Enantioselective C C Bond Forming Reactions
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Author |
: |
Publisher |
: Elsevier |
Total Pages |
: 338 |
Release |
: 2023-12-01 |
ISBN-10 |
: 9780443237003 |
ISBN-13 |
: 044323700X |
Rating |
: 4/5 (03 Downloads) |
Synopsis Enantioselective C-C Bond Forming Reactions by :
Enantioselective C-C Bond Forming Reactions: From Metal Complex-, Organo-, and Bio-catalyzed Perspectives, Volume 73 in the Advances in Catalysis series, highlights new advances in the field, with this new volume presenting interesting chapters on topics such as An introduction to Chirality, Metal-catalyzed stereoselective C-C-bond forming reactions, Enantioselective C-C bond forming reactions promoted by organocatalysts based on unnatural amino acid derivatives, Enantioselective C-C bond formation in complex multicatalytic system, Gold-based multicatalytic systems for enantioselective C-C Bond forming reactions, Novel enzymatic tools for C-C bond formation through the development of new-to-nature biocatalysis, and more. - Provides the authority and expertise of leading contributors from an international board of authors - Presents the latest release in Advances in Catalysis serials - Updated release includes the latest information in the field
Author |
: Rainer Mahrwald |
Publisher |
: Springer Science & Business Media |
Total Pages |
: 400 |
Release |
: 2011-08-03 |
ISBN-10 |
: 9789048138678 |
ISBN-13 |
: 9048138671 |
Rating |
: 4/5 (78 Downloads) |
Synopsis Enantioselective Organocatalyzed Reactions II by : Rainer Mahrwald
Organocatalyzed Reactions I and II presents a timely summary of organocatalysed reactions including: a) Enantioselective C-C bond formation processes e.g. Michael-addition, Mannich-reaction, Hydrocyanation (Strecker-reaction), aldol reaction, allylation, cycloadditions, aza-Diels-Alder reactions, benzoin condensation, Stetter reaction, conjugative Umpolung, asymmetric Friedel-Crafts reactions; b) Asymmetric enantioselective reduction processes e.g. Reductive amination of aldehydes or ketones, asymmetric transfer hydrogenation; c) Asymmetric enantioselective oxidation processes; d) Asymmetric epoxidation, Bayer-Villiger oxidation; e) Enantioselective a-functionalization; f) A-alkylation of ketones, a-halogenation and a-oxidation of carbonyl compounds.
Author |
: Mark Stephen Taylor |
Publisher |
: |
Total Pages |
: 654 |
Release |
: 2005 |
ISBN-10 |
: OCLC:61888884 |
ISBN-13 |
: |
Rating |
: 4/5 (84 Downloads) |
Synopsis Enantioselective, Catalytic Carbon-carbon Bond-forming Reactions by : Mark Stephen Taylor
Author |
: Rainer Mahrwald |
Publisher |
: Springer Science & Business Media |
Total Pages |
: 400 |
Release |
: 2011-08-03 |
ISBN-10 |
: 9789048138678 |
ISBN-13 |
: 9048138671 |
Rating |
: 4/5 (78 Downloads) |
Synopsis Enantioselective Organocatalyzed Reactions II by : Rainer Mahrwald
Organocatalyzed Reactions I and II presents a timely summary of organocatalysed reactions including: a) Enantioselective C-C bond formation processes e.g. Michael-addition, Mannich-reaction, Hydrocyanation (Strecker-reaction), aldol reaction, allylation, cycloadditions, aza-Diels-Alder reactions, benzoin condensation, Stetter reaction, conjugative Umpolung, asymmetric Friedel-Crafts reactions; b) Asymmetric enantioselective reduction processes e.g. Reductive amination of aldehydes or ketones, asymmetric transfer hydrogenation; c) Asymmetric enantioselective oxidation processes; d) Asymmetric epoxidation, Bayer-Villiger oxidation; e) Enantioselective a-functionalization; f) A-alkylation of ketones, a-halogenation and a-oxidation of carbonyl compounds.
