Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing presents the physical and chemical principles of the sol-gel process. The book emphasizes the science behind sol-gel processing with a chapter devoted to applications. The first chapter introduces basic terminology, provides a brief historical sketch, and identifies some excellent texts for background reading. Chapters 2 and 3 discuss the mechanisms of hydrolysis and condensation for nonsilicate and silicate systems. Chapter 4 deals with stabilization and gelation of sols. Chapter 5 reviews theories of gelation and examines the predicted and observed changes in the properties of a sol in the vicinity of the gel point. Chapter 6 describes the changes in structure and properties that occur during aging of a gel in its pore liquor (or some other liquid). The discussion of drying is divided into two parts, with the theory concentrated in Chapter 7 and the phenomenology in Chapter 8. The structure of dried gels is explored in Chapter 9. Chapter 10 shows the possibility of using the gel as a substrate for chemical reactions or of modifying the bulk composition of the resulting ceramic by performing a surface reaction (such as nitridation) on the gel. Chapter 11 reviews the theory and practice of sintering, describing the mechanisms that govern densification of amorphous and crystalline materials, and showing the advantages of avoiding crystallization before sintering is complete. The properties of gel-derived and conventional ceramics are discussed in Chapter 12. The preparation of films is such an important aspect of sol-gel technology that the fundamentals of film formation are treated at length in Chapter 13. Films and other applications are briefly reviewed in Chapter 14. Materials scientists and researchers in the field of sol-gel processing will find the book invaluable.

Sol-Gel Science and Technology covers optical, electronic and magnetic, chemical, mechanical, biomedical and biotechnological materials. Concerning the microstructures, the sol-gel method applies to porous materials, dense materials like glasses and ceramics, organic-inorganic hybrids and nanocomposites. The four volumes of this reference treat four areas that are timely, important and seeing great research activity: -Sol-gel prepared ferroelectrics and related materials. -Sol-gel processing of titanium oxides: photocatalyst and other applications. -Sol-gel prepared organic-inorganic hybrids and nanocomposites. -Sol-gel processing of porous materials: application to catalysts, enzymes, chemical analysis, sensors, and membranes. The goal of these four volumes is to disseminate the recent research results published in recent issues of Journal of Sol-Gel Science and Technology, which is a unique journal devoted to Sol-Gel.

Emerging Fields in Sol-gel Science and Technology contains selected papers from the symposium on "Sol-Gel and Vitreous Materials and Applications" held during the International Materials Research Congress in Cancún, México in August 2002. One hundred and twenty researchers representing 10 countries attended this symposium. Some of the subjects covered in this symposium include 1.) synthesis of new materials endowed with outstanding and non-conventional optical, magnetic, electrical, thermal, catalytic, and mechanical properties; 2.) study of the sorption properties of model porous materials in order to test the validity of previous and recent theories; 3.) theoretical studies related to density functional theory, fractal and scaling law approaches, 4.) synthesis of biomaterials for use in medicine and pollution control; 5.) application of sol-gel colloids in the fine-chemistry industry in products such as fragrances and pharmaceuticals; 6.) development of special vitreous materials; 7.) implementation of inorganic thin films, and 8.) synthesis of materials for energy saving.

Sol-Gel Techniques for Glass Producers and Users provides technological information, descriptions and characterizations of prototypes, or products already on the market, and illustrates advantages and disadvantages of the sol-gel process in comparison to other methods. The first chapter entitled "Wet Chemical Technology" gives a summary of the basic principles of the sol-gel chemistry. The most promising applications are related to coatings. Chapter 2 describes the various "Wet Chemical Coating Technologies" from glass cleaning to many deposition and post-coating treatment techniques. These include patterning of coatings through direct or indirect techniques which have became very important and for which the sol-gel processing is particularly well adapted. Chapter 3 entitled "Bulk Glass Technologies" reports on the preparation of special glasses for different applications. Chapter 4 entitled "Coatings and Materials Properties" describes the properties of the different coatings and the sol-gel materials, fibers and powders. The chapter also includes a section dedicated to the characterization techniques especially applied to sol-gel coatings and products.

