Carboxylic Ortho Acid Derivatives: Preparation and Synthetic Applications discusses the principal classes of ortho acid derivatives and their preparation, properties, and reactions. The book is a critical survey and attempts to collate literature regarding the wide array of information on ortho acid derivatives to be of use to chemists studying different sorts of problems. The text is divided into seven chapters, where Chapter 1 begins with a discussion of the general concepts of carboxylic ortho esters, their synthesis, and properties. Chapters 2 to 4 tackle reactions of ortho esters that result to different bonds and bond formations such as (a) carbon-oxygen and carbon-halogen bond, (b) carbon-nitrogen or carbon-phosphorus, and (c) carbon-carbon or carbon-hydrogen bond formation. Chapter 5 discusses the synthesis, properties, and applications of carbohydrate ortho esters. Related compounds and their properties, preparation, and chemical transformations are the topic of Chapters 6 and 7. Some of these compounds are trithioorthocarboxylates, tetrathioorthocarbonates, and amide acetals. The book is a valuable reference to students or anyone else interested in chemistry.

Monographs in Organic Functional Group Analysis, Volume 3: Determination of Carboxylic Functional Groups focuses on the quantitative determination of acid chlorides, esters, carboxylic acids, anhydrides, lactones, and amides. The monograph first takes a look at the determination of carboxylic acids. Countercurrent and electrophoretic separation of organic acids; polarography of organic acids; acid-base equilibrium in non-aqueous media; and titrimetric determination of acids are discussed. The book also examines the determination of acid anhydrides, chlorides, and esters. The characteristics and composition of acid chlorides and anhydrides, as well as the saponification and spectroscopic methods used in the identification of esters, are presented. The book also evaluates the methods and use of Grignard's reagent in the determination of amides. The text also presents an analysis of binary and ternary mixtures. Mixtures of acids and acid chlorides, differentiation of acids, mixtures of acids and esters, and mixtures of acids and amides are discussed. The monograph is a vital reference for readers interested in the quantitative determination of acid chlorides, esters, carboxylic acids, and other related compounds.

This book is an attempt to bring together current knowledge on the role and importance of organic acids in life processes. There are lots of compounds based on the chemical nature of this functional group, which makes this class of molecules to be present in our lives starting with the human body (Krebs cycle - the core of cellular metabolism) to the products we currently use (food, medicines and cosmetics). No overall consensus is sought in this book, and the following chapters are authored by dedicated researchers presenting a diversity of applications and hypotheses concerning organic acids. The five chapters in this book include general information on carboxylic acids and their applications in life sciences (use in organic synthesis, nanotechnology, plant physiology, plant nutrition and soil chemistry).

The collection of contributions in this volume presents the most up-to-date findings in catalytic hydrogenation. The individual chapters have been written by 36 top specialists each of whom has achieved a remarkable depth of coverage when dealing with his particular topic. In addition to detailed treatment of the most recent problems connected with catalytic hydrogenations, the book also contains a number of previously unpublished results obtained either by the authors themselves or within the organizations to which they are affiliated.Because of its topical and original character, the book provides a wealth of information which will be invaluable not only to researchers and technicians dealing with hydrogenation, but also to all those concerned with homogeneous and heterogeneous catalysis, organic technology, petrochemistry and chemical engineering.

Gathering together the widespread literature in the field, this monograph acts as a reference guide to this very important chemical reaction. Following an introduction, the book goes on to discuss methodology, before treating synthetic and industrial applications -- the latter being a new focus in this completely revised, updated and extended second edition. A must-have for organic, natural products and catalytic chemists, as well as those working in industry, of for lecturers in chemistry.

Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.

Organic Chemistry for General Degree Students is written to meet the requirements of the London General Internal examination and degree examinations of a similar standing. It will also provide for the needs of students taking the Part 1 examination for Graduate Membership of the Royal Institute of Chemistry, or the Higher National Certificate, whilst the treatment is such that Ordinary National Certificate courses can be based on the first two volumes Within the limits broadly defined by the syllabus, the aim of this first volume is to provide a concise summary of the important general methods of preparation and properties of the main classes of aliphatic compounds. Due attention is paid to practical considerations with particular reference to important industrial processes. At the same time, the fundamental theoretical principles of organic chemistry are illustrated by the discussion of a selection of the more important reaction mechanisms. Questions and problems are included, designed to test the student's appreciation of the subject and his ability to apply the principles embodied therein. A selection of questions set in the relevant examinations is also included.