Excited States, Volume 3 deals with excited states and covers topics ranging from two-photon molecular spectroscopy in liquids and gases to time evolution of excited molecular states. Product energy distributions in the dissociation of polyatomic molecules are also discussed, along with the mechanism of optical nuclear polarization in molecular crystals and vibronic interactions and luminescence in aromatic molecules with non-bonding electrons. Comprised of five chapters, this volume begins with a didactic treatment of the theory of simultaneous two-photon absorption spectroscopy from the point of view concerned primarily with molecular gases and liquids. The basic theoretical quantity is shown to be an absorption tensor, as contrasted with the absorption vector of one-photon spectroscopy. The next chapter considers the time evolution of a molecular system interacting with a photon wave packet. The theory is applied to handle photon scattering from several physical models for molecular level structure in excited electronic states of polyatomic molecules. The remaining chapters explore various polyatomic decomposition processes and the basic features governing the internal energy distribution of the fragments; optical nuclear polarization in molecular crystals and vibronic interactions; and luminescence in aromatic molecules with non-bonding electrons. This book should be of interest to chemists and molecular physicists.

Higher Excited States of Polyatomic Molecules, Volume III focuses on higher electronic excitations in polyatomic molecules, with emphasis on excitations beyond 50,000 cm-1. This book explores the various transitions on the basis of their orbital characteristics. Organized into 22 chapters, this volume begins with an overview of the relationships between spectra of different molecules and between the results of various types of spectroscopy. This book then discusses the higher excited states involving Rydberg excitation. Other chapters explore the higher excited states in all classes of biological, organic, and inorganic molecules. This text further discusses the progress in the area of higher excitations in polyatomic atoms and the technique of multiphoton ionization (MPI) spectroscopy that yields a remarkable amount of spectroscopic information applicable to the vacuum-ultraviolet region. The final chapter deals with the vacuum-ultraviolet spectroscopy of biological materials. Analytical chemists, photochemists, molecular spectroscopists, and researchers will find this book extremely useful.

Higher Excited States of Polyatomic Molecules, Volume I focuses on the spectra in the vacuum-ultraviolet region between 50,000 and 100,000 cm-1. This book explores the higher excitations in molecules beyond 50,000 cm-1. Organized into three chapters, this volume starts with an overview of the excited-state properties of a molecule and the excited-state ionization potential. This book then proceeds with a discussion of the original classification of the properties as well as the types of excitations observed in the vacuum-ultraviolet. Other chapters discuss photoelectron spectroscopy, which is an independent, self-sustaining branch of molecular spectroscopy. This text examines as well the distinction between valence shell and Rydberg excitations. The final chapter deals with several topics, including the saturated molecules that are classified as having all valence electrons, the alkene absorption spectra, and the spectroscopic data on boron compounds. Analytical chemists, photochemists, molecular spectroscopists, and researchers will find this book extremely useful.

Excited States, Volume 2 is a collection of papers that deals with molecules in the excited states. The book describes the geometries of molecules in the excited electronic states. One paper describes the geometries of a diatomic molecule and of polyatomic molecules; it also discusses the determination of the many excited state geometries of molecules with two, three, or four atoms by techniques similar to diatomic spectroscopy. Another paper introduces an ordered theory related to excitons in pure and mixed molecular crystals. This paper also presents some experimental data such as those involving pure and neat crystals, very dilute isotopic mixed crystals, and medium dilute isotopic mixed crystals. The book also discusses the dynamics of primary photochemical processes including the classical theory of unimolecular reactions, the quantum theory of molecular reactions, and the theory of "nonchemical" radiationless processes. One paper also reviews the electron donor-acceptor complexes in their excited states. This book is suitable for nuclear physicists and researchers whose work involves molecular chemistry and solid state physics.

This volume presents applications of mathematical techniques for modelling and performance analysis of neural networks. The collection of articles is motivated by the observation that the theory of neural network dynamics, i.e. Neurodynamics, still has to be given a thorough mathematical foundation. Therefore, the volume comprises research work on different mathematical approaches to neural networks; analytical and numerical techniques of dynamical systems theory, geometrical techniques, and methods of statistical physics. Articles analyse dynamics of neural netwroks in general or concentrate on specific network models of biological or neurocomputing origin. A few of the articles serve as a good introduction to these subjects.

