The book deals with the most accurate method to describe thermodynamic property data, with empirical multiparameter equations of state. Due to new theoretical approaches, to increasing demands on the accuracy of thermodynamic property data, and to increasing computer power such equations became a valuable tool for every day calculations in scientific and engineering applications, rather than just the basis of printed property charts and tables. The book is dedicated both to users, who apply such formulations either in form of commercially available software or in form of programs written by themselves, and to scientists engaged in the development of empirical equations of state. Starting from a brief history, it covers the fundamentals of this subject as well as the most recent developments in the fields of highly accurate reference equations, of equations for advanced technical applications, and of the description of mixtures with multiparameter equations of state.

As a basis for printed property charts and tables, empirical multiparameter equa tions of state have been the most important source of accurate thermodynamic property data for more than 30 years now. However, due to increasing demands on the accuracy of thermodynamic property data in computerised calculations as well as the availability of appropriate software tools, and the ever increasing computer power, such formulations are nowadays becoming a valuable tool for everyday work. This development has substantially increased the number of scientists, engi neers, and students who are working with empirical multiparameter equations of state, and it continues to do so. Nevertheless, common knowledge on this kind of thermodynamic property models and on the ongoing progress in this scientific discipline is still very limited. Multiparameter equations of state do not belong to the topics which are taught intensively in thermodynamic courses in engineering and natural sciences and the books and articles where they are published mainly deal with the thermodynamic properties of certain substances rather than with the theoretical background of the used equations of state. In contrast to this, my concern mainly was to give a survey of the theoretical background of multiparameter equations of state both with regard to their application and their development.

This book has been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The book gives an up-to-date presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.

Published under the auspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the needs of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydrocarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commercial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.

One of the masters in the differential equations community, the late F.V. Atkinson contributed seminal research to multiparameter spectral theory and Sturm-Liouville theory. His ideas and techniques have long inspired researchers and continue to stimulate discussion. With the help of co-author Angelo B. Mingarelli, Multiparameter Eigenvalue Problem

Volumetric properties play an important role in research at the interface of physical chemistry and chemical engineering, but keeping up with the latest developments in the field demands a broad view of the literature. Presenting a collection of concise, focused chapters, this book offers a comprehensive guide to the latest developments in the field and a starting point for more detailed research. The chapters are written by acknowledged experts, covering theory, experimental methods, techniques, and results on all types of liquids and vapours. The editors work at the forefront of thermodynamics in mixtures and solutions and have brought together contributions from all areas related to volume properties, offering a synergy of ideas across the field. Graduates, researchers and anyone working in the field of volumes will find this book to be their key reference.

The corresponding-states principle helps the understanding and calculating of thermodynamic, transport, and surface properties of substances in various states, required by our modern lifestyle. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids describes the origins and applications of the principle from a universal point of view with comparisons to experimental data where possible. It uses the universal theory to explain present theories. Emphasis is on the properties of pure systems, and the corresponding-states theory can also be extended to mixtures, which are treated as pure systems. Furthermore, the author discusses current progress, and shows technicians how to derive practical equations from molecular modeling. The Corresponding-States Principle and its Practice: Thermodynamic, Transport and Surface Properties of Fluids is the ideal handbook for those in chemical science and engineering related to energy, environment, natural gas, and petroleum.* Describes the origins and applications from a universal viewpoint* Includes experimental data for comparisons * Suitable for researchers, applied engineers, and those interested in the corresponding states theory

Organic Rankine Cycle (ORC) Power Systems: Technologies and Applications provides a systematic and detailed description of organic Rankine cycle technologies and the way they are increasingly of interest for cost-effective sustainable energy generation. Popular applications include cogeneration from biomass and electricity generation from geothermal reservoirs and concentrating solar power installations, as well as waste heat recovery from gas turbines, internal combustion engines and medium- and low-temperature industrial processes. With hundreds of ORC power systems already in operation and the market growing at a fast pace, this is an active and engaging area of scientific research and technical development. The book is structured in three main parts: (i) Introduction to ORC Power Systems, Design and Optimization, (ii) ORC Plant Components, and (iii) Fields of Application. - Provides a thorough introduction to ORC power systems - Contains detailed chapters on ORC plant components - Includes a section focusing on ORC design and optimization - Reviews key applications of ORC technologies, including cogeneration from biomass, electricity generation from geothermal reservoirs and concentrating solar power installations, waste heat recovery from gas turbines, internal combustion engines and medium- and low-temperature industrial processes - Various chapters are authored by well-known specialists from Academia and ORC manufacturers

Self-contained presentation: from elementary material to state-of-the-art research; Much of the theory in book-form for the first time; Connections are made between probability and other areas of mathematics, engineering and mathematical physics

This concise text provides an essential treatment of thermodynamics and a discussion of the basic principles built on an intuitive description of the microscopic behavior of matter. Aimed at a range of courses in mechanical and aerospace engineering, the presentation explains the foundations valid at the macroscopic level in relation to what happens at the microscopic level, relying on intuitive and visual explanations which are presented with engaging cases. With ad hoc, real-word examples related also to current and future renewable energy conversion technologies and two well-known programs used for thermodynamic calculations, FluidProp and StanJan, this text provides students with a rich and engaging learning experience.