This collection covers the physical and chemical phenomena of metal surfaces, including surface modifications and treatments. It is targeted at researchers working in materials science and also at newcomers to the research field of metal surfaces and surface analysis.

The Structure of Rare-Earth Metal Surfaces introduces the concepts of surface crystallography and surface-structure determination, outlines the principles of the most widely used experimental techniques and theoretical simulations, and reviews their application to the surfaces of rare-earth metals. In particular, the results of quantitative low-energy electron-diffraction experiments and multiple-scattering calculations axe covered in some depth. The book is aimed at science graduates with an interest in surface crystallography.

In this new work, the focus is on the dynamical response of metal electrons to several types of incident electromagnetic fields. The author, an eminent theorist, discusses Time-Dependent Local Density Approximation's importance in both elucidating electronic surface excitations and describing the ground state properties of electronic systems. Chapters detail theoretical formulations and computational procedures, covering such areas as single-particle and collective modes, spatial distribution of the induced surface charges, and local electric fields. Excitation spectra are shown for a variety of clean simple metals, noble metals, chemisorbed overlayers, charged surfaces, and small metal particles.

Using lasers to induce and probe surface processes has the advantages of quantum state specificity, species selectivity, surface sensitivity, fast time-resolution, high frequency resolution, and accessibility to full pressure ranges. These advantages make it highly desirable to use light to induce, control, or monitor surface chemical and physical processes. Recent applications of laser based techniques in studying surface processes have stimulated new developments and enabled the understanding of fundamental problems in energy transfer and reactions. This volume will include discussions on spectroscopic techniques, energy transfer, desorption dynamics, and photochemistry.

The collisions of neutral or charged gaseous particles with solid surfaces govern many physical and chemical phenomena, as has been The gas/solid phenomena in turn depend on a recognized for a long time. great variety of processes such as the charge transfer of the gas/solid interface, adsorption and desorption, the energy transfer between an incident particle and the surface, etc. Our knowledge of these processes, however, is only fragmentary. This is partly due to the difficulty in adequately controlling the ex perimental conditions. Consequently, until recently the data were usually so complex that reliable information about a particular elementary process could not be deduced. Within the last five to ten years, however, the techniques of ultra-high vacuum and surface preparation have developed rapidly and there has been a booming and widespread interest in the role of gas/solid interactions in such diverse fields as plasma physics, thermonuclear reactions, thermionic energy conversion, ion propulsion, sputtering corrosion of the surface of satellites and ion engines, ion getter pumps, deposition of thin films, etc. This led to extensive investigations of numerous gas/solid phenomena, such as surface ionization, sputtering, emission of secondary electrons and ions from surfaces under atom and/or ion impact, ion neutralization, and the thermal accomodation of gaseous particles on surfaces. As a result, it has become possible to gather a variety of valuable information.

Imagine that a young physicist would approach a granting agen cy and propose to contribute to heterogeneous catalysis by studying the heat conductivity of gases in contact with a hot filament. How would he be received now? How would he have been treated sixty years ago ? Yet, more than sixty years ago, Irving Langmuir, through his study of heat transfer from a tungsten filament, uncovered most of the fundamental ideas which are used to-day by the scientific com munity in pure and applied heterogeneous catalysis. Through his work with what were for the first time "clean" metal surfaces, Langmuir formulated during a period of a little over ten years un til the early thirties, the concepts of chemisorption, monolayer, adsorption sites, adsorption isotherm, sticking probability, cata lytic mechanisms by way of the interaction between chemisorbed spe cies, behavior of non-uniform surfaces and repulsion between adsor bed dipoles. It is fair to say that many of these ideas constituting the first revolution in surface chemistry have since been refined through thousands of investigations. Countless papers have been pu blished on the subject of the Langmuir adsorption isotherm, the Langmuir catalytic kinetics and the Langmuir site-exclusion adsorp tion kinetics. The refinements have been significant. ThE original concepts in their primitive or amended form are used everyday by catalytic chemists and chemical engineers allover the world in their treatment of experimental data, design of reactors or inven tion of new processes.

Using lasers to induce and probe surface processes has the advantages of quantum state specificity, species selectivity, surface sensitivity, fast time-resolution, high frequency resolution, and accessibility to full pressure ranges. These advantages make it highly desirable to use light to induce, control, or monitor surface chemical and physical processes. Recent applications of laser based techniques in studying surface processes have stimulated new developments and enabled the understanding of fundamental problems in energy transfer and reactions. This volume will include discussions on spectroscopic techniques, energy transfer, desorption dynamics, and photochemistry.

This book is dedicated to recent advancements in theoretical and computational studies on the interactions of hydrogen and hydrogenated molecules with metal surfaces. These studies are driven by the development of high-performance computers, new experimental findings, and the extensive work of technological applications towards the realization of a sustainable hydrogen economy. Understanding of the elementary processes of physical and chemical reactions on the atomic scale is important in the discovery of new materials with high chemical reactivity and catalytic activity, as well as high stability and durability. From this point of view, the book focuses on the behavior of hydrogen and hydrogenated molecules on flat, stepped, and reconstructed metal surfaces. It also tackles the quantum mechanical properties of hydrogen and related adsorbates; namely, molecular orbital angular momentum (spin) and diffusion along the minimum potential energy landscape on metal surfaces. All of these profoundly influence the outcomes of (1) catalytic reactions that involve hydrogen; (2) hydrogen storage in metals; and (3) hydrogen purification membranes. Lastly, it surveys the current status of the technology, outlook, and challenges for the long-desired sustainable hydrogen economy in relation to the topics covered in the book.

Given the fact of the increasing meaning of individual and functional micro- or nanostructures, it is of high interest to open up two-photon polymerization (TPP) as a structuring technology for production. TPP offers real 3D capability while providing a high precision, so arbitrary geometries with optical, photonic or biological func-tionalities can be realized. Thus, the aim is to use TPP as a mastering technology for metal substrates that serve as tools for injection moulding.

Using lasers to induce and probe surface processes has the advantages of quantum state specificity, species selectivity, surface sensitivity, fast time-resolution, high frequency resolution, and accessibility to full pressure ranges. These advantages make it highly desirable to use light to induce, control, or monitor surface chemical and physical processes. Recent applications of laser based techniques in studying surface processes have stimulated new developments and enabled the understanding of fundamental problems in energy transfer and reactions. This volume will include discussions on spectroscopic techniques, energy transfer, desorption dynamics, and photochemistry.