Role of Strongly Interacting Additives in Tuning the Structure and Properties of Polymer Systems

Role of Strongly Interacting Additives in Tuning the Structure and Properties of Polymer Systems
Author :
Publisher :
Total Pages : 174
Release :
ISBN-10 : OCLC:785407382
ISBN-13 :
Rating : 4/5 (82 Downloads)

Synopsis Role of Strongly Interacting Additives in Tuning the Structure and Properties of Polymer Systems by : Vikram Kumar Daga

Block copolymer (BCP) nanocomposites are an important class of hybrid materials in which the BCP guides the spatial location and the periodic assembly of the additives. High loadings of well-dispersed nanofillers are generally important for many applications including mechanical reinforcing of polymers. In particular the composites shown in this work might find use as etch masks in nanolithography, or for enabling various phase selective reactions for new materials development. This work explores the use of hydrogen bonding interactions between various additives (such as homopolymers and non-polymeric additives) and small, disordered BCPs to cause the formation of well-ordered morphologies with small domains. A detailed study of the organization of homopolymer chains and the evolution of structure during the process of ordering is performed. The results demonstrate that by tuning the selective interaction of the additive with the incorporating phase of the BCP, composites with significantly high loadings of additives can be formed while maintaining order in the BCP morphology. The possibility of high and selective loading of additives in one of the phases of the ordered BCP composite opens new avenues due to high degree of functionalization and the proximity of the additives within the incorporating phase. This aspect is utilized in one case for the formation of a network structure between adjoining additive cores to derive mesoporous inorganic materials with their structures templated by the BCP. The concept of additive-driven assembly is extended to formulate BCP-additive blends with an ability to undergo photo-induced ordering. Underlying this strategy is the ability to transition a weakly interacting additive to its strongly interacting form. This strategy provides an on-demand, non-intrusive route for formation of well-ordered nanostructures in arbitrarily defined regions of an otherwise disordered material. The second area explored in this dissertation deals with the incorporation of additives into photoresists for next generation extreme ultra violet (EUV) photolithography applications. The concept of hydrogen bonding between the additives and the polymeric photoresist was utilized to cause formation of a physical network that is expected to slow down the diffusion of photoacid leading to better photolithographic performance (25-30 nm resolution obtained).

Polymer Science: A Comprehensive Reference

Polymer Science: A Comprehensive Reference
Author :
Publisher : Newnes
Total Pages : 7752
Release :
ISBN-10 : 9780080878621
ISBN-13 : 0080878628
Rating : 4/5 (21 Downloads)

Synopsis Polymer Science: A Comprehensive Reference by :

The progress in polymer science is revealed in the chapters of Polymer Science: A Comprehensive Reference, Ten Volume Set. In Volume 1, this is reflected in the improved understanding of the properties of polymers in solution, in bulk and in confined situations such as in thin films. Volume 2 addresses new characterization techniques, such as high resolution optical microscopy, scanning probe microscopy and other procedures for surface and interface characterization. Volume 3 presents the great progress achieved in precise synthetic polymerization techniques for vinyl monomers to control macromolecular architecture: the development of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization procedures, and atom transfer radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain transfer systems as the most often used controlled/living radical polymerization methods. Volume 4 is devoted to kinetics, mechanisms and applications of ring opening polymerization of heterocyclic monomers and cycloolefins (ROMP), as well as to various less common polymerization techniques. Polycondensation and non-chain polymerizations, including dendrimer synthesis and various "click" procedures, are covered in Volume 5. Volume 6 focuses on several aspects of controlled macromolecular architectures and soft nano-objects including hybrids and bioconjugates. Many of the achievements would have not been possible without new characterization techniques like AFM that allowed direct imaging of single molecules and nano-objects with a precision available only recently. An entirely new aspect in polymer science is based on the combination of bottom-up methods such as polymer synthesis and molecularly programmed self-assembly with top-down structuring such as lithography and surface templating, as presented in Volume 7. It encompasses polymer and nanoparticle assembly in bulk and under confined conditions or influenced by an external field, including thin films, inorganic-organic hybrids, or nanofibers. Volume 8 expands these concepts focusing on applications in advanced technologies, e.g. in electronic industry and centers on combination with top down approach and functional properties like conductivity. Another type of functionality that is of rapidly increasing importance in polymer science is introduced in volume 9. It deals with various aspects of polymers in biology and medicine, including the response of living cells and tissue to the contact with biofunctional particles and surfaces. The last volume is devoted to the scope and potential provided by environmentally benign and green polymers, as well as energy-related polymers. They discuss new technologies needed for a sustainable economy in our world of limited resources. Provides broad and in-depth coverage of all aspects of polymer science from synthesis/polymerization, properties, and characterization methods and techniques to nanostructures, sustainability and energy, and biomedical uses of polymers Provides a definitive source for those entering or researching in this area by integrating the multidisciplinary aspects of the science into one unique, up-to-date reference work Electronic version has complete cross-referencing and multi-media components Volume editors are world experts in their field (including a Nobel Prize winner)

Ionomers

Ionomers
Author :
Publisher : Springer Science & Business Media
Total Pages : 524
Release :
ISBN-10 : 9789400914612
ISBN-13 : 940091461X
Rating : 4/5 (12 Downloads)

Synopsis Ionomers by : M.R. Tant

Polymers have achieved an enviable position as the class of materials having the highest volume of production, exceeding that of both metals and ceramics. The meteoric rise in the production and utilization of polymers has been due to advances in polymer synthesis which allow the creation of specific and well-defined molecular structures, to new knowledge concerning the relationships between polymer structure and properties, and to an improved understanding of how processing can be used as a tool to develop morphological features which result in desired properties. Polymers have truly become 'engineered materials' in every sense of the term. Polymer scientists and engineers are forever seeking to modify and improve the properties of synthetic polymeric systems for use in specific applications. Towards this end they have often looked to nature for advice on how to design molecules for specific needs. An excellent illustration of this is the use of noncovalent bonding (ionic, hydrogen, and van der Waals) in lipids, proteins, and nucleic acids, where these noncovalent bonds, acting both intra and intermolecularly, precisely control the structure and thus the function of the entire system. The utilization of ionic bonding, in particular in man-made polymers has attracted widespread interest in recent years, since ionic interactions exert a similar strong influence on the structure and properties of these synthetic systems.

