The idea that a long-lived form of spin order, namely singlet order, can be prepared from nuclear spin magnetisation first emerged in 2004. The unusual properties of singlet order–its long lifetime and the fact that it is NMR silent but interconvertible into other forms of NMR active order—make it a ‘smart tag’ that can be used to store information for a long time or through distant space points. It is not unexpected then, that since its first appearance, this idea has caught the attention of research groups interested in exploiting this form of order in different fields of research spanning from biology to materials science and from hyperpolarisation to quantum computing. This first book on the subject gives a thorough description of the various aspects that affect the development of the topic and details the interdisciplinary applications. The book starts with a section dedicated to the basic theories of long-lived spin order and then proceeds with a description of the state-of-the-art experimental techniques developed to manipulate singlet order. It then concludes by covering the generalization of the concept of singlet order by introducing and discussing other forms of long-lived spin order.

Study Edition

Nuclear isomers are the long-lived excited states of nuclei. Therefore, they constitute the meta-stable landscape of nuclei. The first isomer was probably identified as early as 1921. Since then, the number of isomers has been growing steadily picking up pace in recent times. Interest in nuclear isomers has grown in recent years for many reasons. The experimental capabilities to observe isomers have been expanding to cover a wider time scale. This has opened up new windows to observe and decipher the underlying nuclear structure and interactions. Further, the isomers are beginning to be seen as potential energy storage devices and nuclear clocks with a host of applications. Possible discovery of a gamma ray laser has also ignited many researches in this area. Isomers now cover the full nuclear landscape with structural peculiarities specific to each region of the nuclear chart. Exploring the nuclear isomers, therefore, provides a novel insight into the nuclear structure properties of that region. There could be many different reasons for the long lives of excited nuclear states, which lead to the classification of isomers. Isomers are broadly classified in to four classes: Spin isomers, shape isomers, fission isomers and K-isomers. Seniority isomers have also been identified which are often clubbed with the spin isomers. We discuss this classification and the underlying causes in detail. Many examples are considered to highlight the large variety of isomers. The range of half-lives covered by the isomers varies from billions of years to nano-seconds and even small. To understand this vast variation is a fascinating endeavor in itself. The angular momentum couplings, nuclear shapes, pairing etc. conspire together to give this vast range of half-lives. We go through these aspects in detail, highlighting the various selection rules at work. It is interesting that the nuclear shapes play an important role in many types of isomers. The spin isomers, which occur in spherical or, near-spherical nuclei, are generally confined to the magic numbers. Seniority isomers are largely found in semi-magic nuclei and should be explored in conjunction with the spin isomers. New developments in seniority and generalized seniority isomers are discussed in detail. As the nuclei deform; the nature of isomers changes. We take a close look into the decay properties of isomers in deformed nuclei, particularly the K isomers, the shape isomers and the fission isomers. While doing so, the theoretical and experimental developments of isomers are also addressed. A number of open questions are posed for possible new experiments and better understanding of the isomers.

Spin Dynamics: Basics of Nuclear Magnetic Resonance, Second Edition is a comprehensive and modern introduction which focuses on those essential principles and concepts needed for a thorough understanding of the subject, rather than the practical aspects. The quantum theory of nuclear magnets is presented within a strong physical framework, supported by figures. The book assumes only a basic knowledge of complex numbers and matrices, and provides the reader with numerous worked examples and exercises to encourage understanding. With the explicit aim of carefully developing the subject from the beginning, the text starts with coverage of quarks and nucleons and progresses through to a detailed explanation of several important NMR experiments, including NMR imaging, COSY, NOESY and TROSY. Completely revised and updated, the Second Edition features new material on the properties and distributions of isotopes, chemical shift anisotropy and quadrupolar interactions, Pake patterns, spin echoes, slice selection in NMR imaging, and a complete new chapter on the NMR spectroscopy of quadrupolar nuclei. New appendices have been included on Euler angles, and coherence selection by field gradients. As in the first edition, all material is heavily supported by graphics, much of which is new to this edition. Written for undergraduates and postgraduate students taking a first course in NMR spectroscopy and for those needing an up-to-date account of the subject, this multi-disciplinary book will appeal to chemical, physical, material, life, medical, earth and environmental scientists. The detailed physical insights will also make the book of interest for experienced spectroscopists and NMR researchers. • An accessible and carefully written introduction, designed to help students to fully understand this complex and dynamic subject • Takes a multi-disciplinary approach, focusing on basic principles and concepts rather than the more practical aspects • Presents a strong pedagogical approach throughout, with emphasis placed on individual spins to aid understanding • Includes numerous worked examples, problems, further reading and additional notes Praise from the reviews of the First Edition: "This is an excellent book... that many teachers of NMR spectroscopy will cherish... It deserves to be a ‘classic’ among NMR spectroscopy texts." NMR IN BIOMEDICINE "I strongly recommend this book to everyone…it is probably the best modern comprehensive description of the subject." ANGEWANDTE CHEMIE, INTERNATIONAL EDITION

