Supercapacitors are a relatively new energy storage system that provides higher energy density than dielectric capacitors and higher power density than batteries. They are particularly suited to applications that require energy pulses during short periods of time, e.g., seconds or tens of seconds. They are recommended for automobiles, tramways, buses, cranes, fork-lifts, wind turbines, electricity load leveling in stationary and transportation systems, etc. Despite the technological maturity of supercapacitors, there is a lack of comprehensive literature on the topic. Many high performance materials have been developed and new scientific concepts have been introduced. Taking into account the commercial interest in these systems and the new scientific and technological developments now is the ideal time to publish this book, capturing all this new knowledge. The book starts by giving an introduction to the general principles of electrochemistry, the properties of electrochemical capacitors, and electrochemical characterization techniques. Electrical double layer capacitors and pseudocapacitors are then discussed, followed by the various electrolyte systems. Modelling, manufacture of industrial capacitors, constraints, testing, and reliability as well as applications are also covered. 'Supercapacitors - Materials, Systems, and Applications' is part of the series on Materials for Sustainable Energy and Development edited by Prof. G.Q. Max Lu. The series covers advances in materials science and innovation for renewable energy, clean use of fossil energy, and greenhouse gas mitigation and associated environmental technologies.

Materials for Supercapacitor Applications provides a snapshot of the present status of this rapidly growing field. It covers motivations, innovations, ongoing breakthroughs in research and development, innovative materials, impacts, and perspectives, as well as the challenges and technical barriers to identifying an ideal material for practical applications. This comprehensive reference by electro-chemists explains concepts in materials selection and their unique applications based on their electro-chemical properties. Chemists, chemical and electrical engineers, material scientists, and research scholars and students interested in energy will benefit from this overview of many important reference points in understanding the materials used in supercapacitors. - Provides an overview of the formulation for new materials and how to characterize them for supercapacitor applications - Describes all the information on the available materials for supercapacitor applications - Outlines potential material characterization methods - Discusses perspectives and future directions of the field

The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc ture of electrolyte solutions into the model of a metal/solution interface, by en visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti cians have introduced a number of new parameters of which people were not aware 50 years ago.

Although recognized as an important component of all energy storage and conversion technologies, electrochemical supercapacitators (ES) still face development challenges in order to reach their full potential. A thorough examination of development in the technology during the past decade, Electrochemical Supercapacitors for Energy Storage and Delivery: Fundamentals and Applications provides a comprehensive introduction to the ES from technical and practical aspects and crystallization of the technology, detailing the basics of ES as well as its components and characterization techniques. The book illuminates the practical aspects of understanding and applying the technology within the industry and provides sufficient technical detail of newer materials being developed by experts in the field which may surface in the future. The book discusses the technical challenges and the practical limitations and their associated parameters in ES technology. It also covers the structure and options for device packaging and materials choices such as electrode materials, electrolyte, current collector, and sealants based on comparison of available data. Supplying an in depth understanding of the components, design, and characterization of electrochemical supercapacitors, the book has wide-ranging appeal to industry experts and those new to the field. It can be used as a reference to apply to current work and a resource to foster ideas for new devices that will further the technology as it becomes a larger part of main stream energy storage.

Advances in Supercapacitor and Supercapattery: Innovations in Energy Storage Devices provides a deep insight into energy storage systems and their applications. The first two chapters cover the detailed background, fundamental charge storage mechanism and the various types of supercapacitor. The third chapter give details about the hybrid device (Supercapattery) which comprises of battery and capacitive electrode. The main advantages of Supercapattery over batteries and supercapacitor are discussed in this chapter. The preceding three chapters cover the electrode materials used for supercapattery. The electrolyte is a major part that significantly contributes to the performance of the device. Therefore, different kinds of electrolytes and their suitability are discussed in chapter 6 and 7. The book concludes with a look at the potential applications of supercapattery, challenges and future prospective. This book is beneficial for research scientists, engineers and students who are interested in the latest developments and fundamentals of energy storage mechanism and clarifies the misleading concepts in this field. Presents the three classes of energy storage devices and clarifies the difference between between pseudocapacitor and battery grade material Covers the synthesis strategies to enhance the overall performance of the supercapacitor device (including power density) Explains the energy storage mechanism based on the fundamental concept of physics and electrochemistry

