Chemical Kinetics and Process Dynamics in Aquatic Systems is devoted to chemical reactions and biogeochemical processes in aquatic systems. The book provides a thorough analysis of the principles, mathematics, and analytical tools used in chemical, microbial, and reactor kinetics. It also presents a comprehensive, up-to-date description of the kinetics of important chemical processes in aquatic environments. Aquatic photochemistry and correlation methods (e.g., LFERs and QSARs) to predict process rates are covered. Numerous examples are included, and each chapter has a detailed bibliography and problems sets. The book will be an excellent text/reference for professionals and students in such fields as aquatic chemistry, limnology, aqueous geochemistry, microbial ecology, marine science, environmental and water resources engineering, and geochemistry.

Aquatic systems play a salient role in the complex processes of energy and matter exchange between the geosphere and the atmosphere. For example, reactions taking place in cloud water droplets can substantially alter the atmospheric budget and chemistry of trace gases; pollution induced weathering reactions at water/soil interfaces can affect the availability of nutrients and increase the concentration of potentially toxic metals in groundwaters. Moreover, the inextricable links between the water cycle, the geosphere and the atmosphere ensure that apparently localized environmental problems have increasingly impacts in other parts of the world. To identify local-to-global scale variables associated with environmental changes, a focus must be placed on the recognition of processes, rather than a continued reliance on monitoring state variables. However, in heterogeneous aquatic systems, small scale aspects of a process under observation may not be summed directly to obtain regional estimates because of process nonlinearities with change in scale. To understand this, the integrated use of measurements across a range of scales is required.

Considering that environmental science draws students and practitioners with widely varied backgrounds, there is a need for materials that help readers to grow their knowledge of fundamental principles from chemistry, physics, and biology to understand, describe, and predict the ways in which constituents (sediment, nutrients, organic matter, etc.) interact and move in aquatic systems (rivers, lakes, groundwater, and the atmosphere). Aquatic Environmental Systems: An Interdisciplinary Approach for Scientists and Engineers focuses on developing a common vocabulary and a rigorous material balance-based approach to understanding these movements and interactions. It examines the key properties of water and the ways they impact the behavior of water in the environment, providing a focused enumeration of those aspects of water structure that have direct and profound impacts on aquatic environmental systems. Features: Provides open-ended exercises to allow students to tailor work to their personal local/regional interests Focuses on conveying understanding of the underlying principles and assumptions/limitations which are frequently underemphasized or overlooked entirely in other books Deemphasizes straight memorization while focusing on methods that can be applied to more broad-based problem solving Accommodates a wide range of mathematics skills and backgrounds

This book describes advances in this new, fast developing science, which seeks to decipher fundamental mechanisms ruling the behaviour in water, soils, atmosphere, food and living organisms of toxic metals, fossil fuels, pesticides and other organic pollutants. Sections on eco-toxicology, green chemistry, and analytical chemistry round out this thorough survey of conditions and analytical techniques in an emerging specialty.

It is presently well recognized that total concentrations of trace elements in any environmental compartment supply insufficient information to understand important phenomena. The distinction and separate analysis of specific chemical species are essential for understanding cycles in the aquatic environment, involving identification and quantification of sources, transport pathways, distributions and sinks, or, in the area of interactions between trace elements and organisms to understand uptake, distribution, excretion mechanisms and effects. In the past, various ways have been developed to determine the nature and extent of complexation of trace elements in natural systems. Approaches have been followed along very different lines. These have not always been fully appreciated by specialists working in even related fields of complexation research. The first International Symposium on the Complexation of Trace metals in Natural Waters was held at the Netherlands Institute for Sea Research (NIOZ, Texel, the Netherlands from 2-6 May 1983. The scientific programme was planned by the chief organizers Drs. C.J.M. Kramer and J.C. Duinker (NIOZ) together with Prof. Dr. H.W. Nurnberg (Kernforschungsanlage, Julich, Federal Republic of Germany) and Dr. M. Branica (Rudjer Boskovic Institute, Zagreb, Yugoslavia).

Chemical and Biological Regulation of Aquatic Systems covers the fundamentals of chemical and microbial process that control the quality of surface water. Topics discussed include the nature and environmental role of surface, complexation and redox reactions; fluxes in the water column and at sediment-water interface; bioavailability; intra- and extra-cellular processes; interactions of microbes with their environment; and microbial ecology. Basic principles are clearly explained and important examples are described in each case. For each environmental process, the respective roles of chemistry and biology are explained. The book features 600 references, 140 figures, and 55 tables. It's an excellent text for students in environmental sciences, researchers involved in quality control, and government and industry professionals who need to learn the fundamentals of an integrated approach to aquatic systems.

Overviews of the source, supply and variability of DOM, surveys of the processes that mediate inputs to microbial food webs, and syntheses consolidating research findings provide a comprehensive review of what is known of DOM in freshwater. This book will be important to anyone interested in understanding the fundamental factors associated with DOM that control aquatic ecosystems."--BOOK JACKET.

Major advancement in the U-Th measurement techniques since the 1990's have resulted in new opportunities for the use of these nuclides to probe into aquatic processes in greater detail. U-Th Series Nuclides in Aquatic Systems provides state-of-the-art reviews on the applications of U-Th series nuclides to "time" and "tag" in a variety of processes occurring in aquatic systems. - State of art reviews on the applications of U-Th Series nuclides to 'time'and 'tag' key processes occurring in aquatic systems. - Self-contained, each chapter presents nuclide source functions, processes regulating their distributions and models used to describe them - Emphasizes current thinking in the field and future directions

This book provides a detailed examination of the concentration, form and cycling of trace metals and metalloids through the aquatic biosphere, and has sections dealing with the atmosphere, the ocean, lakes and rivers. It discusses exchanges at the water interface (air/water and sediment/water) and the major drivers of the cycling, concentration and form of trace metals in aquatic systems. The initial chapters focus on the fundamental principles and modelling approaches needed to understand metal concentration, speciation and fate in the aquatic environment, while the later chapters focus on specific environments, with case studies and research highlights. Specific examples deal with metals that are of particular scientific interest, such as mercury, iron, arsenic and zinc, and the book deals with both pollutant and required (nutrient) metals and metalloids. The underlying chemical principles controlling toxicity and bioavailability of these elements to microorganisms and to the aquatic food chain are also discussed. Readership: Graduate students studying environmental chemistry and related topics, as well as scientists and managers interested in the cycling of trace substances in aqueous systems Additional resources for this book can be found at: www.wiley.com/go/mason/tracemetals.