The book presents the modeling and control of hydrogen-air PEM fuel cells, including simultaneous estimation of the parameters and states, fuzzy cluster modeling, SPM-based predictive control and advanced fuzzy control. MATLAB/Simulink-based modeling and control programs are discussed in detail. With simulations and experiments, it is an essential reference for both scientists and industrial engineers.

PEM Fuel Cells: Fundamentals, Advanced Technologies, and Practical Application provides a comprehensive introduction to the principles of PEM fuel cell, their working condition and application, and the latest breakthroughs and challenges for fuel cell technology. Each chapter follows a systematic and consistent structure with clear illustrations and diagrams for easy understanding. The opening chapters address the basics of PEM technology; stacking and membrane electrode assembly for PEM, degradation mechanisms of electrocatalysts, platinum dissolution and redeposition, carbon-support corrosion, bipolar plates and carbon nanotubes for the PEM, and gas diffusion layers. Thermodynamics, operating conditions, and electrochemistry address fuel cell efficiency and the fundamental workings of the PEM. Instruments and techniques for testing and diagnosis are then presented alongside practical tests. Dedicated chapters explain how to use MATLAB and COMSOL to conduct simulation and modeling of catalysts, gas diffusion layers, assembly, and membrane. Degradation and failure modes are discussed in detail, providing strategies and protocols for mitigation. High-temperature PEMs are also examined, as are the fundamentals of EIS. Critically, the environmental impact and life cycle of the production and storage of hydrogen are addressed, as are the risk and durability issues of PEMFC technology. Dedicated chapters are presented on the economics and commercialization of PEMFCs, including discussion of installation costs, initial capital costs, and the regulatory frameworks; apart from this, there is a separate chapter on their application to the automotive industry. Finally, future challenges and applications are considered. PEM Fuel Cells: Fundamentals, Advanced Technologies, and Practical Application provides an in-depth and comprehensive reference on every aspect of PEM fuel cells fundamentals, ideal for researchers, graduates, and students. - Presents the fundamentals of PEM fuel cell technology, electrolytes, membranes, modeling, conductivity, recent trends, and future applications - Addresses commercialization, public policy, and the environmental impacts of PEMFC in dedicated chapters - Presents state-of-the-art PEMFC research alongside the underlying concepts

Demand for fuel cell technology is growing rapidly. Fuel cells are being commercialized to provide power to buildings like hospitals and schools, to replace batteries in portable electronic devices, and as replacements for internal combustion engines in vehicles. PEM (Proton Exchange Membrane) fuel cells are lighter, smaller, and more efficient than other types of fuel cell. As a result, over 80% of fuel cells being produced today are PEM cells. This new edition of Dr. Barbir's groundbreaking book still lays the groundwork for engineers, technicians and students better than any other resource, covering fundamentals of design, electrochemistry, heat and mass transport, as well as providing the context of system design and applications. Yet it now also provides invaluable information on the latest advances in modeling, diagnostics, materials, and components, along with an updated chapter on the evolving applications areas wherein PEM cells are being deployed. Comprehensive guide covers all aspects of PEM fuel cells, from theory and fundamentals to practical applications Provides solutions to heat and water management problems engineers must face when designing and implementing PEM fuel cells in systems Hundreds of original illustrations, real-life engineering examples, and end-of-chapter problems help clarify, contextualize, and aid understanding

Although, the basic concept of a fuel cell is quite simple, creating new designs and optimizing their performance takes serious work and a mastery of several technical areas. PEM Fuel Cell Modeling and Simulation Using Matlab, provides design engineers and researchers with a valuable tool for understanding and overcoming barriers to designing and building the next generation of PEM Fuel Cells. With this book, engineers can test components and verify designs in the development phase, saving both time and money. Easy to read and understand, this book provides design and modelling tips for fuel cell components such as: modelling proton exchange structure, catalyst layers, gas diffusion, fuel distribution structures, fuel cell stacks and fuel cell plant. This book includes design advice and MATLAB and FEMLAB codes for Fuel Cell types such as: polymer electrolyte, direct methanol and solid oxide fuel cells. This book also includes types for one, two and three dimensional modeling and two-phase flow phenomena and microfluidics. *Modeling and design validation techniques *Covers most types of Fuel Cell including SOFC *MATLAB and FEMLAB modelling codes *Translates basic phenomena into mathematical equations

Proton exchange membrane (PEM) fuel cells are promising clean energy converting devices with high efficiency and low to zero emissions. Such power sources can be used in transportation, stationary, portable and micro power applications. The key components of these fuel cells are catalysts and catalyst layers. “PEM Fuel Cell Electrocatalysts and Catalyst Layers” provides a comprehensive, in-depth survey of the field, presented by internationally renowned fuel cell scientists. The opening chapters introduce the fundamentals of electrochemical theory and fuel cell catalysis. Later chapters investigate the synthesis, characterization, and activity validation of PEM fuel cell catalysts. Further chapters describe in detail the integration of the electrocatalyst/catalyst layers into the fuel cell, and their performance validation. Researchers and engineers in the fuel cell industry will find this book a valuable resource, as will students of electrochemical engineering and catalyst synthesis.