This book presents a broad, general introduction to the processing of Sol-Gel technologies. This updated volume serves as a general handbook for researchers and students entering the field. This new edition provides updates in fields that have undergone rapid developments, such as Ceramics, Catalysis, Chromatropgraphy, biomaterials, glass science, and optics. It provides a simple, compact resource that can also be used in graduate-level materials science courses.

Sol--Gel--Optics encompasses numerous schemes for fabricating optical materials from gels -- materials such as bulk optics, optical waveguides, doped oxides for laser and nonlinear optics, gradient refractive index (GRIN) optics, chemical sensors, environmental sensors, and `smart' windows. Sol--Gel--Optics: Processing and Applications provides in-depth coverage of the synthesis and fabrication of these materials and discusses the optics related to microporous, amorphous, crystalline and composite materials. The reader will also find in this book detailed descriptions of new developments in silica optics, bulk optics, waveguides and thin films. Various applications to sensor and device technology are highlighted. For researchers and students looking for novel optical materials, processing methods or device ideas, Sol--Gel--Optics: Processing and Applications surveys a wide array of promising new avenues for further investigation and for innovative applications. (This book is the first in a new subseries entitled `Electronic Materials: Science and Technology).

This comprehensive three-volume handbook brings together a review of the current state together with the latest developments in sol-gel technology to put forward new ideas. The first volume, dedicated to synthesis and shaping, gives an in-depth overview of the wet-chemical processes that constitute the core of the sol-gel method and presents the various pathways for the successful synthesis of inorganic and hybrid organic-inorganic materials, bio- and bio-inspired materials, powders, particles and fibers as well as sol-gel derived thin films, coatings and surfaces. The second volume deals with the mechanical, optical, electrical and magnetic properties of sol-gel derived materials and the methods for their characterization such as diffraction methods and nuclear magnetic resonance, infrared and Raman spectroscopies. The third volume concentrates on the various applications in the fields of membrane science, catalysis, energy research, biomaterials science, biomedicine, photonics and electronics.

A unique perspective of twentieth century research and development in materials science. It summarizes the fifteen years of sol-gel silica processing research leading to the commercial development of bioactive gel-glasses for medical applications. It demonstrates the combined use of quantum mechanical molecular modeling and spectroscopy to solve environmental stability problems. A final chapter addresses the topic of Technology Transfer - how to transfer technology from the laboratory to a profitable commercial enterprise using examples from various chapters in the book.

Sol-gel processing is a soft-chemistry method to obtain functional materials at low temperatures. This route can be used to produce very sophisticated nanomaterials and to tailor the materials to very specific applications. Adsorption and detection of pollutants, water purification and soil remediation represent challenging fields of application that can be exploited by sol-gel materials. In this volume several contributions from invited speakers and participants at the NATO advanced research workshop on "Sol-gel approaches to materials for pollution control, water purification and soil remediation", which has been held in Kiev, Ukraine on October 2007, are reported. The book offers a wide and updated overview of the most advanced sol-gel methods for materials processing and at the same time presents several case studies concerning possible solutions for environmental issues. General articles on sol-gel from the invited speakers and focused research articles allow getting inside sol-gel applications on this very important field.

Sol-Gel processing methods, first used historically for decorative and constructional materials, were extensively developed in the last century for applications such as glasses, ceramics, catalysts, coatings, composites and fibres. Today they are reaching their full potential, enabling the preparation of new generations of advanced materials not easily accessible by other methods yet using mild, low-energy conditions. The topic is therefore increasingly included in advanced undergraduate, MSc and PhD programmes in the areas of chemistry, physics and materials science. This concise introductory text, written at the advanced undergraduate/first-year postgraduate level, is also suitable as an introduction to the development, mechanisms, chemistry, characterisation methods and applications of the technique. It provides readers with an extensive yet concise grounding in the theory of each area of the subject and details the real and potential applications and the future prospects of sol-gel chemistry.