Solidification is one of the oldest processes for producing useful implements and remains one of the most important modern commercial processes. This text describes the fundamentals of the technology in a coherent way, using consistent notation.

Solidification and Crystallization Processing in Metals and Alloys Hasse Fredriksson KTH, Royal Institute of Technology, Stockholm, Sweden Ulla Åkerlind University of Stockholm, Sweden Solidification or crystallization occurs when atoms are transformed from the disordered liquid state to the more ordered solid state, and is fundamental to metals processing. Conceived as a companion volume to the earlier works, Materials Processing during Casting (2006) and Physics of Functional Materials (2008), this book analyzes solidification and crystallization processes in depth. Starting from the thermodynamic point of view, it gives a complete description, taking into account kinetics and mass transfer, down to the final structure. Importantly, the book shows the relationship between the theory and the experimental results. Topics covered include: Fundamentals of thermodynamics Properties of interfaces Nucleation Crystal growth - in vapours, liquids and melts Heat transport during solidification processes Solidification structures - faceted, dendritic, eutectic and peritectic Metallic glasses and amorphous alloy melts Solidification and Crystallization Processing in Metals and Alloys features many solved examples in the text, and exercises (with answers) for students. Intended for Masters and PhD students as well as researchers in Materials Science, Engineering, Chemistry and Metallurgy, it is also a valuable resource for engineers in industry.

“Principles of Solidification” offers comprehensive descriptions of liquid-to-solid transitions encountered in shaped casting, welding, and non-biological bulk crystal growth processes. The book logically develops through careful presentation of relevant thermodynamic and kinetic theories and models of solidification occurring in a variety of materials. Major topics encompass the liquid-state, liquid-solid transformations, chemical macro- and microsegregation, purification by fractional crystallization and zone refining, solid-liquid interfaces, polyphase freezing, and rapid solidification processing. Solid-liquid interfaces are discussed quantitatively both as sharp and diffuse entities, with supporting differential geometric descriptions. The book offers: • Detailed mathematical examples throughout to guide readers • Applications of solidification and crystal growth methodologies for preparation and purification of metals, ceramics, polymers and semiconductors • Appendices providing supporting information on special topics covered in the chapters. Readers in materials, metallurgical, chemical, and mechanical engineering will find this to be a useful source on the subjects of solidification and crystal growth. Chemists, physicists, and geologists concerned with melting/freezing phenomena will also find much of value in this book.

Solidification is one of the oldest processes for producing complex shapes for applications ranging from art to industry, and remains as one of the most important commercial processes for many materials. Since the 1980s, numerous fundamental developments in the understanding of solidification processes and microstructure formation have come from both analytical theories and the application of computational techniques using commonly available powerful computers. This book integrates these developments in a comprehensive volume that also presents and places them in the context of more classical theories. This second edition highlights the key concepts within each chapter to help guide the reader through the most important aspects of the topics. The figures are now in color, in order to improve the visualization of phenomena and concepts. Recent important developments in the field since the first edition was published have also been added. The three-part text is aimed at graduate and professional engineers. The first part, Fundamentals and Macroscale Phenomena, presents the thermodynamics of solutions and then builds on that subject to motivate and describe equilibrium phase diagrams. Transport phenomena are discussed next, focusing on the issues of most importance to liquid-solid phase transformations, then moving on to describing in detail both analytical and numerical approaches to solving such problems. The second part, Microstructure, employs these fundamental concepts for the treatment of nucleation, dendritic growth, microsegregation, eutectic and peritectic solidification, and microstructure competition. This part concludes with a chapter describing the coupling of macro- and microscopic phenomena in microstructure development. The third and final part describes various types of Defects that may occur, with emphasis on porosity, hot tearing and macrosegregation, presented using the modeling tools and microstructure descriptions developed earlier.

The processes of freezing and melting were present at the beginnings of the Earth and continue to dominate the natural and industrial worlds. The solidification of a liquid or the melting of a solid involves a complex interplay of many physical effects. This book systematically presents the field of continuum solidification theory based on instability phenomena. An understanding of the physics is developed by using examples of increasing complexity with the object of creating a deep physical insight applicable to more complex problems. Applied mathematicians, engineers, physicists, and materials scientists will all find this volume of interest.

Written by leading experts in their respective fields, Solidification and Casting provides a comprehensive review of topics fundamental to metallurgy and materials science as well as indicates recent trends. From an industrial perspective, the book begins with chapters on the casting techniques most commonly used in industry today. It then d

This volume details the principles underlying rapid solidification processing, material structure and properties, and their applications. This practical resource presents a manifold approach to both amorphous and crystalline rapidly solidified metallic alloys.;Written by over 30 internationally acclaimed specialists in their respective fields, Rapidly Solidified Alloys: surveys nucleation and growth studies in undercooled melts; examines various processes for the production of rapidly solidified alloys; discusses the compaction of amorphous alloys; describes surface remelting treatments for the rapid solidification of surface layers and the resultant improved workpiece properties; covers the closely related topics of structural relaxation, atomic transport and other thermally induced processes; demonstrates microstructure-property relationships in rapidly quenched crystalline alloy systems and their beneficial effects in applications; and elucidates the basic, engineeering, and applications-oriented magnetic properties of amorphous alloys.;Furnishing more than 2300 literature citations for further study of specific subjects, Rapidly Solidified Alloys is intended for materials, mechanical, product, and civil engineers; metallurgists; magneticians; physicists; physical chemists; and graduate students in these disciplines.

Directional Solidification of Steel Castings summarizes the results of a large number of investigations, mostly scientific in character, on the directional solidification of steel castings. The influence of design on the technical possibilities of producing casting in the foundry is examined. Diagrams, simple basic rules, and formulae are provided, along with many practical examples. This book is comprised of 16 chapters and begins with an introduction to the technical and psychological aspects of steel casting before turning to a discussion of the influence of shape and dimensions on the time it takes for castings to solidify. The thermal gradient, feeder heads, and cavities in steel castings are then considered. In particular, the effect of the thermal gradient on solidification and feeding range are examined. Methods for increasing the thermal gradient in the casting are described, including the use of mold heating pads, breaker cores or Washburn cores; external cooling (iron chills); cooling fins; internal chills; and exothermic pads. Cavities in steel castings which are commonly mistaken for true shrinkage cavities are also analyzed. This monograph is particularly suitable for foundry managers, foremen, technicians, casting designers, and students.

The progress of civilization can be, in part, attributed to their ability to employ metallurgy. This book is an introduction to multiple facets of physical metallurgy, materials science, and engineering. As all metals are crystalline in structure, it focuses attention on these structures and how the formation of these crystals are responsible for certain aspects of the material's chemical and physical behaviour. Concepts in Physical Metallurgy also discusses the mechanical properties of metals, the theory of alloys, and physical metallurgy of ferrous and non-ferrous alloys.

This monograph comprehensively describes phenomena of heat flow during phase change as well as the dynamics of liquid solidification, i.e. the development of a solidified layer. The book provides the reader with basic knowledge for practical designs, as well as with equations which describe processes of energy transformation. The target audience primarily comprises researchers and experts in the field of heat flow, but the book may also be beneficial for both practicing engineers and graduate students.