This volume is concerned with a detailed description of the canonical operator method - one of the asymptotic methods of linear mathematical physics. The book is, in fact, an extension and continuation of the authors' works [59], [60], [65]. The basic ideas are summarized in the Introduction. The book consists of two parts. In the first, the theory of the canonical operator is develop ed, whereas, in the second, many applications of the canonical operator method to concrete problems of mathematical physics are presented. The authors are pleased to express their deep gratitude to S. M. Tsidilin for his valuable comments. THE AUTHORS IX INTRODUCTION 1. Various problems of mathematical and theoretical physics involve partial differential equations with a small parameter at the highest derivative terms. For constructing approximate solutions of these equations, asymptotic methods have long been used. In recent decades there has been a renaissance period of the asymptotic methods of linear mathematical physics. The range of their applicability has expanded: the asymptotic methods have been not only continuously used in traditional branches of mathematical physics but also have had an essential impact on the development of the general theory of partial differential equations. It appeared recently that there is a unified approach to a number of problems which, at first sight, looked rather unrelated.

This book presents the basic methods and applications in semiclassical approximation in the light of developments.

This volume deals with those topics of mathematical physics, associated with the study of the Schrödinger equation, which are considered to be the most important. Chapter 1 presents the basic concepts of quantum mechanics. Chapter 2 provides an introduction to the spectral theory of the one-dimensional Schrödinger equation. Chapter 3 opens with a discussion of the spectral theory of the multi-dimensional Schrödinger equation, which is a far more complex case and requires careful consideration of aspects which are trivial in the one-dimensional case. Chapter 4 presents the scattering theory for the multi-dimensional non-relativistic Schrödinger equation, and the final chapter is devoted to quantization and Feynman path integrals. These five main chapters are followed by three supplements, which present material drawn on in the various chapters. The first two supplements deal with general questions concerning the spectral theory of operators in Hilbert space, and necessary information relating to Sobolev spaces and elliptic equations. Supplement 3, which essentially stands alone, introduces the concept of the supermanifold which leads to a more natural treatment of quantization. Although written primarily for mathematicians who wish to gain a better awareness of the physical aspects of quantum mechanics and related topics, it will also be useful for mathematical physicists who wish to become better acquainted with the mathematical formalism of quantum mechanics. Much of the material included here has been based on lectures given by the authors at Moscow State University, and this volume can also be recommended as a supplementary graduate level introduction to the spectral theory of differential operators with both discrete and continuous spectra. This English edition is a revised, expanded version of the original Soviet publication.

It is a surprising fact that so far almost no books have been published on KAM theory. The first part of this book seems to be the first monographic exposition of this subject, despite the fact that the discussion of KAM theory started as early as 1954 (Kolmogorov) and was developed later in 1962 by Arnold and Moser. Today, this mathematical field is very popular and well known among physicists and mathematicians. In the first part of this Ergebnisse-Bericht, Lazutkin succeeds in giving a complete and self-contained exposition of the subject, including a part on Hamiltonian dynamics. The main results concern the existence and persistence of KAM theory, their smooth dependence on the frequency, and the estimate of the measure of the set filled by KAM theory. The second part is devoted to the construction of the semiclassical asymptotics to the eigenfunctions of the generalized Schrödinger operator. The main result is the asymptotic formulae for eigenfunctions and eigenvalues, using Maslov`s operator, for the set of eigenvalues of positive density in the set of all eigenvalues. An addendum by Prof. A.I. Shnirelman treats eigenfunctions corresponding to the "chaotic component" of the phase space.

This book represents the first asymptotic analysis, via completely integrable techniques, of the initial value problem for the focusing nonlinear Schrödinger equation in the semiclassical asymptotic regime. This problem is a key model in nonlinear optical physics and has increasingly important applications in the telecommunications industry. The authors exploit complete integrability to establish pointwise asymptotics for this problem's solution in the semiclassical regime and explicit integration for the underlying nonlinear, elliptic, partial differential equations suspected of governing the semiclassical behavior. In doing so they also aim to explain the observed gradient catastrophe for the underlying nonlinear elliptic partial differential equations, and to set forth a detailed, pointwise asymptotic description of the violent oscillations that emerge following the gradient catastrophe. To achieve this, the authors have extended the reach of two powerful analytical techniques that have arisen through the asymptotic analysis of integrable systems: the Lax-Levermore-Venakides variational approach to singular limits in integrable systems, and Deift and Zhou's nonlinear Steepest-Descent/Stationary Phase method for the analysis of Riemann-Hilbert problems. In particular, they introduce a systematic procedure for handling certain Riemann-Hilbert problems with poles accumulating on curves in the plane. This book, which includes an appendix on the use of the Fredholm theory for Riemann-Hilbert problems in the Hölder class, is intended for researchers and graduate students of applied mathematics and analysis, especially those with an interest in integrable systems, nonlinear waves, or complex analysis.

