Over the last century and a half, groundwaters have become contaminated by a growing number of organic and inorganic substances ranging from petroleum-derived hydrocarbons to radioactive compounds, to cancer-causing hexavalent chromium. The importance of uncontaminated groundwater for agriculture, human consumption, and the environmental health of ecosystems is paramount to the health and productivity of industrial society. Water scientists and managers are focused on developing cost-effective methods to reverse this trend.Several methodologies have been developed, however few are as cost-effective as the use of readily available materials, such as iron and organic compost, for absorbing and isolating contaminants within the matrix of a permeable barrier. The Handbook of Groundwater Remediation using Permeable Reactive Barriers presents readers with this latest technology and developments within four main sections:1. Innovations in Design, Construction, and Evaluation of PRBs2. Development of Reactive Materials3. Evaluations of Chemical and Biological Processes4. Case Studies of Permeable Reactive Barrier InstallationsThe Handbook is one of the first references specifically on this topic. It is an excellent fit for graduate students entering this emerging field as well as professionals conducting research or implementing this technology.

"Advances in Environmental Geotechnics" presents the latest developments in this interdisciplinary field. The topics covered include basic and advanced theories for modeling of geoenvironmental phenomena, testing and monitoring for geoenvironmental engineering, municipal solid wastes and landfill engineering, sludge and dredged soils, geotechnical reuse of industrial wastes, contaminated land and remediation technology, applications of geosynthetics in geoenvironmental engineering, geoenvironmental risk assessment, management and sustainability, ecological techniques and case histories. This proceedings includes papers authored by core members of ISSMGE TC5 (International Society of Soil Mechanics and Geotechnical Engineering---Environmental Geotechnics) and geoenvironmental researchers from more than 20 countries and regions. It is a valuable reference for geoenvironmental and geotechnical engineers as well as civil engineers. Yunmin Chen, Xiaowu Tang, and Liangtong Zhan are Professors at the Department of Civil Engineering of Zhejiang University, China.

... The goal of this field experiment was to achieve emplacement of a granular-iron permeable reactive barrier deeper than attempted before ...

Environmental remediation technologies to control or prevent pollution from hazardous waste material is a growing research area in academia and industry, and is a matter of utmost concern to public health, to improve ecology and to facilitate the redevelopment of a contaminated site. Recently, in situ and ex situ remediation technologies have been developed to rectify the contaminated sites, utilizing various tools and devices through physical, chemical, biological, electrical, and thermal processes to restrain, remove, extract, and immobilize mechanisms to minimize the contamination effects. This handbook brings altogether classical and emerging techniques for hazardous wastes, municipal solid wastes and contaminated water sites, combining chemical, biological and engineering control methods to provide a one-stop reference. This handbook presents a comprehensive and thorough description of several remediation techniques for contaminated sites resulting from both natural processes and anthropogenic activities. Providing critical insights into a range of treatments from chemical oxidation, thermal treatment, air sparging, electrokinetic remediation, stabilization/solidification, permeable reactive barriers, thermal desorption and incineration, phytoremediation, biostimulation and bioaugmentation, bioventing and biosparging through ultrasound-assisted remediation methods, electrochemical remediation methods, and nanoremediation, this handbook provides the reader an inclusive and detailed overview and then discusses future research directions. Closing chapters on green sustainable remediation, economics, health and safety issues, and environmental regulations around site remediation will make this a must-have handbook for those working in the field.

Remediation of groundwater is complex and often challenging. But the cost of pump and treat technology, coupled with the dismal results achieved, has paved the way for newer, better technologies to be developed. Among these techniques is permeable reactive barrier (PRB) technology, which allows groundwater to pass through a buried porous barrier that either captures the contaminants or breaks them down. And although this approach is gaining popularity, there are few references available on the subject. Until now. Permeable Reactive Barrier: Sustainable Groundwater Remediation brings together the information required to plan, design/model, and apply a successful, cost-effective, and sustainable PRB technology. With contributions from pioneers in this area, the book covers state-of-the-art information on PRB technology. It details design criteria, predictive modeling, and application to contaminants beyond petroleum hydrocarbons, including inorganics and radionuclides. The text also examines implementation stages such as the initial feasibility assessment, laboratory treatability studies (including column studies), estimation of PRB design parameters, and development of a long-term monitoring network for the performance evaluation of the barrier. It also outlines the predictive tools required for life cycle analysis and cost/performance assessment. A review of current PRB technology and its applications, this book includes case studies that exemplify the concepts discussed. It helps you determine when to recommend PRB, what information is needed from the site investigation to design it, and what regulatory validation is required.

