Treatise on Materials Science and Technology, Volume 10: Properties of Solid Polymeric Materials, Part A covers knowledge in the critical areas of polymeric materials. The book provides a background in polymer structure and morphogenesis, and discusses rubberlike elasticity, a phenomenon thermodynamically unique to long-chain polymers. The text also describes the mechanics of anisotropie, oriented polymeric systems and of glassy polymers. The fatigue behavior in solid polymers and the electrical properties of solid polymers are also reviewed. The book further tackles the electron processes and electrical breakdown in polymers. The text concludes with a discussion of the role of the environment on the integrity of polymeric solids. Materials scientists, materials engineers, and graduate students taking related courses will find the book useful.

Provides a comprehensive introduction to the mechanical behaviour of solid polymers. Extensively revised and updated throughout, the second edition now includes new material on mechanical relaxations and anisotropy, composites modelling, non-linear viscoelasticity, yield behaviour and fracture of tough polymers. The accessible approach of the book has been retained with each chapter designed to be self contained and the theory and applications of the subject carefully introduced where appropriate. The latest developments in the field are included alongside worked examples, mathematical appendices and an extensive reference. Fully revised and updated throughout to include all the latest developments in the field Worked examples at the end of the chapter An invaluable resource for students of materials science, chemistry, physics or engineering studying polymer science

A concise, self-contained introduction to solid polymers, the mechanics of their behavior and molecular and structural interpretations. This updated edition provides extended coverage of recent developments in rubber elasticity, relaxation transitions, non-linear viscoelastic behavior, anisotropic mechanical behavior, yield behavior of polymers, breaking phenomena, and other fields.

Treatise on Materials Science and Technology, Volume 10: Properties of Solid Polymeric Materials, Part B covers knowledge in critical areas of polymeric materials. The book discusses the anisotropie elastic behavior of crystalline polymers; the mechanical properties of glassy polymers; and the fatigue behavior of engineering polymers. The text also describes the electronic properties of polymers; electric breakdown in polymers; and environmental degradation. People working in some area of polymer materials science will find the book useful.

Providing an updated and comprehensive account of the properties of solid polymers, the book covers all aspects of mechanical behaviour. This includes finite elastic behavior, linear viscoelasticity and mechanical relaxations, mechanical anisotropy, non-linear viscoelasicity, yield behavior and fracture. New to this edition is coverage of polymer nanocomposites, and molecular interpretations of yield, e.g. Bowden, Young, and Argon. The book begins by focusing on the structure of polymers, including their chemical composition and physical structure. It goes on to discuss the mechanical properties and behaviour of polymers, the statistical molecular theories of the rubber-like state and describes aspects of linear viscoelastic behaviour, its measurement, and experimental studies. Later chapters cover composites and experimental behaviour, relaxation transitions, stress and yielding. The book concludes with a discussion of breaking phenomena.

This volume explores the mechanics of the behaviour of solid polymers, discussing molecular and structural interpretations and emphasizing the physical rather than the engineering approach. Readers are provided with a set of elementary problems and their solutions.

Providing an updated and comprehensive account of the propertiesof solid polymers, the book covers all aspects of mechanicalbehaviour. This includes finite elastic behavior, linearviscoelasticity and mechanical relaxations, mechanical anisotropy,non-linear viscoelasicity, yield behavior and fracture. New to thisedition is coverage of polymer nanocomposites, and molecularinterpretations of yield, e.g. Bowden, Young, and Argon. The book begins by focusing on the structure of polymers,including their chemical composition and physical structure. It goes on to discuss the mechanical properties and behaviour ofpolymers, the statistical molecular theories of the rubber-likestate and describes aspects of linear viscoelastic behaviour, itsmeasurement, and experimental studies. Later chapters cover composites and experimental behaviour,relaxation transitions, stress and yielding. The book concludeswith a discussion of breaking phenomena.

Properties of Polymers: Their Correlation with Chemical Structure; Their Numerical Estimation and Prediction from Additive Group Contributions summarizes the latest developments regarding polymers, their properties in relation to chemical structure, and methods for estimating and predicting numerical properties from chemical structure. In particular, it examines polymer electrical properties, magnetic properties, and mechanical properties, as well as their crystallization and environmental behavior and failure. The rheological properties of polymer melts and polymer solutions are also considered. Organized into seven parts encompassing 27 chapters, this book begins with an overview of polymer science and engineering, including the typology of polymers and their properties. It then turns to a discussion of thermophysical properties, from transition temperatures to volumetric and calorimetric properties, along with the cohesive aspects and conformation statistics. It also introduces the reader to the behavior of polymers in electromagnetic and mechanical fields of force. The book covers the quantities that influence the transport of heat, momentum, and matter, particularly heat conductivity, viscosity, and diffusivity; properties that control the chemical stability and breakdown of polymers; and polymer properties as an integral concept, with emphasis on processing and product properties. Readers will find tables that give valuable (numerical) data on polymers and include a survey of the group contributions (increments) of almost every additive function considered. This book is a valuable resource for anyone working on practical problems in the field of polymers, including organic chemists, chemical engineers, polymer processers, polymer technologists, and both graduate and PhD students.

This book contains a collection of original research papers which were presented in honor of the Bordon Award recipient, Professor Eric Baer, on the occasion of the 55th Meeting of the American Chemical Society (Atlanta, Georgia, March, 1981). The contributors are present or former colleagues and students who have worked with him in the Department of Macromolecular Science at Case Institute of Technology of Case Western Reserve University. Throughout his work, Eric Baer has attempted to find the relation ships of solid state structure and hierarchy to the resultant pro perties from which specific functions are derived. Although he has studied many seemingly unrelated subjects, from irreversible de formation, mechanics and yield processes in amorphous polymeric solids to structural organization and mechanical function of ten don, his unique goal has been to develop models from the real structure that would allow a quantitative description of properties. Today, this area of "microscience" is rapidly expanding as new and sophisticated applications of polymeric materials with multifunc tional properties are emerging from our understanding and control of the solid state. The wide-ranging ideas and the original ity of Professor Baer's contributions have stimulated many new concepts which are now widely accepted in the field of high polymers. The contributions to this volume represent many of the areas which he has explored.