This book presents the techniques used in the microlocal treatment of semiclassical problems coming from quantum physics in a pedagogical, way and is mainly addressed to non-specialists in the subject. It is based on lectures taught by the author over several years, and includes many exercises providing outlines of useful applications of the semi-classical theory.

An introduction to the rapidly evolving methodology of electronic excited states For academic researchers, postdocs, graduate and undergraduate students, Quantum Chemistry and Dynamics of Excited States: Methods and Applications reports the most updated and accurate theoretical techniques to treat electronic excited states. From methods to deal with stationary calculations through time-dependent simulations of molecular systems, this book serves as a guide for beginners in the field and knowledge seekers alike. Taking into account the most recent theory developments and representative applications, it also covers the often-overlooked gap between theoretical and computational chemistry. An excellent reference for both researchers and students, Excited States provides essential knowledge on quantum chemistry, an in-depth overview of the latest developments, and theoretical techniques around the properties and nonadiabatic dynamics of chemical systems. Readers will learn: ● Essential theoretical techniques to describe the properties and dynamics of chemical systems ● Electronic Structure methods for stationary calculations ● Methods for electronic excited states from both a quantum chemical and time-dependent point of view ● A breakdown of the most recent developments in the past 30 years For those searching for a better understanding of excited states as they relate to chemistry, biochemistry, industrial chemistry, and beyond, Quantum Chemistry and Dynamics of Excited States provides a solid education in the necessary foundations and important theories of excited states in photochemistry and ultrafast phenomena.

"...A graduate level text introducing readers to semiclassical and microlocal methods in PDE." -- from xi.

International Series in Natural Philosophy, Volume 30: Problems in Quantum Mechanics focuses on the processes, principles, reactions, and methodologies involved in quantum mechanics. The publication first elaborates on the mathematical formalism of quantum mechanics, simple quantum systems, and mean values and uncertainty relations. Discussions focus on mean values of dynamical variables, uncertainty relations, eigenfunctions and the energy spectrum, motion in a central field, matrix representation of vectors and operators, Hubert spaces, and operators in Hilbert space. The text then takes a look at mean values and uncertainty relations, semi-classical approximation, and pictures and representations. The book takes a look at orbital angular momentum and spin, systems of identical particles, and perturbation theory. Topics include variational method, stationary state perturbation theory, isotopic spin, second quantization, properties of angular momentum operators, and angular momentum and rotations of coordinate axes. The manuscript also ponders on functions used in quantum mechanics, relativistic quantum mechanics, and radiation theory. The publication is a dependable reference for researchers interested in quantum mechanics.

A graduate-level text that examines the semiclassical approach to quantum mechanics Physical systems have been traditionally described in terms of either classical or quantum mechanics. But in recent years, semiclassical methods have developed rapidly, providing deep physical insight and computational tools for quantum dynamics and spectroscopy. In this book, Eric Heller introduces and develops this subject, demonstrating its power with many examples. In the first half of the book, Heller covers relevant aspects of classical mechanics, building from them the semiclassical way through the semiclassical limit of the Feynman path integral. The second half of the book applies this approach to various kinds of spectroscopy, such as molecular spectroscopy and electron imaging and quantum dynamical systems with an emphasis on tunneling. Adopting a distinctly time-dependent viewpoint, Heller argues for semiclassical theories from experimental and theoretical vantage points valuable to research in physics and chemistry. Featuring more than two hundred figures, the book provides a geometric, phase-space, and coordinate-space pathway to greater understanding. Filled with practical examples and applications, The Semiclassical Way to Dynamics and Spectroscopy is a comprehensive presentation of the tools necessary to successfully delve into this unique area of quantum mechanics. A comprehensive approach for using classical mechanics to do quantum mechanics More than two hundred figures to assist intuition Emphasis on semiclassical Green function and wave packet perspective, as well as tunneling and spectroscopy Chapters include quantum mechanics of classically chaotic systems, quantum scarring, and other modern dynamical topics