Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites: From Synthesis to Applications offers extensive coverage of polyhedral oligomeric silsesquioxanes and their nanocomposites, including their synthesis, characterization, interfacial interactions and advanced applications. Sections introduce essentials, information on their preparation and discussions on polymeric materials, including elastomers, thermoplastics, thermosetting polymers, polymer blends and IPNs. Further sections cover the latest analysis techniques, examine the properties of POSS-polymer nanocomposites, and discuss key application areas, such as biological, energy, defense, and space. Finally, issues surrounding industry implementation and lifecycle are explored. This is a valuable reference for researchers, scientists and advanced students in the areas of polymer composites and nanocomposites, polymer chemistry, polymer physics, polymer science, and materials science and engineering. In an industrial setting, this book will be of great interest to scientists, R&D professionals, and engineers across industries and disciplines. - Covers all aspects of polyhedral oligomeric silsesquioxanes (POSS) and their nanocomposites, including synthesis and characterization techniques, properties, analysis, applications and trends - Targets POSS nanocomposites, describing synthesis, characterization and the selection of POSS filler types according to polymeric material - Explains the preparation and utilization of POSS polymer nanocomposites for cutting-edge applications, including biological, energy, and defense field applications

Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites: From Synthesis to Applications offers extensive coverage of polyhedral oligomeric silsesquioxanes and their nanocomposites, including their synthesis, characterization, interfacial interactions and advanced applications. Sections introduce essentials, information on their preparation and discussions on polymeric materials, including elastomers, thermoplastics, thermosetting polymers, polymer blends and IPNs. Further sections cover the latest analysis techniques, examine the properties of POSS-polymer nanocomposites, and discuss key application areas, such as biological, energy, defense, and space. Finally, issues surrounding industry implementation and lifecycle are explored. This is a valuable reference for researchers, scientists and advanced students in the areas of polymer composites and nanocomposites, polymer chemistry, polymer physics, polymer science, and materials science and engineering. In an industrial setting, this book will be of great interest to scientists, R&D professionals, and engineers across industries and disciplines. Covers all aspects of polyhedral oligomeric silsesquioxanes (POSS) and their nanocomposites, including synthesis and characterization techniques, properties, analysis, applications and trends Targets POSS nanocomposites, describing synthesis, characterization and the selection of POSS filler types according to polymeric material Explains the preparation and utilization of POSS polymer nanocomposites for cutting-edge applications, including biological, energy, and defense field applications

This book provides an overview of polymer nanocomposites and hybrid materials with polyhedral oligomeric silsesquioxanes (POSS). Among inorganic nanoparticles, functionalized POSS are unique nano-building blocks that can be used to create a wide variety of hybrid and composite materials, where precise control of nanostructures and properties is required. This book describes the influence of incorporation of POSS moieties into (organic) polymer matrices on the mechanical, thermal and flammability behavior of composites and hybrid organic-inorganic materials. Importantly, POSS-containing materials can be bio-functionalized by linking e.g. peptides and growth factors through appropriate surface modification in order to enhance the haemo-compatibility of cardiovascular devices made of these materials. This volume includes descriptions of synthesis routes of POSS and POSS-containing polymeric materials (e.g. based on polyolefines, epoxy resins and polyurethanes), presentation of POSS’ role as flame retardants and as biocompatible linker, as well as the depiction of decomposition and ageing processes.

The commercial availability and decreasing cost of polyhedral oligomeric silsesquioxanes in recent years has opened up the field to everybody who wishes to apply these unique properties in their own technologies. This is the first book to provide a comprehensive overview of these applications, and covers the synthesis, characterization and history of polyhedral oligomeric silsesquioxanes, their use as metallasilsesquioxane catalysts, their effect upon polymer properties and plastics performance, and their use in superhydrophobic nanocomposites, and electronics, energy, space and biomedical applications. "Applications of Polyhedral Oligomeric Silsesquioxanes" is a valuable reference for those working across a range of disciplines, including chemists, materials scientists, polymer physicists, plastics engineers, surface scientists, and anybody with a commercial or academic interest in plastics, composite materials, space materials, dental materials, tissue engineering, drug delivery, lithography, fuel cells, batteries, lubricants, or liquid crystal, LED, sensor, photovoltaic or biomedical devices.

The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.

Combines chemistry and material science in order to provide a complete overview of the design, synthesis, and applications of organo-silica This book offers comprehensive and systematic coverage of the latest developments in functional hybrid silicon copolymers, their applications, and how they were developed in relation to previous works in the preparation of various functional groups terminated silicone materials. Silicon Containing Hybrid Copolymers begins with a chapter that introduces readers to organo-silicon materials. It then presents a chapter on reactive functionally terminated polyorganosiloxanes, and contains a section on the methods and advances of functionalized polyhedral oligomeric silsesquioxanes (POSS) and copolymers. Nanostructured self-assemblies from silicon containing hybrid copolymers are discussed?as are superhydrophobic materials derived from hybrid silicon. Other chapters examine silicone copolymers for healthcare and personal care applications; construction of organic optoelectronic materials by using polyhedral oligomeric silsesquioxanes (POSS); and 3D printing silicone materials and devices. The book also includes an overview of material toughening and fire retardancy in regards to hybrid POSS nanocomposites. This title: -Focuses on design and synthesis strategies, providing a valuable resource for researchers in academia and industry -Presents recent applications, with emphasis on the underlying strategies and the influence from previous designs, in fields such as healthcare and consumer care -Combines synthetic pathways with design specific considerations to provide the reader with greater control over the design process Silicon Containing Hybrid Copolymers is an ideal book for materials scientists, polymer chemists, and bioinorganic chemists.

