchers active in the fields of materials chemistry and sustainable chemistry. Clay minerals, with surfaces ranging from hydrophilic, to hydrophobic, are widely studied and used as adsorbents. Adsorption can occur at the edges and surfaces of clay mineral layers and particles, and in the interlayer region. This diversity in properties and the possibility to tune the surface properties of clay minerals to match the properties of adsorbed molecules is the basis for study. This book requires a fundamental understanding of the surface and interface chemistry of clay minerals, and of the interaction between adsorbate and adsorbent. It is an essential resource for clay scientists, geologists, chemists, physicists, material scientists, researchers, and students. - Presents scientists and engineers with a resource they can rely on for their own research and work involving clay minerals - Includes an in-depth look at ion exchange, adsorption of inorganic and organic molecules, including polymers and proteins, and catalysis occurring at the surfaces of clay minerals - Includes materials chemistry of clay minerals with chiral clay minerals, optical materials and functional films

Bringing together information widely distributed throughout scientific and industrial journals, here is an overview of the chemical consititution and properties of clay minerals and the environmental conditions that lead to their formation. Provides a detailed picture of the chemical consititution of the eight main groups of clay minerals containing silica and of the non-siliceous oxide clays. The central section of the book deals with the properties of clays: their colloidal behavior, cation exchange, interaction with water, reactions on heating, catalytic properties, and reactions with organic compounds. Also discusses the chemical conditions that favor the formation of clays and their evolution or decomposition into other materials.

The first edition of the Handbook of Clay Science published in 2006 assembled the scattered literature on the varied and diverse aspects that make up the discipline of clay science. The topics covered range from the fundamental structures (including textures) and properties of clays and clay minerals, through their environmental, health and industrial applications, to their analysis and characterization by modern instrumental techniques. Also included are the clay-microbe interaction, layered double hydroxides, zeolites, cement hydrates, and genesis of clay minerals as well as the history and teaching of clay science. The 2e adds new information from the intervening 6 years and adds some important subjects to make this the most comprehensive and wide-ranging coverage of clay science in one source in the English language. - Provides up-to-date, comprehensive information in a single source - Covers applications of clays, as well as the instrumental analytical techniques - Provides a truly multidisciplinary approach to clay science

Infrared and Raman Spectroscopies of Clay Minerals, Volume 8 in the Developments in Clay Science series, is an up-to-date overview of spectroscopic techniques used in the study of clay minerals. The methods include infrared spectroscopy, covering near-IR (NIR), mid-IR (MIR), far-IR (FIR) and IR emission spectroscopy (IES), as well as FT-Raman spectroscopy and Raman microscopy. This book complements the succinct introductions to these methods described in the original Handbook of Clay Science (Volumes 1, 1st Edition and 5B, 2nd Edition), offering greater depth and featuring the most important literature since the development and application of these techniques in clay science. No other book covers such a wide variety of vibrational spectroscopic techniques in a single volume for clay and soil scientists. - Includes a systematic review of spectroscopic methods - Covers the theory of infrared and Raman spectroscopies and instrumentation - Features a series of chapters each covering either a particular technique or application

Of huge relevance in a number of fields, this is a survey of the different processes of soil clay mineral formation and the consequences of these processes concerning the soil ecosystem, especially plant and mineral. Two independent systems form soil materials. The first is the interaction of rocks and water, unstable minerals adjusting to surface conditions. The second is the interaction of the biosphere with clays in the upper parts of alteration profiles.

Origin and Mineralogy of Clays, the first of two volumes, lays the groundwork for a thorough study of clays in the environment. The second volume will deal with environmental interaction. Going from soils to sediments to diagenesis and hydrothermal alteration, the book covers the whole spectrum of clays. The chapters on surface environments are of great relevance in regard to environmental problems in soils, rivers and lake-ocean situations, showing the greatest interaction between living species and the chemicals in their habitat. The book is of interest to scientists and students working on environmental issues.

Layer charge determination by Alkylammonium Ions; Role of layer charge Role of layer charge in organic contaminant sorption by organo-clays; Evaluation of structural formulae and Alkylammonium methods of determining layer charge; Problems associated with layer charge characterization of 2:1 phyllosilicates; The movement of neutral particles in charged media.

Probably more than any other element, iron markedly influences the chemical and physical properties of soils and sediments in the earth. Considering its transition metal status, with potential variation in electronic configuration, ionic radius, and magnetic moment, combined with its abundance and relatively large mass, little wonder that one sees its unique influence on every hand. Pre sentations at the NATO Advanced Study Institute (NATO AS!) on Iron in Soils and Clay Minerals reviewed and discussed the occurrence, behavior, and properties of Fe-bearing minerals found in soils and in the clay mineral groups kaolinite, smectite, and mica. Also discussed at the NATO AS! were the basic chemical properties of Fe, methods for separating and identifying Fe in minerals, and the role of Fe minerals in weathering and other soil-forming processes. The present publication is the reviewed and edited proceedings of that Advanced Study Institute. The sequence of chapters follows the general pattern beginning with introductory chapters which overview the general occurrence of Fe in the earth and its chemistry, both generally and in mineral environments, followed by identification and characterization methods for Fe and Fe phases in minerals. The properties and behavior of Fe oxides, Fe-bearing clay minerals, and other Fe minerals in soils are then described, and the text ends with a summary of the role of Fe in soil-forming processes. A Table of Contents and subject index are provided to assist the reader in finding specific topics within the text.