Radiation detection is key to experimental nuclear physics as well as underpinning a wide range of applications in nuclear decommissioning, homeland security and medical imaging. This book presents the state-of-the-art in radiation detection of light and heavy ions, beta particles, gamma rays and neutrons. The underpinning physics of different detector technologies is presented, and their performance is compared and contrasted. Detector technology likely to be encountered in contemporary international laboratories is also emphasized. There is a strong focus on experimental design and mapping detector technology to the needs of a particular measurement problem. This book will be invaluable to PhD students in experimental nuclear physics and nuclear technology, as well as undergraduate students encountering projects based on radiation detection for the first time. Key Features Provides clear, concise descriptions of key detection techniques Describes detector types with "telescopic depth", so readers can go as deep as they wish Covers real-world applications including short case studies in industry

Dramatic progress has been made in all branches of physics since the National Research Council's 1986 decadal survey of the field. The Physics in a New Era series explores these advances and looks ahead to future goals. The series includes assessments of the major subfields and reports on several smaller subfields, and preparation has begun on an overview volume on the unity of physics, its relationships to other fields, and its contributions to national needs. Nuclear Physics is the latest volume of the series. The book describes current activity in understanding nuclear structure and symmetries, the behavior of matter at extreme densities, the role of nuclear physics in astrophysics and cosmology, and the instrumentation and facilities used by the field. It makes recommendations on the resources needed for experimental and theoretical advances in the coming decade.

Impressive in its overall size and scope, this five-volume reference work provides researchers with the tools to push them into the forefront of the latest research. The Handbook covers all of the chemical aspects of nuclear science starting from the physical basics and including such diverse areas as the chemistry of transactinides and exotic atoms as well as radioactive waste management and radiopharmaceutical chemistry relevant to nuclear medicine. The nuclear methods of the investigation of chemical structure also receive ample space and attention. The international team of authors consists of 77 world-renowned experts - nuclear chemists, radiopharmaceutical chemists and physicists - from Austria, Belgium, Germany, Great Britain, Hungary, Holland, Japan, Russia, Sweden, Switzerland and the United States. The Handbook is an invaluable reference for nuclear scientists, biologists, chemists, physicists, physicians practicing nuclear medicine, graduate students and teachers - virtually all who are involved in the chemical and radiopharmaceutical aspects of nuclear science. The Handbook also provides for further reading through its rich selection of references.

Molecular Symmetry and Spectroscopy deals with the use of group theory in quantum mechanics in relation to problems in molecular spectroscopy. It discusses the use of the molecular symmetry group, whose elements consist of permutations of identical nuclei with or without inversion. After reviewing the permutation groups, inversion operation, point groups, and representation of groups, the book describes the use of representations for labeling molecular energy. The text explains an approximate time independent Schrödinger equation for a molecule, as well as the effect of a nuclear permutation or the inversion of E* on such equation. The book also examines the expression for the complete molecular Hamiltonian and the several groups of operations commuting with the Hamiltonian. The energy levels of the Hamiltonian can then be symmetrically labeled by the investigator using the irreducible representations of these groups. The text explains the two techniques to change coordinates in a Schrödinger equation, namely, (1) by using a diatomic molecule in the rovibronic Schrödinger equation, and (2) by a rigid nonlinear polyatomic molecule. The book also explains that using true symmetry, basis symmetry, near symmetry, and near quantum numbers, the investigator can label molecular energy levels. The text can benefit students of molecular spectroscopy, academicians, and investigators of molecular chemistry or quantum mechanics.