While extensive research has been performed on many technological aspects of permeable reactive barriers and a number of contaminants have so far been successfully treated by PRB systems, long-term performance has not been extensively considered and little is known about the processes influencing long-term behaviour. This gap in our knowledge is all the more disadvantageous as design life has a decisive influence on the economic viability of PRBs. The book describes methods for evaluation and enhancement of the long-term performance of PRB systems, especially of those targeting heavy metals, specifically uranium, and organic contaminants by sorption and/or precipitation mechanisms. Major topics in the book are: - Selection and characterisation of suitable reactive materials - Characterisation of the relevant contaminant attenuation processes - Developing new contaminant-binding chemical compounds ("ligands") - Accelerated testing methods to assess the long-term performance of the attenuation mechanisms in PRBs - Evaluation of the influence of site characteristics on PRB performance - Monitoring of existing and new field installations - Coupling of electrokinetic techniques and PRB systems - Large-scale laboratory and field tests and their results It addresses the long-term performance of PRBs, an important feature of this novel remediation technology, systematically. It deals extensively with heavy metal removal, with special emphasis on uranium. A number of case studies, experiences with large-scale modelling and test site experiments provide insight into the practical application of the results. This volume will contribute to the science underpinning groundwater remediation, and this will result in the improvement of quality of life and health and safety.* A systematic approach to investigating the long-term performance of permeable reactive barriers* Development of new contaminant-binding chemical compounds ("ligands"), accelerated testing methods to assess the long-term performance, and efficiency enhancing electrokinetic techniques* Extensive data and information on a Hungarian uranium mining facility; once a carefully kept secret of the Soviet Union

This new edition discusses chemical and engineering principles as they apply to the cleanup and removal of hazardous chemicals from soil and groundwater. There is emphasis on environmental chemistry, soil science, microbiology, and plant science. The first part of the book provides an overview of the recent history of environmental contamination and the formulation of relevant regulations for hazardous waste site remediation. This part also provides a background for several salient aspects of site remediation (e.g., soil science, the site assessment process). The second part of the book examines field remediation technologies, including phytoremediation, bioremediation, and several chemical and physical technologies. Theory of operation, practical considerations, and possible environmental impacts and other consequences of their use are discussed. Covers both metal- and hydrocarbon-based contamination and remediation Many competitors only address one industry, or source, of contamination—this title provides an overview of all of the sources. Presents both the assessment of contaminated sites and the technologies currently available for environmental cleanup Effective for use in field situations and for academic (i.e., university course) use. Two new chapters: (i) the use of nanomaterials for remediation of contaminated soil and water; and (ii) revegetation of severely disturbed sites.

This book provides an overview of the current development status of remediation technologies involving electrochemical processes, which are used to clean up soils that are contaminated with different types of contaminants (organics, inorganics, metalloids and radioactive). Written by internationally recognized experts, it comprises 21 chapters describing the characteristics and theoretical foundations of various electrochemical applications of soil remediation. The book’s opening section discusses the fundamental properties and characteristics of the soil, which are essential to understand the processes that can most effectively remove organic and inorganic compounds. This part also focuses on the primary processes that contribute to the application of electrochemically assisted remediation, hydrodynamic aspects and kinetics of contaminants in the soil. It also reviews the techniques that have been developed for the treatment of contaminated soils using electrochemistry, and discusses different strategies used to enhance performance, the type of electrode and electrolyte, and the most important operating conditions. In turn, the book’s second part deals with practical applications of technologies related to the separation of pollutants from soil. Special emphasis is given to the characteristics of these technologies regarding transport of the contaminants and soil toxicity after treatment. The third part is dedicated to new technologies, including electrokinetic remediation and hybrid approaches, for the treatment of emerging contaminants by ex-situ and in-situ production of strong oxidant species used for soil remediation. It also discusses pre-pilot scale for soil treatment and the use of solar photovoltaic panels as an energy source for powering electrochemical systems, which can reduce both the investment and maintenance costs of electrochemically assisted processes.