In recent times, polymer nanocomposites have attracted a great deal of scientific interest due to their unique advantages over conventional plastic materials, such as superior strength, modulus, thermal stability, thermal and electrical conductivity, and gas barrier. They are finding real and fast-growing applications in wide-ranging fields such as automotive, aerospace, electronics, packaging, and sports. This book focuses on the development of polymer nanocomposites as an advanced material for textile applications, such as fibers, coatings, and nanofibers. It compiles and details cutting-edge research in the science and nanotechnology of textiles with special reference to polymer nanocomposites in the form of invited chapters from scientists and subject experts from various institutes from all over the world. They include authors who are actively involved in the research and development of polymer nanocomposites with a wide range of functions—including antimicrobial, flame-retardant, gas barrier, shape memory, sensor, and energy-scavenging—as well as medical applications, such as tissue engineering and wound dressings, to create a new range of smart and intelligent textiles. Edited by Mangala Joshi, a prominent nanotechnology researcher at the premier Indian Institute of Technology, Delhi, India, this book will appeal to anyone involved in nanotechnology, nanocomposites, advanced materials, polymers, fibers and textiles, and technical textiles.

Nanomaterials are defined as materials in which at least one length dimension is below 100 nanometers. In this size regime, these materials exhibit particular - and tunable - optical, electrical or mechanical properties that are not present at the macro-scale. This opens up the possibility for a plethora of applications at the interface of materials, chemistry, physics and biology, many of which have already entered the commercial realm. When nanomaterials are blended with other materials not necessarily in the nanometer regime, the resulting nanocomposites can exhibit dramatically different properties than the bulk material alone, leading to an enhanced performance in terms of, for example, increased thermal and mechanical stability. This book presents the synthesis, characterization and applications of nanomaterials and nanocomposites, covering zero-dimensional, elemental nanoparticles, one-dimensional materials such as nanorods and nanowhiskers, two-dimensional materials such as graphene and boron nitride as well as three-dimensional materials such as fullerenes, polyhedral oligomers and zeolites, complemented by bio-based nanomaterials, e.g., cellulose, chitin, starch and proteins. Introductory chapters on the state-of-the-art of nanomaterial research and the chemistry and physics in nanoscience and nanotechnology round off the book.

This handbook provides a wide overview of the field, fundamental understanding of the synthetic methods and structure/property correlation, as well as studies related to applications in a wide range of subjects. The handbook also provides 1H and 13C NMR spectra, FTIR spectra, DSC and TGA thermograms to aid in research activities. Additional tables on key NMR and FTIR frequencies unique to benzoxazine, heat of polymerization, Tg, and char yield will greatly aid in the choice of proper benzoxazine for a specific application. - Provides thorough coverage of the chemistry and applications of benzoxazine resins with an evidence-based approach to enable chemists, engineers and material scientists to evaluate effectiveness - Features spectra, which allow researchers to compare results, avoid repetition and save time as well as tables on key NMR frequency, IR frequency, heat of polymerization, of many benzoxazine resins to aid them in selection of materials - Written by the foremost experts in the field

Explore the diverse electrical engineering application of polymer composite materials with this in-depth collection edited by leaders in the field Polymer Composites for Electrical Engineering delivers a comprehensive exploration of the fundamental principles, state-of-the-art research, and future challenges of polymer composites. Written from the perspective of electrical engineering applications, like electrical and thermal energy storage, high temperature applications, fire retardance, power cables, electric stress control, and others, the book covers all major application branches of these widely used materials. Rather than focus on polymer composite materials themselves, the distinguished editors have chosen to collect contributions from industry leaders in the area of real and practical electrical engineering applications of polymer composites. The books relevance will only increase as advanced polymer composites receive more attention and interest in the area of advanced electronic devices and electric power equipment. Unique amongst its peers, Polymer Composites for Electrical Engineering offers readers a collection of practical and insightful materials that will be of great interest to both academic and industrial audiences. Those resources include: A comprehensive discussion of glass fiber reinforced polymer composites for power equipment, including GIS, bushing, transformers, and more) Explorations of polymer composites for capacitors, outdoor insulation, electric stress control, power cable insulation, electrical and thermal energy storage, and high temperature applications A treatment of semi-conductive polymer composites for power cables In-depth analysis of fire-retardant polymer composites for electrical engineering An examination of polymer composite conductors Perfect for postgraduate students and researchers working in the fields of electrical, electronic, and polymer engineering, Polymer Composites for Electrical Engineering will also earn a place in the libraries of those working in the areas of composite materials, energy science and technology, and nanotechnology.