This is the first volume of a two-volume set of critical reviews of many aspects of both asphaltenes and asphalts and their interrelationship. Asphaltene is invariably present in asphalt or bitumen and other fossil fuel-derived liquids such as coal tar, coal liquefaction products, pyrolyzed shale oil from oil shales, source rock extracts and numerous naturally occurring bituminous substances. The latter include asphaltites, asphaltoids, waxes, and carbonaceous deposits containing a composition of petroleum and coal.The contents cover not only the basic science of asphaltene but also deal with the applications and technology such as upstreams (production, recovery) and down streams (refining, upgrading) of petroleum, and the paving technology and formulation preparation. The main features of the book are: it provides an up-to-date, in-depth review of every aspect of asphaltenes and asphalts; it spans five decades of research and technology of heavy fractions of petroleum; it presents a global view of asphaltene related to exploration production, refining and upgrading.The book will be welcomed as a valuable reference source for petroleum companies, research institutes, refineries, universities and also by individuals dealing with the production, origin, formation, engineering, conversion and catalysis of heavy oil, tar sands and other bitumens materials.

This is the second volume in the series of Asphaltenes and Asphalts. Since the publication of the first volume in 1994, there has been a significant advancement in our knowledge. Knowledge of both asphaltenes and asphalts is needed by several disciplines, and often the progress is dictated by interdisciplinary sciences and technology. This includes material sciences, fuel sciences, chemical engineering, civil engineering, environmental engineering, polymer sciences, transportation engineering, petroleum engineering, chemistry, geological sciences, physics, geochemistry rheology, biological sciences, tribology, soil sciences, petroleum science. The development in this field is not based on our knowledge of chemistry or petroleum engineering alone, as many chemists and petroleum engineers believe. In this volume, therefore, significant contributions from different disciplines have been included.

Asphaltenes have traditionally been viewed as being extremely complex, thus very hard to characterize. In addition, certain fundamental properties of asphaltenes have pre viously been inaccessible to study by traditional macroscopic methods, further limiting understanding of asphaltenes. These limitations inhibited development of descriptions regarding the microscopic structure and solution dynamics of asphaltenes. However, a variety ofmore recent studies have implied that asphaltenes share many chemical properties with the smaller, more tractable components of crude oils. Recent measurements have indicated that asphaltene molecular weights are not as !arge as previously thought, perhaps in the range of 600 to I 000 amu. In addition, new experimental methods applied to asphaltene chemical structures have been quite revealing, yielding a broad understanding. Conse quently, the ability to relate chemical structure with physical and chemical properties can be developed and extended to the understanding of important commercial properties of asphal tenes. This book treats significant new developments in the fundamentals and applications of asphaltenes. In the first section ofthe book, new experimental methods are described that characterize asphaltene structures from the molecular to colloidallength scale. The colloidal properties are understandable in terms of asphaltene chemical structures, especially with regard to the heteroatom impact on bonding. However, quantitative measurements of the of asphaltene self-association still need to be determined. In the second section of enthalpy this book, the fundamental understanding of asphaltenes is related riirectly to asphaltene utilization.

THE CURRENT STATE OF THE ART of several aspects of asphaltene is presented in this volume. It documents the proceedings of the Internationl Symposium on Asphaltene Particles in Fossil Fuel Exploration, Recovery, Refining and Production Processes sponsored by the Fine particle Society (FPS). This meeting was held il1 Las vegas, Nevada, July 13 -17, 1992. The symposium upon which this volume is based was organized in four sessions emphasizing various basic and applied aspects of research on asphaltene technology. Major topics discussed involve surface phenomena of asphaltene, processed and unprocessed bitumen, asphaltene effect on natural and accelerated ageing of bitumens, asphaltene conversion, theoretical aspects of asphaltenes and interactions of asphaltene colloids in organic solvents. This edition includes eighteen selected papers presented at the symposium. These papers are divided in four broad categories: (1) Bitumen and Coal-Derived Asphaltenes, (2) Asphalt and Asphaltene conversion, (3) Surface and Colloidal Aspects of Asphaltenes, and (4) Thermodynamic and Molecular Aspects of Asphaltenes.

"Offers comprehensive, authoritative coverage of the chemistry, technology, and engineering of asphaltic products for paving, road construction, roofing, coatings, adhesives, and batteries. Analyzes microcracking and elucidates the mechanisms of degradation to aid the development of hot melt asphalt and increase longevity."

Asphaltenes are molecular substances that are found in crude oil, along with resins, aromatic hydrocarbons, and alkanes (i.e., saturated hydrocarbons). Asphaltenes in the form of distillation products from oil refineries are used as "tar-mats" on roads. This new book discusses the characterisation of alphaltenes and crude oils using near-UV/visible absorption spectroscopy. An overview of alphaltenes in petroleum and the cause of sediment deposition during production and refining is examined as well as the effects of magnetic fields on the paramagnetic, antioxidant, and viscous properties of oils and resin-alphaltene components. Insights into the structural characteristics of asphaltenes and its geochemical significance is also discussed.