The progressive dwindling of fossil resources, coupled with the drastic increase in oil prices, have sparked a feverish activity in search of alternatives based on renewable resources for the production of energy. Given the predominance of petroleum- and carbon-based chemistry for the manufacture of organic chemical commodities, a similar preoccupation has recently generated numerous initiatives aimed at replacing these fossil sources with renewable counterparts. In particular, major efforts are being conducted in the field of polymer science and technology to prepare macromolecular materials based on renewable resources. The concept of the bio-refinery, viz. the rational exploitation of the vegetable biomass in terms of the separation of its components and their utilisation as such, or after suitable chemical modifications, is thus gaining momentum and considerable financial backing from both the public and private sectors. This collection of chapters, each one written by internationally recognised experts in the corresponding field, covers in a comprehensive fashion all the major aspects related to the synthesis, characterization and properties of macromolecular materials prepared using renewable resources as such, or after appropriate modifications. Thus, monomers such as terpenes and furans, oligomers like rosin and tannins, and polymers ranging from cellulose to proteins and including macromolecules synthesized by microbes, are discussed with the purpose of showing the extraordinary variety of materials that can be prepared from their intelligent exploitation. Particular emphasis has been placed on recent advances and imminent perspectives, given the incessantly growing interest that this area is experiencing in both the scientific and technological realms. - Discusses bio-refining with explicit application to materials - Replete with examples of applications of the concept of sustainable development - Presents an impressive variety of novel macromolecular materials

Biopolymers from Renewable Resources is a compilation of information on the diverse and useful polymers derived from agricultural, animal, and microbial sources. The volume provides insight into the diversity of polymers obtained directly from, or derived from, renewable resources. The beneficial aspects of utilizing polymers from renewable resources, when considering synthesis, pro cessing, disposal, biodegradability, and overall material life-cycle issues, suggests that this will continue to be an important and growing area of interest. The individual chapters provide information on synthesis, processing and properties for a variety of polyamides, polysaccharides, polyesters and polyphenols. The reader will have a single volume that provides a resource from which to gain initial insights into this diverse field and from which key references and contacts can be drawn. Aspects of biology, biotechnology, polymer synthesis, polymer processing and engineering, mechanical properties and biophysics are addressed to varying degrees for the specific biopolymers. The volume can be used as a reference book or as a teaching text. At the more practical level, the range of important materials derived from renewable resources is both extensive and impressive. Gels, additives, fibers, coatings and films are generated from a variety of the biopolymers reviewed in this volume. These polymers are used in commodity materials in our everyday lives, as well as in specialty products.

This book details polysaccharides and other important biomacromolecules covering their source, production, structures, properties, and current and potential application in the fields of biotechnology and medicine. It includes a systematic discussion on the general strategies of isolation, separation and characterization of polysaccharides and proteins. Subsequent chapters are devoted to polysaccharides obtained from various sources, including botanical, algal, animal and microbial. In the area of botanical polysaccharides, separate chapters are devoted to the sources, structure, properties and medical applications of cellulose and its derivatives, starch and its derivatives, pectins, and exudate gums, notably gum arabic. Another chapter discusses the potential of hemicelluloses (xylans and xylan derivatives) as a new source of functional biopolymers for biomedical and industrial applications. The algal polysaccharide, alginate, has significant application in food, pharmaceuticals and the medical field, all of which are reviewed in a separate chapter. Polysaccharides of animal origin are included with separate chapters on the sources, production, biocompatibility, biodegradability and biomedical applications of chitin (chitosan) and hyaluronan. With the increasing knowledge and applications of genetic engineering there is also an introduction in the book to nucleic acid polymers, the genome research and genetic engineering. Proteins and protein conjugates are covered, with one chapter providing a general review of structural glycoproteins, fibronectin and laminin, together with their role in the promotion of cell adhesion in vascular grafts, implants and tissue engineering. Another chapter discusses general aspects of a number of industrial proteins, including casein, caseinates, whey protein, gluten and soy proteins, with emphasis on their medical applications, and with reference to the potential of bacterial proteins. Another natural polymer resource, microbial polyesters, although small compared with polysaccharides and proteins, is also gaining increasing interest in biomedical technology and other industrial sectors. One chapter, therefore, is devoted to microbial polyesters, with comprehensive coverage of their biosynthesis, properties, enzymic degradation and applications. By dealing with biopolymers at the molecular level, the book is aimed at the biomedical and wider materials science communities and provides an advanced overview of biopolymers at the graduate and postgraduate level. In addition it will appeal to both academic and industrial life scientists who are involved in research and development activities in the medical and biotechnology field.

