This study has developed a complete procedure for the measurement of oxygen isotopes in arsenic oxyanions in natural waters by using different adsorbents. The experimental results of kinetic exchange of oxygen between AsO43- and water show that the entire exchange procedure happens in a very short time at different pH conditions and temperatures.

Selenium (Se), being an essential nutrient and a toxin, enters the food chain mainly via plants. Selenium isotope signatures were proved to be an excellent redox tracer, making it a promising tool for the exploration of the Se cycle in plants. The analytical method is sensitive on organic samples and requires particular preparation methods, which were developed and validated in this study. Plant cultivation setups revealed the applicability of these methods to trace plant internal processes.

The aim of this study was to describe and quantify Se transfer at the interface between soil and plant. For this purpose, three Se reservoirs were defined: soil, soil solution and plant, represented by kaolinite or goethite, nutrient solution and rice. First, Se transfer from solution to plant and Se partitioning in the plant was studied; then adsorption-desorption processes of Se onto kaolinite and goethite were investigated. Finally, a mass balance of the combined experiment was modelled.

V.3 ... consists of individual chapters that describe 1) the conceptual background for radionuclides, including tritium, radon, strontium, technetium, uranium, iodine, radium, thorium, cesium, plutonium-americium and 2) data requirements to be met during site characterization.

This book consolidates much of what is known about the geochemistry of arsenic and provides new information on relationships between high concentrations of arsenic in ground water and geochemical environments. The subject matter of this book ranges in scope from molecular-scale geochemical processes that affect the mobility of arsenic in ground water, to arsenic contaminated ground water at the national scale. Chapters were contributed by an international group of research scientists from a broad range of backgrounds.

This third edition of the book has been completely re-written, providing a wider scope and enhanced coverage. It covers the general principles of the natural occurrence, pollution sources, chemical analysis, soil chemical behaviour and soil-plant-animal relationships of heavy metals and metalloids, followed by a detailed coverage of 21 individual elements, including: antimony, arsenic, barium, cadmium, chromium, cobalt, copper, gold, lead, manganese, mercury, molybdenum, nickel, selenium, silver, thallium, tin, tungsten, uranium, vanadium and zinc. The book is highly relevant for those involved in environmental science, soil science, geochemistry, agronomy, environmental health, and environmental engineering, including specialists responsible for the management and clean-up of contaminated land.

Arsenic in drinking water derived from groundwater is arguably the biggest environmental chemical human health risk known at the present time, with well over 100,000,000 people around the world being exposed. Monitoring the hazard, assessing exposure and health risks and implementing effective remediation are therefore key tasks for organisations and individuals with responsibilities related to the supply of safe, clean drinking water. Best Practice Guide on the Control of Arsenic in Drinking Water, covering aspects of hazard distribution, exposure, health impacts, biomonitoring and remediation, including social and economic issues, is therefore a very timely contribution to disseminating useful knowledge in this area. The volume contains 10 short reviews of key aspects of this issue, supplemented by a further 14 case studies, each of which focusses on a particular area or technological or other practice, and written by leading experts in the field. Detailed selective reference lists provide pointers to more detailed guidance on relevant practice. The volume includes coverage of (i) arsenic hazard in groundwater and exposure routes to humans, including case studies in USA, SE Asia and UK; (ii) health impacts arising from exposure to arsenic in drinking water and biomonitoring approaches; (iii) developments in the nature of regulation of arsenic in drinking water; (iv) sampling and monitoring of arsenic, including novel methodologies; (v) approaches to remediation, particularly in the context of water safety planning, and including case studies from the USA, Italy, Poland and Bangladesh; and (vi) socio-economic aspects of remediation, including non-market valuation methods and local community engagement.