PEM fuel cells have potential for meeting automotive industry`s power density and cost requirements, such as 0.8 kW/kg, 0.8 kW/1 and $30/kW. For automotive applications, the fuel cell power requirements are in the 10-100 kW range. As the first phase in reaching this power output, a 10 kW PEM fuel cell stack has been developed at Energy Partners. The stack consists of 50 cells with relatively large active area of 780 cm2. The main feature of the stack is the advanced membrane electrode assembly (MEA) developed by W.L. Gore & Associates, Inc. These novel MEAs consist of a thin composite perfluorinated polymer membrane with a catalyst layer with platinum loading of 0.3 Mg/cm2 on each side. The combination of reinforcement and thinness provides high membrane conductance and improved water distribution in the operating cell. In addition, the membrane has excellent mechanical properties (particularly when it is hydrated) and dimensional stability.

Polymer Electrolyte Membrane (PEM) fuel cells convert chemical energy in hydrogen into electrical energy with water as the only by-product. Thus, PEM fuel cells hold great promise to reduce both pollutant emissions and dependency on fossil fuels, especially for transportation—passenger cars, utility vehicles, and buses—and small-scale stationary and portable power generators. But one of the greatest challenges to realizing the high efficiency and zero emissions potential of PEM fuel cells technology is heat and water management. This book provides an introduction to the essential concepts for effective thermal and water management in PEM fuel cells and an assessment on the current status of fundamental research in this field. The book offers you: • An overview of current energy and environmental challenges and their imperatives for the development of renewable energy resources, including discussion of the role of PEM fuel cells in addressing these issues; • Reviews of basic principles pertaining to PEM fuel cells, including thermodynamics, electrochemical reaction kinetics, flow, heat and mass transfer; and • Descriptions and discussions of water transport and management within a PEM fuel cell, including vapor- and liquid-phase water removal from the electrodes, the effects of two-phase flow, and solid water or ice dynamics and removal, particularly the specialized case of starting a PEM fuel cell at sub-freezing temperatures (cold start) and the various processes related to ice formation.

This book covers all the proposed fuel cell systems including PEMFC, SOFC, PAFC, MCFC, regenerative fuel cells, direct alcohol fuel cells, and small fuel cells to replace batteries.

This book covers a significant number of R&D projects, performed mostly after 2000, devoted to the understanding and prevention of performance degradation processes in polymer electrolyte fuel cells (PEFCs). The extent and severity of performance degradation processes in PEFCs were recognized rather gradually. Indeed, the recognition overlapped with a significant number of industrial dem- strations of fuel cell powered vehicles, which would suggest a degree of technology maturity beyond the resaolution of fundamental failure mechanisms. An intriguing question, therefore, is why has there been this apparent delay in addressing fun- mental performance stability requirements. The apparent answer is that testing of the power system under fully realistic operation conditions was one prerequisite for revealing the nature and extent of some key modes of PEFC stack failure. Such modes of failure were not exposed to a similar degree, or not at all, in earlier tests of PEFC stacks which were not performed under fully relevant conditions, parti- larly such tests which did not include multiple on–off and/or high power–low power cycles typical for transportation and mobile power applications of PEFCs. Long-term testing of PEFCs reported in the early 1990s by both Los Alamos National Laboratory and Ballard Power was performed under conditions of c- stant cell voltage, typically near the maximum power point of the PEFC.

Today's consumers of portable electronics consumers are demanding devices not only deliver more power but also work healthy for the environment. This fact alone has lead major corporations like Intel, BIC, Duracell and Microsoft to believe that Microfuel Cells could be the next-generation power source for electronic products. Compact and readable, Microfuels Principles and Applications, offers engineers and product designers a reference unsurpassed by any other in the market. The book starts with a clear and rigorous exposition of the fundamentals engineering principles governing energy conversion for small electronic devices, followed by self-contained chapters concerning applications. The authors provide original points of view on all types of commercially available micro fuel cells types, including micro proton exchange membrane fuel cells, micro direct methanol fuel cells, micro solid oxide fuel cells and micro bio-fuel cells. The book also contains a detailed introduction to the fabrication of the components and the assembly of the system, making it a valuable reference both in terms of its application to product design and understanding micro engineering principles. - An overview of the micro fuel cell systems and applications - A detailed introduction to the fabrication of the components and the assembly of the system - Original points of view on prospects of micro fuel cells