Nonlinear Optical Properties of Organic Molecules and Crystals, Volume 2 deals with the nonlinear optical properties of organic molecules and crystals, with emphasis on cubic nonlinear optical effects and and the intermolecular bond. Topics covered include the basic structural and electronic properties of polydiacetylenes; cubic effects in polydiacetylene solutions and films; and degenerate third-order nonlinear optical susceptibility of polydiacetylenes. Dimensionality effects and scaling laws in nonlinear optical susceptibilities are also considered. This volume is comprised of seven chapters divided into two sections and begins with a discussion on the basic structural and electronic properties of polydiacetylenes as well as their methods of preparation. Cubic nonlinearities in polydiacetylene solutions and films are then examined, paying particular attention to polarization in one-dimensional media; multiple reflections of fundamental and harmonic waves; and harmonic generation in an absorbing medium. The following chapters focus on degenerate third-order nonlinear optical susceptibility of polydiacetylenes; dimensionality effects and scaling laws in nonlinear optical susceptibilities; polarizabilities and hyperpolarizabilities of long molecules; and resonant molecular optics. The final chapter analyzes the nonlinear optics of a wide range of compounds that are held together by intermolecular bonding and form supramolecular assemblies. This monograph will be a useful resource for physicists, physical and organic chemists, and those in the field of quantum electronics.

Nonlinear Optical Properties of Organic Molecules and Crystals, Volume 1 discusses the nonlinear optical effects in organic molecules and crystals, providing a classical distinction between quadratic and cubic processes. This book begins with a general overview of the basic properties of organic matter, followed by a review on the benefits derived from quantum-chemistry-based models and growth and characterization of high quality, bulk organic crystals and waveguided structures. A case study focusing on a specific material, namely urea, which exemplifies a situation in which transparency in the UV region has been purposely traded for nonlinear efficiency is also deliberated. This text concludes with a description of a type of trade-off between the unpredictable orientation of molecules in crystalline media, polarity of liquid-crystalline structures, and dominant electronic contribution to the electro-optic effect. This publication is beneficial to solid-state physicists and chemists concerned with nonlinear optical properties of organic molecules and crystals.

Photonics is being labelled by many as the technology for the 21st century. Because of the structural flexibility both at the molecular and bulk levels, organic materials are emerging as a very important class of nonlinear optical materials to be used for generating necessary nonlinear optical functions for the technology of photonics. Since the last NATO advanced research workshop on "Polymers for Nonlinear Optics"held in June 1988, at Nice - Sophia Antipolis, France. there has been a tremendous growth of interest worldwide and important development in this field. Significant progress has been made in theoretical modeling, material development, experimental studies and device concepts utilizing organic materials. These important recent developments provided the rationale for organizing the workshop on "Organic Materials for Nonlinear Optics and Photonics" which was held in La Rochelle, France, in August 1990. This proceeding is the outcome of the workshop held in La Rochelle. The objective of the workshop was to bring together scientists and engineers of varied backgrounds working in this field in order to assess the current status of this field by presenting significant recent developments and make recommendations on future directions of research. The workshop was multidisciplinary as it had contributions from chemists, physicists, materials scientists and device engineers. The participants were both from industries and universities. The workshop included plenary lectures by leading international scientists in this field, contributed research papers and a poster session. Panel discussion groups were organized to summarize important developments and to project future directions.

Nonlinear Optical Properties of Organic Molecules and Crystals V2 ...

Mathematical methods play a significant role in the rapidly growing field of nonlinear optical materials. This volume discusses a number of successful or promising contributions. The overall theme of this volume is twofold: (1) the challenges faced in computing and optimizing nonlinear optical material properties; and (2) the exploitation of these properties in important areas of application. These include the design of optical amplifiers and lasers, as well as novel optical switches. Research topics in this volume include how to exploit the magnetooptic effect, how to work with the nonlinear optical response of materials, how to predict laser-induced breakdown in efficient optical devices, and how to handle electron cloud distortion in femtosecond processes.

Nonlinear Optical Properties of Organic Molecules and Crystals V1 ...

This is a monograph/text devoted to a detailed treatment of the optical, electro-optical and nonlinear optical properties of all the mesophases of liquid crystals and related processes, phenomena and application principles. Quantitative data on material and optical parameters spanning the ultraviolet, visible, infrared as well as the microwave regimes are presented along with detailed theoretical treatments of basic liquid crystal physics, material properties and nonlinear optics.Starting with a discussion on the basic building blocks of liquid crystalline molecules, the authors proceed to present in a pedagogical manner current theories, experiments, and applications of these unique and important optical properties of liquid crystals. Numerous tables of hard-to-find liquid crystalline parameters, a self-contained chapter on general nonlinear optics, and comprehensive literature review are also included.

The field of nonlinear optics emerged three decades ago with the development of the first operating laser and the demonstration of frequency doubling phenomena. These milestone discoveries not only generated much interest in laser science, but also set the stage for future work on nonlinear optics. This book presents an excellent overview of the exciting new advances in nonlinear optical (NLO) materials and their applications in emerging photonics technologies. It is the first reference source available to cover every NLO material published through 1995. All theoretical approaches, measurement techniques, materials, technologies, and applications are covered. With more than 1,800 bibliographic citations, 324 figures, 218 tables, and 812 equations, this book is an invaluable reference source for graduate and undergraduate students, researchers, scientists and engineers working in academia and industries in chemistry, solid-state physics, materials science, optical and polymer engineering, and computational science.

Small molecules and conjugated polymers, the two main types of organic materials used for optoelectronic and photonic devices, can be used in a number of applications including organic light-emitting diodes, photovoltaic devices, photorefractive devices and waveguides. Organic materials are attractive due to their low cost, the possibility of their deposition from solution onto large-area substrates, and the ability to tailor their properties. The Handbook of organic materials for optical and (opto)electronic devices provides an overview of the properties of organic optoelectronic and nonlinear optical materials, and explains how these materials can be used across a range of applications.Parts one and two explore the materials used for organic optoelectronics and nonlinear optics, their properties, and methods of their characterization illustrated by physical studies. Part three moves on to discuss the applications of optoelectronic and nonlinear optical organic materials in devices and includes chapters on organic solar cells, electronic memory devices, and electronic chemical sensors, electro-optic devices.The Handbook of organic materials for optical and (opto)electronic devices is a technical resource for physicists, chemists, electrical engineers and materials scientists involved in research and development of organic semiconductor and nonlinear optical materials and devices. - Comprehensively examines the properties of organic optoelectronic and nonlinear optical materials - Discusses their applications in different devices including solar cells, LEDs and electronic memory devices - An essential technical resource for physicists, chemists, electrical engineers and materials scientists

This second volume of the series on photorefractive effects focuses on the most recent developments in the field and highlights the parameters which govern the photoinduced nonlinearity. Besides reviewing conventional electro-optic crystals, this book deals with organic photorefractive materials, giving an in-depth assessment of the present understanding of the effect in a variety of materials. The materials considered in this volume will play a significant role in the development of applications such as presented in the third volume.