Topics include the theory of atom tunneling reactions, conclusive evidence and controlling factors for such reactions in solid hydrogen, tunneling dislocation motion, coherent tunneling diffusion, the production of interstellar molecules and semiconductors using tunneling reactions, the effect of atom tunneling on molecular structure and crystalline structure, the suppression of mutation and cancer by an atom tunneling reaction of vitamin C, and atom tunneling reactions of vitamin E and of enzymes.

In the last two decades remarkable progress has been made in understanding and describing tunneling processes in complex systems in terms of classical trajectories. This book introduces recent concepts and achievements with particular emphasis on a dynamical formulation and relations to specific systems in mesoscopic, molecular, and atomic physics. Advanced instanton techniques, e.g. for decay rates and tunnel splittings, are discussed in the first part. The second part covers current developments for wave-packet tunneling in real-time, and the third part describes thermodynamics and dynamical approaches for barrier transmission in statistical, particularly dissipative systems.

Quantum mechanical tunneling plays important roles in a wide range of natural sciences, from nuclear and solid-state physics to proton transfer and chemical reactions in chemistry and biology. Responding to the need for further understanding of multidimensional tunneling, the authors have recently developed practical methods that can be applied to

The chemistry of reactive intermediates is central to a modern mechanistic and quantitative understanding of organic chemistry. Moreover, it underlies a significant portion of modern synthetic chemistry and is integral to a molecular view of biological chemistry. Reviews in Reactive Intermediate Chemistry presents an up-to-date, authoritative guide to this fundamental topic. Although it follows Reactive Intermediate Chemistry by the same authors, it serves as a free-standing resource for the entire chemical and biochemical community. The book includes: Relevant, practical applications Coverage of such topics as mass spectrometry methods, reactive intermediates in interstellar medium, quantum mechanical tunnelling, solvent effects, reactive intermediates in biochemical processes, and excited state surfaces Discussions of emerging areas, particularly those involving dynamics and theories Concluding sections identifying key directions for future research are provided at the end of each chapter

This book, written by experts in the fields of atomic physics and nonlinear science, covers the important developments in a special aspect of Bose-Einstein condensation, namely nonlinear phenomena in condensates. Topics covered include bright, dark, gap and multidimensional solitons; vortices; vortex lattices; optical lattices; multicomponent condensates; mathematical methods/rigorous results; and the beyond-the-mean-field approach.

Each scientist works with certain information and collects it in the course of prof- sional activity. In the same manner, the author collected data for atomic physics and atomic processes. This information was checked in the course of the author’s p- fessional activity and was published in the form of appendices to the corresponding books on atomic and plasma physics. Now it has been decided to publish these data separately. This book contains atomic data and useful information about atomic particles and atomic systems including molecules, nanoclusters, metals and condensed s- tems of elements. It also gives information about atomic processes and transport processes in gases and plasmas. In addition, the book deals with general concepts and simple models for these objects and processes. We give units and conversion factors for them as well as conversion factors for spread formulas of general physics and the physics of atoms, clusters and ionized gases since such formulas are used in professional practice by each scientist of this area.

When one approaches the study of the quantal relativistic theory of the electron, one may be surprised by the gap which lies between the frame of the experiments, i.e. the real geometry of the space and time, and the abstraction of the complex matrices and spinors formalism employed in the presentation of the theory. This book uses a theory of the electron, introduced by David Hestenes, in which the mathematical language is the same as the one of the geometry of the space and time. Such a language not only allows one to find again the well known results concerning the one-electron atoms theory but furthermore leads easily to the resolution of problems considered for a long time without solution.

This book is intended for physicists and chemists who need to understand the theory of atomic and molecular structure and processes, and who wish to apply the theory to practical problems. As far as practicable, the book provides a self-contained account of the theory of relativistic atomic and molecular structure, based on the accepted formalism of bound-state Quantum Electrodynamics. The author was elected a Fellow of the Royal Society of London in 1992.