This book is a printed edition of the Special Issue "Polymers from Renewable Resources" that was published in Polymers

Biodegradable Polymer Blends and Composites from Renewable Resources provides a comprehensive, current overview of biopolymeric blends and composites and their applications in various industries. The book is organized according to the type of blend or composite. For each topic, the relationship between the structure of the blends/composites and their respective properties is explored, with particular focus on interface, compatibility, mechanical, and thermal properties. Real-life applications and potential markets are discussed. This is a premier reference for graduate students and researchers in polymer science, chemical and bio engineering, and materials science.

Offering a unique perspective summarizing research on this timely important topic around the globe, this book provides comprehensive coverage of how molecular biomass can be transformed into sustainable polymers. It critically discusses and compares a few classes of biomass - oxygen-rich, hydrocarbon-rich, hydrocarbon and non-hydrocarbon (including carbon dioxide) as well as natural polymers - and equally includes products that are already commercialized. A must-have for both newcomers to the field as well as established researchers in both academia and industry.

Considerable international concerns exist about global climate change and its relationship to the growing use of fossil fuels. Carbon dioxide is released by chemical reactions that are employed to extract energy from fuels, and any regulatory policy limiting the amount of CO2 that could be released from sequestered sources or from energy-generating reactions will require substantial involvement of the chemical sciences and technology R&D community. Much of the public debate has been focused on the question of whether global climate change is occurring and, if so, whether it is anthropogenic, but these questions were outside the scope of the workshop, which instead focused on the question of how to respond to a possible national policy of carbon management. Previous discussion of the latter topic has focused on technological, economic, and ecological aspects and on earth science challenges, but the fundamental science has received little attention. This workshop was designed to gather information that could inform the Chemical Sciences Roundtable in its discussions of possible roles that the chemical sciences community might play in identifying and addressing underlying chemical questions.

Designing polymers and developing polymerization processes that are safe, prevent pollution, and are more efficient in the use of materials and engergy is an important topic in modern chemistry. Today, green polymer research can be seen increasingly in academia nd industry. It tackles all aspects of polymers and polymerization - everything from chemical feedstocks, synthetic pathways, and reaction media to the nature of the final polymer as related to its inherent nontoxicity or degradability. This book summarizes and evaluates the latest developments in green polymerization methods. Specifically, new catalytic methods and processes which incorporate renewable resources will be discussed by leading experts in the field of polymer chemistry. This book is a must-have for Polymer Chemists, Chemists Working with/on Organometallics, Biochemists, Physical Chemists, Chemical Engineers, Biotechnologists, Materials Scientists, and Catalytic Chemists.

The research and development activities in energy conversion and storage are playing a significant role in our daily lives owing to the rising interest in clean energy technologies to alleviate the fossil-fuel crisis. Polymers are used in energy conversion and storage technology due to their low-cost, softness, ductility and flexibility compared to carbon and inorganic materials. Polymers in Energy Conversion and Storage provides in-depth literature on the applicability of polymers in energy conversion and storage, history and progress, fabrication techniques, and potential applications. Highly accomplished experts review current and potential applications including hydrogen production, solar cells, photovoltaics, water splitting, fuel cells, supercapacitors and batteries. Chapters address the history and progress, fabrication techniques, and many applications within a framework of basic studies, novel research, and energy applications. Additional Features Include: Explores all types of energy applications based on polymers and its composites Provides an introduction and essential concepts tailored for the industrial and research community Details historical developments in the use of polymers in energy applications Discusses the advantages of polymers as electrolytes in batteries and fuel cells This book is an invaluable guide for students, professors, scientists and R&D industrial experts working in the field.

This book includes papers on polymeric materials from renewable resources known as `Biorelated Polymers and Plastics', and issues are bound to their utilization and environmental impact in their production, conversions to manufacts and ultimate disposal of post-costume manufacts. Modern industrial developments inspired by the new concepts of sustainability and ecocompatibility require a deeper attention to renewable resources as a new-old source of raw material and feedback. This new trend, occurring not only in industrialized countries but also in emerging countries and countries in transition, thoroughly permeates the polymer and plastic industry, due to the big impact that those materials have on the modern way of life. Plastic waste, specifically that stemming from segments of packaging, containers for solids and liquids and single use items, is attracting much effort from municipality officers, producers and converters, aimed at finding a harmonized solution among the various options available for their appropriate management. In this respect, polymeric materials of natural origin (biopolymers), as well as materials from renewable resources useable for the production of monomeric precursors, or semi-synthetic polymeric materials, constitute a focal point for future industrial development in the production of polymers and plastics. The present book contains much valuable information and scientific hints on a modern approach aimed at designing processes and products with minimal negative environmental impact.