Electrolytes for Electrochemical Supercapacitors provides a state-of-the-art overview of the research and development of novel electrolytes and electrolyte configurations and systems to increase the energy density of electrochemical supercapacitors. Comprised of chapters written by leading international scientists active in supercapacitor research

The 21 chapters in this book presents a comprehensive overview of flexible supercapacitors using engineering nanoarchitectures mediated by functional nanomaterials and polymers as electrodes, electrolytes, and separators, etc. for advanced energy applications. The various aspects of flexible supercapacitors, including capacitor electrochemistry, evaluating parameters, operating conditions, characterization techniques, different types of electrodes, electrolytes, and flexible substrates are covered. This is probably the first book of its type which systematically describes the recent developments and progress in flexible supercapacitor technology, and will be very helpful for generating new and innovative ideas in the field of energy storage material for wearable/flexible industry applications.

This eBook is a collection of articles from a Frontiers Research Topic. Frontiers Research Topics are very popular trademarks of the Frontiers Journals Series: they are collections of at least ten articles, all centered on a particular subject. With their unique mix of varied contributions from Original Research to Review Articles, Frontiers Research Topics unify the most influential researchers, the latest key findings and historical advances in a hot research area! Find out more on how to host your own Frontiers Research Topic or contribute to one as an author by contacting the Frontiers Editorial Office: frontiersin.org/about/contact.

Supercapacitors can both hold large amounts of energy and charge up almost instantly. They have higher energy densities, higher efficiencies and longer lifetimes so can be used in a wide range of energy harvesting and storage systems including portable power and grid applications. Despite offering key performance advantages, many device components pose significant environmental hazards, often containing fluorine, sulfur and cyanide groups which are harmful when discarded. In recent years, there has been increasing research into more sustainable electrode materials for supercapacitor applications. In this book, readers are introduced to the extensive and ongoing research on the rationalization of low-carbon supercapacitor materials, their structures at varying scales and dimensions, the development of effective and low-cost synthesis techniques, design and architecture of green materials, as well as clarification of their electrochemical performance. It is an ideal book for researchers and industry professionals at the energy–environment nexus, searching for new advancements in supercapacitor science and technologies.

Supercapacitors: Materials, Design, and Commercialization provides a comprehensive overview of the latest research trends and opportunities in supercapacitors, and particularly in terms of novel materials and electrolytes.The book will address the transformation in supercapacitive technology from double layer capacitance to battery-type capacitance, providing a clear understanding of the conceptual differences between various charge storage processes for supercapacitors, charge storage based on materials and electrolytes, and calculation for capacitance for these charge processes. Detailed chapters discuss recent developments in materials, such as carbons, chalcogenides, MXene and phosphorene, various polymer nanocomposites, and polyoxometalates for supercapacitors. This is followed by in-depth coverage of electrolytes, including the evolution of electrolytes from aqueous to water-in-salt electrolytes and their role in improving the energy density of supercapacitors. The final part of the book examines the role of artificial intelligence in the design of supercapacitors, and latest developments in translating novel supercapacitor technologies from laboratory-scale research to a commercialization.This is a valuable resource for advanced students, researchers, and scientists in the fields of energy storage, electrical engineering, materials science, and chemical engineering, as well as engineers and R&D personnel working with supercapacitors or energy storage in an industrial setting. - Brings together the latest developments in supercapacitor materials and electrolytes - Discusses cutting-edge charge storage concepts and methods for supercapacitors - Addresses the role of machine learning and the scale-up from laboratory to commercialization