A unique guide to the application and theory of photothermalspectroscopy. This book debunks the myth that photothermal spectroscopy is toocomplicated for practical application to chemical analysis, anddemonstrates the advantages this technique has over conventionalspectroscopy in facilitating extremely sensitive measurements ofoptical absorption in homogeneous media. The book covers thesubject from the ground up, lists all practical considerationsneeded to obtain accurate results, and provides a working knowledgeof the various methods in use--including photo acoustics andphotopyroelectric techniques. Bringing together a wealth of information that has been scatteredthroughout the professional literature, Photothermal SpectroscopyMethods for Chemical Analysis covers methods and information thatshould be known to every analytical chemist, including: * Descriptions of photothermal spectroscopy using a consistentmathematical language * Helpful examples from the literature of analytical applicationsand current research * Illustrations of all important points, consistent equations, andnumerous original figures * A discussion of laser technology and how it is used to obtainaccurate results from extremely small samples of a few molecules * Everything spectroscopists need to know to construct their ownapparatus and use it to conduct successful experiments * Tips on how to interpret experimental results effectively whenusing nonlinear processes and in many other situations inphotothermal spectroscopy * Considerations for further study of heterogeneous sampleanalysis * Unified nomenclature of the patchwork of terms used byresearchers in analytical and physical chemistry, physics, andoptical engineering * Equations that are derived with the aid of a symbolic languageprocessor to ensure correct results Photothermal spectroscopy has seen major advances since the adventof laser technology twenty-five years ago. It is now possible,using a laser's coherent and powerful output, to obtain extremelysensitive measurements of optical absorption that exceed those ofmass spectroscopy by two or three times, and produce accurateresults from only a few molecules. Focusing on samples in homogeneous media, this book provides aunique guide--incorporating theory and application--to allavailable photothermal spectroscopy techniques for chemical andmaterial analysis. It uses a systematic approach in itscomprehensive treatment of the theory, and covers all the necessarybackground material, from laser optics to fluid dynamics. This accessible text describes the various processes used to detectthermal perturbation of a sample, ranging from optical excitationto nonlinear processes, and covers all optical principles necessaryto understand photothermal spectroscopy. When dealing withhydrodynamic equations that govern energy transfer in the samplematrix, it provides an original impulse-response approach. Inaddition, the book explains how to construct the apparatus oneneeds to conduct successful photothermal experiments, sincecommercial equipment is not available as in conventionalspectrophotometry. Throughout, this book draws on information from a wide range offields, including analytical spectroscopy, measurement physics,physical optics, and chemical dynamics. Providing clearexplanations at every turn, the author demonstrates a completeunderstanding of the theory and applications as a firm basis forthe correct interpretation of experimental results. For analytical chemists, as well as for students at the graduatelevel, Photothermal Spectroscopy Methods for Chemical Analysis isan unmatched resource that develops a consistent mathematical basisfor signal description, consolidates previous theories, andprovides invaluable insight into laser technology.

This handbook is a breakthrough in the understanding of the large number of spectral lines in diamond. Data on more than 2000 lines and bands are presented in 200 tables, including many unpublished results. With a novel organization scheme, the search for a specific line is greatly simplified as a benefit for researchers and students. In order to meet the interest in the understanding of the spectra, structure assignments for 80 % of the lines are given, of which 15 % only were published before. The majority of the structures for the 300 centers is explained in most cases for the first time. A key instrument in the interpretation is the analysis by donor-acceptor pair transitions. In a special chapter 95 such centers are listed and discussed, of which only two have been published before, the first one by the present author in 1994.

Covers the advantages of using photothermal spectroscopy over conventional absorption spectroscopy, including facilitating extremely sensitive measurements and non-destructive analysis This unique guide to the application and theory of photothermal spectroscopy has been newly revised and updated to include new methods and applications and expands on applications to chemical analysis and material science. The book covers the subject from the ground up, lists all practical considerations needed to obtain accurate results, and provides a working knowledge of the various methods in use. Photothermal Spectroscopy Methods, Second Edition includes the latest methods of solid state and materials analysis, and describes new chemical analysis procedures and apparatuses in the analytical chemistry sections. It offers a detailed look at the optics, physical principles of heat transfer, and signal analysis. Information in the temperature change and optical elements in homogeneous samples and photothermal spectroscopy in homogeneous samples has been updated with a better description of diffraction effects and calculations. Chapters on analytical measurement and data processing and analytical applications are also updated and include new information on modern applications and photothermal microscopy. Finally, the Photothermal Spectroscopy of Heterogeneous Sample chapter has been expanded to incorporate new methods for materials analysis. New edition updates and expands on applications to chemical analysis and materials science, including new methods of solid state and materials analysis Includes new chemical analysis procedures and apparatuses Provides an unmatched resource that develops a consistent mathematical basis for signal description, consolidates previous theories, and provides invaluable insight into laser technology Photothermal Spectroscopy Methods, Second Edition will appeal to researchers from both academia and industry (graduate students, postdocs, research scientists, and professors) in the general field of analytical chemistry, optics, and materials science, and researchers and engineers at scientific instrument developers in fields related to photonics and spectroscopy.

Given the inherent complexity of food products, most instrumental techniques employed for quality and authenticity evaluation (e.g., chromatographic methods) are time demanding, expensive, and involve a considerable amount of manual labor. Therefore, there has been an increasing interest in simpler, faster, and reliable analytical methods for assessing food quality attributes. Spectroscopic Methods in Food Analysis presents the basic concepts of spectroscopic methods, together with a discussion on the most important applications in food analysis. The determination of product quality and authenticity and the detection of adulteration are major issues in the food industry, causing concern among consumers and special attention among food manufacturers. As such, this book explains why spectroscopic methods have been extensively employed to the analysis of food products as they often require minimal or no sample preparation, provide rapid and on-line analysis, and have the potential to run multiple tests on a single sample (i.e., non-destructive). This book consists of concepts related to food quality and authenticity, that are quite broad, given the different demands of the manufacturer, the consumer, the surveillance and the legislative bodies that ultimately provide healthy and safe products.

Using lasers to induce and probe surface processes has the advantages of quantum state specificity, species selectivity, surface sensitivity, fast time-resolution, high frequency resolution, and accessibility to full pressure ranges. These advantages make it highly desirable to use light to induce, control, or monitor surface chemical and physical processes. Recent applications of laser based techniques in studying surface processes have stimulated new developments and enabled the understanding of fundamental problems in energy transfer and reactions. This volume will include discussions on spectroscopic techniques, energy transfer, desorption dynamics, and photochemistry.