Author |
: |
Publisher |
: |
Total Pages |
: |
Release |
: 2011 |
ISBN-10 |
: OCLC:756234934 |
ISBN-13 |
: |
Rating |
: 4/5 (34 Downloads) |
Synopsis Enantioselective Organocatalyzed Reactions II by :
Author |
: Xiangqian Liu |
Publisher |
: |
Total Pages |
: 139 |
Release |
: 2016* |
ISBN-10 |
: OCLC:983469297 |
ISBN-13 |
: |
Rating |
: 4/5 (97 Downloads) |
Synopsis Development of Nickel-catalyzed C-C Bond Forming Reactions and Catalytic Enantioselective Trifluoromethylthiolations by : Xiangqian Liu
Author |
: Françoise Colobert |
Publisher |
: John Wiley & Sons |
Total Pages |
: 240 |
Release |
: 2019-08-29 |
ISBN-10 |
: 9783527810840 |
ISBN-13 |
: 3527810846 |
Rating |
: 4/5 (40 Downloads) |
Synopsis C-H Activation for Asymmetric Synthesis by : Françoise Colobert
Provides, in one handbook, comprehensive coverage of one of the hottest topics in stereoselective chemistry Written by leading international authors in the field, this book introduces readers to C-H activation in asymmetric synthesis along with all of its facets. It presents stereoselective C-H functionalization with a broad coverage, from outer-sphere to inner-sphere C-H bond activation, and from the control of olefin geometry to the induction of point, planar and axial chirality. Moreover, methods wherein asymmetry is introduced either during the C-H activation or in a different elementary step are discussed. Presented in two parts?asymmetric activation of C(sp3)-H bonds and stereoselective synthesis implying activation of C(sp2)-H bonds?CH-Activation for Asymmetric Synthesis showcases the diversity of stereogenic elements, which can now be constructed by C-H activation methods. Chapters in Part 1 cover: C(sp3)-H bond insertion by metal carbenoids and nitrenoids; stereoselective C-C bond and C-N bond forming reactions through C(sp3)?H bond insertion of metal nitrenoids; enantioselective intra- and intermolecular couplings; and more. Part 2 looks at: C-H activation involved in stereodiscriminant step; planar chirality; diastereoselective formation of alkenes through C(sp2)?H bond activation; amongst other methods. -Covers one of the most rapidly developing fields in organic synthesis and catalysis -Clearly structured in two parts (activation of sp3- and activation of sp2-H bonds) -Edited by two leading experts in C-H activation in asymmetric synthesis CH-Activation for Asymmetric Synthesis will be of high interest to chemists in academia, as well as those in the pharmaceutical and agrochemical industry.
Author |
: Izzat Tiedje Raheem |
Publisher |
: |
Total Pages |
: 834 |
Release |
: 2007 |
ISBN-10 |
: 0549408991 |
ISBN-13 |
: 9780549408994 |
Rating |
: 4/5 (91 Downloads) |
Synopsis I. Enantioselective Total Synthesis of Quinine and Quinidine by : Izzat Tiedje Raheem
II. Thiourea-catalyzed enantioselective C-C bond-forming reactions. The discovery, development, and mechanistic study of new thiourea-catalyzed asymmetric C-C bond-forming reactions are detailed.
Author |
: David Linder |
Publisher |
: |
Total Pages |
: 114 |
Release |
: 2008 |
ISBN-10 |
: OCLC:428366943 |
ISBN-13 |
: |
Rating |
: 4/5 (43 Downloads) |
Synopsis Enantioselective CpRu-catalyzed Decarboxylative C-C Bond Forming Reactions by : David Linder
La combinaison du précatalyseur stable à l'air [CpRu([eta]6-C10H8)] [PF6] avec des ligands de type pyridine-monooxazoline a permis de développer une nouvelle stratégie pour effectuer des réactions de substitution allyliques avec des conditions expérimentales simples. Cette famille de ligands est apparue particulièrement appropriée pour effectuer l'étude de réactions du type réarrangement de Carroll. Le mécanisme de cette réaction a été étudié et un cycle catalytique raisonnable en a découlé. Une stratégie de double activation par co-catalyse a donc été développée: l'utilisation synergique de sels de magnésium a permis d'effectuer ces réactions à température ambiante et donc de manière plus sélective.
Author |
: Arnald Grabulosa |
Publisher |
: Royal Society of Chemistry |
Total Pages |
: 521 |
Release |
: 2011 |
ISBN-10 |
: 9781849731232 |
ISBN-13 |
: 1849731233 |
Rating |
: 4/5 (32 Downloads) |
Synopsis P-stereogenic Ligands in Enantioselective Catalysis by : Arnald Grabulosa
P-stereogenic ligands were among the first to be used in asymmetric catalysis but synthetic difficulties and prejudices have hampered their development. However, continuous screening for new chiral ligands means that they can no longer be ignored and this rigorous reference source reflects their renaissance.The book is filled with many examples from recent primary literature. The synthetic chemist will easily be able to follow the preparation methods which are accompanied by a description of the challenges and limitations. Those working in homogenous catalysis, and wanting to increase their repertoire of ligands, will be able to establish which have already been used in each reaction and their performance.This book provides comprehensive coverage of the application of P-stereogenic ligands in homogeneous catalysis. It begins with a brief chapter on generalities of P-stereogenic compounds: history, configurational stability, and interconversions among them.The book then goes on to describe the main preparative methods, from resolution of racemates to enantioselective catalysis, before focusing on the catalytic applications of P-stereogenic ligands. Chapter 7 describes the use of the ligands in catalytic hydrogenation and related reactions whereas chapter 8 deals with other reactions, mainly C-C bond forming reactions. The aim of these two final chapters is to give an outline of the usefulness of the ligands in homogeneous catalysis.