The new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basicsof thermodynamics and electrode kinetics to transport phenomena inelectrolytes, metals, and semiconductors. Newly updated andexpanded, the Third Edition covers important new treatments, ideas,and technologies while also increasing the book's accessibility forreaders in related fields. Rigorous and complete presentation of the fundamentalconcepts In-depth examples applying the concepts to real-life designproblems Homework problems ranging from the reinforcing to the highlythought-provoking Extensive bibliography giving both the historical developmentof the field and references for the practicing electrochemist.

The new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basics of thermodynamics and electrode kinetics to transport phenomena in electrolytes, metals, and semiconductors. Newly updated and expanded, the Third Edition covers important new treatments, ideas, and technologies while also increasing the book's accessibility for readers in related fields. Rigorous and complete presentation of the fundamental concepts In-depth examples applying the concepts to real-life design problems Homework problems ranging from the reinforcing to the highly thought-provoking Extensive bibliography giving both the historical development of the field and references for the practicing electrochemist.

The new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basics of thermodynamics and electrode kinetics to transport phenomena in electrolytes, metals, and semiconductors. Newly updated and expanded, the Third Edition covers important new treatments, ideas, and technologies while also increasing the book's accessibility for readers in related fields. Rigorous and complete presentation of the fundamental concepts In-depth examples applying the concepts to real-life design problems Homework problems ranging from the reinforcing to the highly thought-provoking Extensive bibliography giving both the historical development of the field and references for the practicing electrochemist.

Atomic-Scale Modelling of Electrochemical Systems A comprehensive overview of atomistic computational electrochemistry, discussing methods, implementation, and state-of-the-art applications in the field The first book to review state-of-the-art computational and theoretical methods for modelling, understanding, and predicting the properties of electrochemical interfaces. This book presents a detailed description of the current methods, their background, limitations, and use for addressing the electrochemical interface and reactions. It also highlights several applications in electrocatalysis and electrochemistry. Atomic-Scale Modelling of Electrochemical Systems discusses different ways of including the electrode potential in the computational setup and fixed potential calculations within the framework of grand canonical density functional theory. It examines classical and quantum mechanical models for the solid-liquid interface and formation of an electrochemical double-layer using molecular dynamics and/or continuum descriptions. A thermodynamic description of the interface and reactions taking place at the interface as a function of the electrode potential is provided, as are novel ways to describe rates of heterogeneous electron transfer, proton-coupled electron transfer, and other electrocatalytic reactions. The book also covers multiscale modelling, where atomic level information is used for predicting experimental observables to enable direct comparison with experiments, to rationalize experimental results, and to predict the following electrochemical performance. Uniquely explains how to understand, predict, and optimize the properties and reactivity of electrochemical interfaces starting from the atomic scale Uses an engaging “tutorial style” presentation, highlighting a solid physicochemical background, computational implementation, and applications for different methods, including merits and limitations Bridges the gap between experimental electrochemistry and computational atomistic modelling Written by a team of experts within the field of computational electrochemistry and the wider computational condensed matter community, this book serves as an introduction to the subject for readers entering the field of atom-level electrochemical modeling, while also serving as an invaluable reference for advanced practitioners already working in the field.

Electrochemical Power Sources: Fundamentals, Systems, and Applications: Hydrogen Production by Water Electrolysis offers a comprehensive overview about different hydrogen production technologies, including their technical features, development stage, recent advances, and technical and economic issues of system integration. Allied processes such as regenerative fuel cells and sea water electrolysis are also covered. For many years hydrogen production by water electrolysis was of minor importance, but research and development in the field has increased significantly in recent years, and a comprehensive overview is missing. This book bridges this gap and provides a general reference to the topic.Hydrogen production by water electrolysis is the main technology to integrate high shares of electricity from renewable energy sources and balance out the supply and demand match in the energy system. Different electrochemical approaches exist to produce hydrogen from RES (Renewable Energy Sources). - Covers the fundamentals of hydrogen production by water electrolysis - Reviews all relevant technologies comprehensively - Outlines important technical and economic issues of system integration - Includes commercial examples and demonstrates electrolyzer projects

Safety of Lithium Batteries describes how best to assure safety during all phases of the life of Lithium ion batteries (production, transport, use, and disposal). About 5 billion Li-ion cells are produced each year, predominantly for use in consumer electronics. This book describes how the high-energy density and outstanding performance of Li-ion batteries will result in a large increase in the production of Li-ion cells for electric drive train vehicle (xEV) and battery energy storage (BES or EES) purposes. The high-energy density of Li battery systems comes with special hazards related to the materials employed in these systems. The manufacturers of cells and batteries have strongly reduced the hazard probability by a number of measures. However, absolute safety of the Li system is not given as multiple incidents in consumer electronics have shown. - Presents the relationship between chemical and structure material properties and cell safety - Relates cell and battery design to safety as well as system operation parameters to safety - Outlines the influences of abuses on safety and the relationship to battery testing - Explores the limitations for transport and storage of cells and batteries - Includes recycling, disposal and second use of lithium ion batteries

This is the first of two volumes offering the very first comprehensive treatise of self-organization and non-linear dynamics in electrochemical systems. The second volume covers spatiotemporal patterns and the control of chaos. The content of both volumes is organized so that each description of a particular electrochemical system is preceded by an introduction to basic concepts of nonlinear dynamics, in order to help the reader unfamiliar with this discipline to understand at least fundamental concepts and the methods of stability analysis. The presentation of the systems is not limited to laboratory models but stretches out to real-life objects and processes, including systems of biological importance, such as neurons in living matter. Marek Orlik presents a comprehensive and consistent survey of the field.

This book is for anyone interested in renewable energy for a sustainable future of mankind. Batteries, fuel cells, capacitors, electrolyzers and solar cells are explained at the molecular level and at the power plant level, in their historical development, in their economical and political impact, and social change. Cases from geophysics and astronomy show that electrochemistry is not confined to the small scale. Examples are shown and exercised.

The storage of electroenergy is an essential feature of modem energy technologies. Unfortunately, no economical and technically feasible method for the solution of this severe problem is presently available. But electrochemistry is a favourite candidate from an engineering point of view. It promises the highest energy densities of all possible alternatives. If this is true, there will be a proportionality between the amount of electricity to be stored and the possible voltage, together with the mass of materials which make this storage possible. Insofar it is a matter of material science to develop adequate systems. Electricity is by far the most important secondary energy source. The present production rate, mainly in the thermal electric power stations, is in the order of 1.3 TW. Rechargeable batteries (RB) are of widespread use in practice for electroenergy storage and supply. The total capacity of primary and rechargeable batteries being exploited is the same as that of the world electric power stations. However, the important goal in the light of modem energy technology, namely the economical storage of large amounts of electricity for electric vehicles, electric route transport, load levelling, solar energy utilization, civil video & audio devices, earth and spatial communications, etc. will not be met by the presently available systems. Unless some of the new emerging electrochemical systems are established up to date, RB's based on aqueous acidic or alkali accumulators are mainly produced today.