Ullmann's Polymers and Plastics

Ullmann's Polymers and Plastics
Author :
Publisher : John Wiley & Sons
Total Pages : 1934
Release :
ISBN-10 : 9783527685950
ISBN-13 : 3527685952
Rating : 4/5 (50 Downloads)

Synopsis Ullmann's Polymers and Plastics by : Wiley-VCH

Your personal Ullmann's: Chemical and physical characteristics, production processes and production figures, main applications, toxicology and safety information are all to be found here in one single resource - bringing the vast knowledge of the Ullmann's Encyclopedia to the desks of industrial chemists and chemical engineers. The ULLMANN’S perspective on polymers and plastics brings reliable information on more than 1500 compounds and products straight to your desktop Carefully selected “best of” compilation of 61 topical articles from the Encyclopedia of Industrial Chemistry on economically important polymers provide a wealth of chemical, physical and economic data on more than 1000 different polymers and hundreds of modifications Contains a wealth of information on the production and use of all industrially relevant polymers and plastics, including organic and inorganic polymers, fibers, foams and resins Extensively updated: more than 30% of the content has been added or updated since the launch of the 7th edition of the Ullmann’s encyclopedia in 2011 and is now available in print for the first time 4 Volumes

Hydrogen Bonded Polymers

Hydrogen Bonded Polymers
Author :
Publisher : Springer Science & Business Media
Total Pages : 215
Release :
ISBN-10 : 9783540685876
ISBN-13 : 3540685871
Rating : 4/5 (76 Downloads)

Synopsis Hydrogen Bonded Polymers by : Wolfgang Binder

Control of polymeric structure is among the most important endeavours of modern macromolecular science. In particular, tailoring the positioning and strength of intermolecular forces within macromolecules by synthetic methods and thus gaining structural control over the final polymeric materials has become feasible, resulting in the field of supramolecular polymer science. Besides other intermolecular forces, hydrogen bonds are unique intermolecular forces enabling the tuning of material properties via self-assembly processes over a wide range of interactions strength ranging from several kJmol to several tens of kJmol . Central for the formation of these structures are precursor molecules of small molecular weight (usually lower than 10 000), which can assemble in solid or solution to aggregates of defined geometry.

Chemical Abstracts

Chemical Abstracts
Author :
Publisher :
Total Pages : 2710
Release :
ISBN-10 : UOM:39015057324306
ISBN-13 :
Rating : 4/5 (06 Downloads)

Synopsis Chemical Abstracts by :

Additive Manufacturing for Polymers

Additive Manufacturing for Polymers
Author :
Publisher : Frontiers Media SA
Total Pages : 94
Release :
ISBN-10 : 9782832528334
ISBN-13 : 2832528333
Rating : 4/5 (34 Downloads)

Synopsis Additive Manufacturing for Polymers by : Jianlei Wang

3D printing, also known as additive manufacturing, is a manufacturing process that connects materials layer by layer to produce a solid object based on networked digital model files. Advantages of 3D printing over traditional manufacturing include less material consumption, lower costs, faster production process, customizable degrees of freedom and complexity of geometric shapes. The traditional manufacturing of a functional structural part often requires multiple independent process steps, while 3D printing can fabricate the same part in one step, enabling small batch production and customization of personalized products. Due to the diversity of materials available, 3D printing for polymer can be used to create lightweight complex structures in aerospace, models of architectural structures, art reproductions, and biological tissues and organs.

Smart Composite Coatings and Membranes

Smart Composite Coatings and Membranes
Author :
Publisher : Elsevier
Total Pages : 491
Release :
ISBN-10 : 9781782422952
ISBN-13 : 1782422951
Rating : 4/5 (52 Downloads)

Synopsis Smart Composite Coatings and Membranes by : Maria Fatima Montemor

Smart Composite Coatings and Membranes: Transport, Structural, Environmental and Energy Applications provides the latest information on the increase in demand for new smart materials for a wide array of different technological applications. The book comprehensively reviews the latest developments in smart composite materials used as membranes, barriers, and coatings, with a special focus on corrosion protection, transportation, structure, and the wide range of applications. Part one examines the properties, processing, and manufacture of smart composite materials, along with techniques for modeling the behavior of these materials, while other sections review the use of smart composite coatings in aerospace, marine, and metal structural applications, examine the protective properties and applications of smart composite coatings, and introduce specific low environmental impact and energy efficient applications, such as energy generation and storage, water management, and stone conservation. - Explores the use of smart composite materials for coatings, barriers and membranes - Comprehensively reviews the latest developments in smart composite materials, with a special focus on corrosion protection, transportation, structure, and the wide range of applications - Examines the properties, processing, manufacture and behavior modeling of smart composite materials - Focuses on applications that have an impact on more effective energy savings and efficiency, green-house emissions, and environmental protection