In the past two decades, the field of nanoporous materials has undergone significant developments. As these materials possess high specific surface areas, well-defined pore sizes, and functional sites, they show a great diversity of applications such as molecular adsorption/storage and separation, sensing, catalysis, energy storage and conversion,

Porous materials are of scientific and technological importance because of the presence of voids of controllable dimensions at the atomic, molecular, and nanometer scales, enabling them to discriminate and interact with molecules and clusters. Interestingly the big deal about this class of materials is about the “nothingness” within — the pore space. International Union of Pure and Applied Chemistry (IUPAC) classifies porous materials into three categories — micropores of less than 2 nm in diameter, mesopores between 2 and 50 nm, and macropores of greater than 50 nm. In this book, nanoporous materials are defined as those porous materials with pore diameters less than 100 nm.Over the last decade, there has been an ever increasing interest and research effort in the synthesis, characterization, functionalization, molecular modeling and design of nanoporous materials. The main challenges in research include the fundamental understanding of structure-property relations and tailor-design of nanostructures for specific properties and applications. Research efforts in this field have been driven by the rapid growing emerging applications such as biosensor, drug delivery, gas separation, energy storage and fuel cell technology, nanocatalysis and photonics. These applications offer exciting new opportunities for scientists to develop new strategies and techniques for the synthesis and applications of these materials.This book provides a series of systematic reviews of the recent developments in nanoporous materials. It covers the following topics: (1) synthesis, processing, characterization and property evaluation; (2) functionalization by physical and/or chemical treatments; (3) experimental and computational studies on fundamental properties, such as catalytic effects, transport and adsorption, molecular sieving and biosorption; (4) applications, including photonic devices, catalysis, environmental pollution control, biological molecules separation and isolation, sensors, membranes, hydrogen and energy storage, etc./a

Atoms and molecules in all states of matter are subject to continuous irregular movement. This process, referred to as diffusion, is among the most general and basic phenomena in nature and determines the performance of many technological processes. This book provides an introduction to the fascinating world of diffusion in microporous solids. Jointly written by three well-known researchers in this field, it presents a coherent treatise, rather than a compilation of separate review articles, covering the theoretical fundamentals, molecular modeling, experimental observation and technical applications. Based on the book Diffusion in Zeolites and other Microporous Solids, originally published in 1992, it illustrates the remarkable speed with which this field has developed since that time. Specific topics include: new families of nanoporous materials, micro-imaging and single-particle tracking, direct monitoring of transient profiles by interference microscopy, single-file diffusion and new approaches to molecular modeling.

This book is a special collection of articles dedicated to the preparation and characterization of nanoporous materials, such as zeolitic-type materials, mesoporous silica (SBA-15, MCM-41, and KIT-6), mesoporous metallic oxides, metal–organic framework structures (MOFs), and pillared clays, and their applications in adsorption, catalysis, and separation processes. This book presents a global vision of researchers from international universities, research centers, and industries working with nanoporous materials and shares the latest results on the synthesis and characterization of such materials, which have given rise to the special interest in their applications in basic and industrial processes.

In the past two decades, the field of nanoporous materials has undergone significant developments. As these materials possess high specific surface areas, well-defined pore sizes, and functional sites, they show a great diversity of applications such as molecular adsorption/storage and separation, sensing, catalysis, energy storage and conversion, drug delivery, and more. Nanoporous Materials: Synthesis and Applications surveys the key developments in the synthesis of nanoporous materials in a broad range from soft porous materials—such as porous organic and metal-organic frameworks—to hard porous materials, such as porous metals and metal oxides, and the significant advances in their applications to date. Topics Include: Synthetic approaches, characterization techniques, and applications of a variety of meso- and microporous polymers and organic frameworks Advances in the synthetic control of structures along with the function exploration of this new class of organic porous materials Synthesis and applications of nanoporous metal-organic frameworks, mesoporous silica, and nanoporous glass Synthesis of mesoporous carbons by a soft- and hard-templating method and their applications for supercapacitors and membrane separations Fabrication of nanoporous semiconductor materials Structural modification and functional improvement of layered zeolites Germanates and related materials with open-frameworks

Having successfully replaced elements used in traditional, pollution-prone, energy-consuming separation processes, nanoporous materials play an important role in chemical processing. Although their unique structural or surface physicochemical properties can, to an extent, be tailored to meet specific process-related requirements, the task of charac

Offering a materials science point of view, the author covers the theory and practice of adsorption and diffusion applied to gases in microporous crystalline, mesoporous ordered, and micro/mesoporous amorphous materials. Examples used include microporous and mesoporous molecular sieves, amorphous silica, and alumina and active carbons, akaganeites, prussian blue analogues, metal organic frameworks and covalent organic frameworks. The use of single component adsorption, diffusion in the characterization of the adsorbent surface, pore volume, pore size distribution, and the study of the parameters characterizing single component transport processes in porous materials are detailed.

Nanoporous Materials IV contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 4th International Symposium on Nanoporous Materials, which will be hosted in Niagara Falls, Ontario, Canada, June 7-10, 2005. This volume covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves (e.g., MCM-41 and SBA-15) and related materials including clays, ordered mesoporous carbons, colloidal crystal templated materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic, separation and environmental processes as well as for the development of nanotechnology. This volume contains over 120 contributions related to the synthesis of ordered mesoporous silicas, organosilicas, nonsiliceous inorganic materials, carbons, polymers and related materials, their characterization and applications in adsorption, catalysis and environmental clean up.* Unique contributions brings readers up-to-date on new research and application developments* Figures and tables supplement comprehensive topics * Extensive author and subject index

Advances in Nanoporous Materials is a collection of comprehensive reviews of lasting value to the field. The contributions cover all aspects of nanoporous materials, including their preparation and structure, post-synthetic modification, characterization and use in catalysis, adsorption/separation, and all other fields of potential application, e.g., membranes, host/guest chemistry, environmental protection, electrochemistry, sensors, and optical devices. "Nanoporous materials" comprise all kinds of porous solids that possess pores in the range from about 0.2 nm up to 50 nm, irrespective of their chemical composition, their origin (natural or synthetic), and their amorphous or crystalline nature. Typical examples are zeolites and zeolite-like materials (e.g., crystalline microporous aluminophosphates and their derivatives), mesoporous oxides such as silica, metal organic frameworks, pillared clays, porous carbons, and related materials. - State-of-the-art reviews keep coverage current - Broad scope provides a full topical overview - Contributions from renowned experts lend authority to the material

Nanoporous Materials III contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 3rd Conference on Nanoporous Materials, which will be hosted in Ottawa, Canada, June 2002. The work covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves M41S and FSM16 and related materials including clays, carbon molecular sieves, colloidal crystal templated organic and inorganic materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic and separation processes as well as the development of nanotechnology. The contents of this title are based on topics to be discussed by invited lecturers, which deal with periodic mesoporous organosilicas, stability and catalytic activity of aluminosilicate mesostructures, electron microscopy studies of ordered materials, imprinted polymers and highly porous metal-organic frameworks. The other contributions deal with tailoring the surface and structural properties of nanoporous materials, giving a detailed characterization as well as demonstrating their usefulness for advanced adsorption and catalytic applications.