Diazo Compounds: Properties and Synthesis focuses on the properties and syntheses of aliphatic diazo compounds. This monograph explores the application of diazo compounds in organic synthesis. Organized into two parts encompassing 16 chapters, this book starts with an overview of the structurally inherent effects of diazoalkenes. This monograph then examines the most important contribution of diazo compounds to the chemistry of carbenes and cycloadditions. Other chapters deal with structure, thermal behavior, acidic decomposition, spectroscopic properties, photochemistry of diazoalkenes, and synthetic methods. This book further discusses the qualitative and quantitative studies of the thermal stabilities of alkyl and aryl diazomethanes. The final chapter deals with the isotope-labeled diazo compounds that are of great importance for investigations of organic reaction mechanisms. This book is intended for chemists with an interest in the synthetic application of diazo compounds. Students and researchers engaged in the study of the physical properties of diazo compounds will find this book extremely useful.

Heinrich Zollinger Diazo Chemistry I Aromatic and Heteroaromatic Compounds By the author of Color Chemistry! Diazo compounds play an important role as reaction intermediates and reagents in organic synthesis. This book is a critical, well-referenced and eminently readable introduction to the chemistry of aromatic and heteroaromatic diazo compounds. It provides well-researched information that could otherwise be obtained only by costly and time-consuming searches of multi-volume treatises and the original literature. Topics covered in depth include: preparation and structure of diazo compounds kinetics and mechanism of diazotizations reactions of diazo compounds applications in organic synthesis Many tables and reaction schemes as well as copious literature citations make this book a highly valuable reference work for synthetic organic chemists, industrial chemists and color chemists. Also forthcoming: Volume 2 of Diazo Chemistry covering aliphatic, inorganic and organometallic compounds!

The most complete resource in functional group chemistry Patai's Chemistry of Functional Groups is one of chemistry's landmark book series in organic chemistry. An indispensible resource for the organic chemist, this is the most comprehensive reference available in functional group chemistry. Founded in 1964 by the late Professor Saul Patai, the aim of Patai's Chemistry of Functional Groups is to cover all the aspects of the chemistry of an important functional group in each volume, with the emphasis not only on the functional group but on the whole molecule.

The foundations of the chemical dyestuffs industry were laid in 1856 when W. H. Perkin discovered the dye Mauveine. At approximately the same time modern chemistry was establishing itself as a major science. Thus, the chemistry of dyes became that branch of organic chemistry in which the early scientific theories were first used. This early eminence has now been largely lost. In fact, many of our academic and teaching institutions pay little attention to this vitally important branch of organic chemistry. We believe that this book will help to rectify this unfortunate situation. The majority of books that have been published on the subject of dyes have been technologically biased and, in our opinion, do not appeal to the mainstream organic chemist. We have, therefore, aimed at producing a book which emphasises the role of organic chemistry in dyestuffs and we have included appropriate modern theories, especially the modern molecular orbital approaches. We have assumed that the reader possesses a knowledge of the basic principles of organic chemistry;* the only other requirement is a general interest in organic chemistry.** The book should interest the newcomer to chemistry, the established academic, and the dyestuffs chemist himself.

Advances in Heterocyclic Chemistry

The objective of this book is to acquaint the reader with a novel class of photochemical oxidants and polymerization initiators that have become widely accepted in industry. As most of the work with these materials is reported in the patent literature, an effort has been made to study this area of scientific activity, as well as present a thorough review of the journal publications. Photochemistry, History and Commercial Applications of HABIs also presents new technologies such as waveguides, holography along with some more traditional applications (i.e. filters, litho plates, and photoresists). - A complete review of technology associated with hexaarylbiimidazoles

Since its original appearance in 1977, Advanced Organic Chemistry has found wide use as a text providing broad coverage of the structure, reactivity and synthesis of organic compounds. The Fourth Edition provides updated material but continues the essential elements of the previous edition. The material in Part A is organized on the basis of fundamental structural topics such as structure, stereochemistry, conformation and aromaticity and basic mechanistic types, including nucleophilic substitution, addition reactions, carbonyl chemistry, aromatic substitution and free radical reactions. The material in Part B is organized on the basis of reaction type with emphasis on reactions of importance in laboratory synthesis. As in the earlier editions, the text contains extensive references to both the primary and review literature and provides examples of data and reactions that illustrate and document the generalizations. While the text assumes completion of an introductory course in organic chemistry, it reviews the fundamental concepts for each topic that is discussed. The Fourth Edition updates certain topics that have advanced rapidly in the decade since the Third Edition was published, including computational chemistry, structural manifestations of aromaticity, enantioselective reactions and lanthanide catalysis. The two parts stand alone, although there is considerable cross-referencing. Part A emphasizes quantitative and qualitative description of structural effects on reactivity and mechanism. Part B emphasizes the most general and useful synthetic reactions. The focus is on the core of organic chemistry, but the information provided forms the foundation for future study and research in medicinal and pharmaceutical chemistry, biological chemistry and physical properties of organic compounds. The New Revised 5th Edition will be available shortly. For details, click on the link in the right-hand column.