This text introduces the beginner to the field with a solid development of the fundamentals, without getting bogged down in details. It provides an insight that can only be found from the author's 40+ years of experience

Amidst developments in nanotechnology and successes in catalytic emulsion polymerization of olefins, polymerization in dispersed media is arousing an increasing interest from both practical and fundamental points of view. This text describes ultramodern approaches to synthesis, preparation, characterization, and functionalization of latexes, nanopa

Amidst developments in nanotechnology and successes in catalytic emulsion polymerization of olefins, polymerization in dispersed media is arousing an increasing interest from both practical and fundamental points of view. This text describes ultramodern approaches to synthesis, preparation, characterization, and functionalization of latexes, nanoparticles, and numerous additional colloidal polymer systems. In chapters contributed by leading international researchers, it communicates critical parameters for method selection, presents guidelines for controlling structural and colloid properties, presents recent results and information on polymer colloids, and describes other tools to assist in the production of desirable outcomes.

From blood to milk, pumice to gelatine, most scientists interact with colloids on a daily basis without any real knowledge of their nature. Building on the success of the first edition, Colloids and Interfaces with Surfactants and Polymers Second Edition is a user-friendly, non-technical introduction to colloids and interfaces. Includes: Many practical examples of colloid and interface science An enhanced section on fluorescence microscopy, a widely used technique in biological systems for the optical imaging of cellular structures A new section on phenomenology (the principle of time/temperature superposition), which enables the experimentalist to extend the frequency range of their rheological instruments New information on sedimentation and strategies for the control of sedimentation, which is critical in many dispersions of commercial importance Fresh treatments of traditional theoretical topics like the electrical double-layer, colloidal interactions, wetting behavior and light scattering, as well as more recent advances in polymer science, statistical mechanics and the use of neutrons In-depth discussions of widely used techniques with mathematics used in a straight-forward way so quantitative descriptions of colloid and interface properties can be derived Colloids and Interfaces with Surfactants and Polymers Second Edition explains all the fundamental concepts of colloids and interfaces as well as detailing some of the more advanced aspects which might be useful in specific applications. Intended for undergraduate and graduate courses in colloids and soft materials, the book is also relevant to those in the chemical, coatings, cosmetics, ceramics, food, pharmaceutical and oil industries. For Powerpoint slides of all the figures in the book, please see the Instructor Companion website at http://bcs.wiley.com/he-bcs/Books?action=index&bcsId=5121&itemId=0470518804

Science and Technology of Polymer Colloids G. W. Poehlein, R. H. Ottewill, J. W. Goodwin (editors) Polymer colloids, more commonly known as latexes, are important in the manufacture of synthetic elastomers, commodity polymers, surface coatings, adhesive and numerous specialty products. The significant growth of the commercial production of polymer latexes during the past decade has been due to a number of factors. First, water-based systems, especially paints and coatings, avoid many of the environ mental problems associated with the solvent-based systems. Second, polymer colloid products can be custom designed to meet a wide range of application requirements. Third, large scale emulsion polymeri zation proceeds smoothly and controllably with a wide range of monomers to produce stable polymer colloids of high molecular weight Polymer colloids are also important in functional scientific studies This importance arises from the spherical shape of the particles, range of attainable particle diameters and the uniformity of their size distribution, and the possibility of controlling and character izing the particle surface. Polymer colloids are useful as size standards in microscopy and in instrument calibration, and as carriers in antibody-enzyme diagnosti, tests. As suspensions of uniform spherical particles, they are idea. experimental systems to test the series of colloidal phenomena as stability and coagulation, electric kinetic or rheological proper ties, and light scattering. In recent years, polymer colloids have received attention as models for many-body molecular phenomena, including the order-disorder transitions and the mechanics of crystalline phases.

Science and Technology of Polymer Colloids G.W. Poehlein, R.H. Ottewill, J.W. Goodwin (editors) Polymer colloids, more commonly known as latexes, are important in the manufacture of synthetic elastomers, commodity polymers, surface coatings, adhesive and numerous specialty products. The significant growth of the commercial production of polymer latexes during the past decade has been due to a number of factors. First, water-based systems, especially paints and coatings, avoid many of the environ mental problems associated with the solvent-based systems. Second, polymer colloid products can be custom designed to meet a wide range of application requirements. Third, large scale emulsion polymeri zation proceeds smoothly and controllably with a wide range of monomers to produce stable polymer colloids of high molecular weight. Polymer colloids are also important in functional scientific studies. This importance arises from the spherical shape of the particles, range of attainable particle diameters and the uniformity of their size distribution, and the possibility of controlling and character izing the particle surface. Polymer colloids are useful as size standards in microscopy and in instrument calibration, and as carriers in antibody-enzyme diagnostic tests. As suspensions of uniform spherical particles, they are ideal experimental systems to test the series of colloidal phenomena as stability and coagulation, electric kinetic or rheological proper ties, and light scattering. In recent years, polymer colloids have received attention as models for many-body molecular phenomena, including the order-disorder transitions and the mechanics of crystalline phases.

Academic and industrial research around polymer-based colloids is huge, driven both by the development of mature technologies, e.g. latexes for coatings, as well as the advancement of new materials and applications, such as building blocks for 2D/3D structures and medicine. Edited by two world-renowned leaders in polymer science and engineering, this is a fundamental text for the field. Based on a specialised course by the editors, this book provides the reader with an invaluable single source of reference. The first section describes formation, explaining basic properties of emulsions and dispersion polymerization, microfluidic approaches to produce polymer-based colloids and formation via directed self-assembly. The next section details characterisation methodologies from microscopy and small angle scattering, to surface science and simulations. The final chapters close with applications, including Pickering emulsions and molecular engineering for materials development. A comprehensive guide to polymer colloids, with contributions by leaders in their respective areas, this book is a must-have for researchers and practitioners working across polymers, soft matter and chemical and molecular engineering.

Colloid–polymer mixtures are subject of intensive research due to their wide range of applicability, for instance in coatings and food-stuffs. This thesis constitutes a fundamental investigation towards a better control over the stability of such suspensions. Through the chapters, different key parameters governing the stability of colloid–polymer mixtures are explored. How the colloid (pigment) shape and the effective polymer-colloid affinity modulate the stability of the suspension are examples of these key parameters. Despise the mostly theoretical results presented, the thesis is written in a format accessible to a broad scientific audience. Some of the equations of state presented might of direct use to experimentalists. Furthermore, new theoretical insights about colloid–polymer mixtures are put forward. These include four-phase coexistences in effective two-component, quantification of depletant partitioning at high colloidal concentrations, multiple re-entrant phase behaviour of the colloidal fluid–solid coexistence, and a condition where polymers are neither depleted nor adsorbed from/to the colloidal surface.

Many commercial systems are complex mixtures but in most cases the basic rules apply and surprises only occur when there is a quite specific interaction present. Hence, by using this text, the user will always have the fundamentals readily to hand.