This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems in the range of sizes from one to 100 nm- when one cannot apply equations or traditional thermodynamic models.

Surface chemistry is an essential and developing area of physical chemistry and one that has become increasingly interdisciplinary. The Second Edition of Surface Science: Foundations of Catalysis and Nanoscience has been fully revised and updated to reflect all the latest developments in the field and now includes an extensive discussion about nanoparticle growth and the quantum confinement effects in nanoscale systems. Two new chapters have been added and discuss The Liquid/Solid Interface and Non-Thermal Reactions, and Photon and Electron Stimulated Chemistry and Atom Manipulation. There are now many more worked examples included throughout to help students develop their problem-solving skills.

Now in a new edition, this book continues to set the standard for teaching readers how to be effective problem solvers, emphasizing the authors's signature methodologies that have taught over a half million students worldwide. This new edition provides a student-friendly approach that emphasizes the relevance of thermodynamics principles to some of the most critical issues of today and coming decades, including a wealth of integrated coverage of energy and the environment, biomedical/bioengineering, as well as emerging technologies. Visualization skills are developed and basic principles demonstrated through a complete set of animations that have been interwoven throughout.

This book provides a concise overview of thermodynamics, and is written in a manner which makes the difficult subject matter understandable. Thermodynamics is systematic in its presentation and covers many subjects that are generally not dealt with in competing books such as: Carathéodory's approach to the Second Law, the general theory of phase transitions, the origin of phase diagrams, the treatment of matter subjected to a variety of external fields, and the subject of irreversible thermodynamics.The book provides a first-principles, postulational, self-contained description of physical and chemical processes. Designed both as a textbook and as a monograph, the book stresses the fundamental principles, the logical development of the subject matter, and the applications in a variety of disciplines. This revised edition is based on teaching experience in the classroom, and incorporates many exercises in varying degrees of sophistication. The stress laid on a didactic, logical presentation, and on the relation between theory and experiment should provide a reader with a more intuitive understanding of the basic principles.Graduate students and professional chemists in physical chemistry and inorganic chemistry, as well as graduate students and professionals in physics who wish to acquire a more sophisticated overview of thermodynamics and related subject matter will find this book extremely helpful. - Takes the reader through various steps to understanding - Review of fundamentals - Development of subject matter - Applications in a variety of disciplines

This graduate-level textbook covers the major developments in surface sciences of recent decades, from experimental tricks and basic techniques to the latest experimental methods and theoretical understanding. It is unique in its attempt to treat the physics of surfaces, thin films and interfaces, surface chemistry, thermodynamics, statistical physics and the physics of the solid/electrolyte interface in an integral manner, rather than in separate compartments. It is designed as a handbook for the researcher as well as a study-text for graduate students. Written explanations are supported by 350 graphs and illustrations.

Small systems are a very active area of research and development due to improved instrumentation that allows for spatial resolution in the range of sizes from one to 100 nm. In this size range, many physical and chemical properties change, which opens up new approaches to the study of substances and their practical application. This affects both traditional fields of knowledge and many other new fields including physics, chemistry, biology, etc. This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems - when one cannot apply equations or traditional thermodynamic models.

"God made solids, but surfaces were the work of the devil." This statement by Nobel prize winner Wolfgang Paul emphasizes the diabolic nature of surfaces. Since surface properties deviate significantly from the bulk solid state, surface studies can be puzzling, misleading, and quite exciting! This book is an introduction to the basics of surface science including thermodynamics, surface structure, experimental probes, spectroscopy, microscopy, and ion-scattering. Surfaces are the external border of materials to the external worlds, thus by exploring surfaces one can investigate the material.

Thermodynamic Approaches in Engineering Systems responds to the need for a synthesizing volume that throws light upon the extensive field of thermodynamics from a chemical engineering perspective that applies basic ideas and key results from the field to chemical engineering problems. This book outlines and interprets the most valuable achievements in applied non-equilibrium thermodynamics obtained within the recent fifty years. It synthesizes nontrivial achievements of thermodynamics in important branches of chemical and biochemical engineering. Readers will gain an update on what has been achieved, what new research problems could be stated, and what kind of further studies should be developed within specialized research. - Presents clearly structured chapters beginning with an introduction, elaboration of the process, and results summarized in a conclusion - Written by a first-class expert in the field of advanced methods in thermodynamics - Provides a synthesis of recent thermodynamic developments in practical systems - Presents very elaborate literature discussions from the past fifty years

This new edition of Borgnakke's Fundamentals of Thermodynamics continues to offer a comprehensive and rigorous treatment of classical thermodynamics, while retaining an engineering perspective. With concise, applications-oriented discussion of topics and self-test problems, this text encourages students to monitor their own learning. This classic text provides a solid foundation for subsequent studies in fields such as fluid mechanics, heat transfer and statistical thermodynamics, and prepares students to effectively apply thermodynamics in the practice of engineering.