Aromatic organic hydrocarbons and heterocycles represent a bulk of about one third of all industrially produced organic basic materials. Aromatic compounds such as benzene, phenol, naphthalene, anthracene, and their homologues, are derived from raw materials, coal, crude oil and biogenic resources by thermal and catalytic refining processes. This book introduces the chemistry of aromatics with a brief discussion of the aromatic character and a survey of historical aspects, particularly the development of the organic dye industry during the 19th century. The main emphasis of the book is to give a clear prospect of industrial processes for the production and the derivatisation of aromatics with consistent flow diagrams. Economical aspects of by- and side-products are especially regarded. For the most important aromatics an analysis of the international market included their derivatives: polymers, pesticides, dyes, pigments and drugs. Professional scientists, managers and students in chemistry and chemical engineering will find a wealth of information for their career and daily work.

All the basic principles of this important topic are clearly presented here in an account which takes as examples many compounds of industrial and biological significance. Consideration is given to the structure, reactions, and properties of benzene and classes of aromatic compounds derived from it, and topics such as thermodynamic versus kinetic control and pericyclic reactions are introduced. The text also covers polycyclic arenes and the small and large ring systems which are embraced by the wider definition of aromaticity.

Organic Chemistry for General Degree Students is written to meet the requirements of the London General Internal examination and degree examinations of a similar standing. It will also provide for the needs of students taking the Part 1 examination for Graduate Membership of the Royal Institute of Chemistry, or the Higher National Certificate, whilst the treatment is such that Ordinary National Certificate courses can be based on the first two volumes Within the limits broadly defined by the syllabus, the aim of this first volume is to provide a concise summary of the important general methods of preparation and properties of the main classes of aliphatic compounds. Due attention is paid to practical considerations with particular reference to important industrial processes. At the same time, the fundamental theoretical principles of organic chemistry are illustrated by the discussion of a selection of the more important reaction mechanisms. Questions and problems are included, designed to test the student's appreciation of the subject and his ability to apply the principles embodied therein. A selection of questions set in the relevant examinations is also included.

Evaluating the aromaticity of a molecular system and the influence of this concept on its properties is a crucial step in the development of novel aromatic systems. Modern computational methods can provide researchers with a high level of insight into such aromaticity, but identifying the most appropriate method for assessing a specific system can prove difficult. Aromaticity: Modern Computational Methods and Applications reviews the latest state-of-the-art computational methods in this field and discusses their applicability for evaluating the aromaticity of a system. In addition to covering aromaticity for typical organic molecules, this volume also explores systems possessing transition metals in their structures, macrocycles and even transition structures. The influence of the aromaticity on the properties of these species (including the structure, magnetic properties and reactivity) is highlighted, along with potential applications in fields including materials science and medicinal chemistry. Finally, the controversial and fuzzy nature of aromaticity as a concept is discussed, providing the basis for an updated and more comprehensive definition of this concept. Drawing on the knowledge of an international team of experts, Aromaticity: Modern Computational Methods and Applications is a unique guide for anyone researching, studying or applying principles of aromaticity in their work, from computational and organic chemists to pharmaceutical and materials scientists. - Reviews a range of computational methods to assess the aromatic nature of different compounds, helping readers select the most useful tool for the system they are studying - Presents a complete guide to the key concepts and fundamental principles of aromaticity - Provides guidance on identifying which variables should be modified to tune the properties of an aromatic system for different potential applications

Class-tested and thoughtfully designed for student engagement, Principles of Organic Chemistry provides the tools and foundations needed by students in a short course or one-semester class on the subject. This book does not dilute the material or rely on rote memorization. Rather, it focuses on the underlying principles in order to make accessible the science that underpins so much of our day-to-day lives, as well as present further study and practice in medical and scientific fields. This book provides context and structure for learning the fundamental principles of organic chemistry, enabling the reader to proceed from simple to complex examples in a systematic and logical way. Utilizing clear and consistently colored figures, Principles of Organic Chemistry begins by exploring the step-by-step processes (or mechanisms) by which reactions occur to create molecular structures. It then describes some of the many ways these reactions make new compounds, examined by functional groups and corresponding common reaction mechanisms. Throughout, this book includes biochemical and pharmaceutical examples with varying degrees of difficulty, with worked answers and without, as well as advanced topics in later chapters for optional coverage. Incorporates valuable and engaging applications of the content to biological and industrial uses Includes a wealth of useful figures and problems to support reader comprehension and study Provides a high quality chapter on stereochemistry as well as advanced topics such as synthetic polymers and spectroscopy for class customization

Polycyclic aromatic hydrocarbons (PAHs) are chemical compounds that consist of fused aromatic rings and do not contain heteroatoms or carry substituents. PAHs are one of the most widespread organic pollutants. Their occurrence is largely a result of anthropogenic and natural emissions such as fossil fuel-burning, motor vehicle, waste incinerator, oil refining, coke and asphalt production, and aluminum production. This book examines recent developments in the field.

Heterocyclic compounds are of prime importance to organic chemists working in the chemical industry, and heterocyclic chemistry is therefore a fundamental topic in undergraduate chemistry courses. The emphasis of this short text is on synthetic aspects, rather than properties, and it covers the essential details and basic principles with reference to all the important classes of heterocyclic compounds. Instructional problems are included as an aid to comprehension, and references to more detailed texts are provided.

Organic Chemistry for General Degree Students, Volume 2: Aromatic Chemistry presents the fundamental aspects of aromatic chemistry. This book explores the systematic study in the first instance of the chemistry of functional groups, based on their structural characteristics in aliphatic systems. Organized into 11 chapters, this volume begins with an overview of the properties of the aromatic nucleus followed by a consideration of the manner in which interaction with the aromatic system may alter the reactivity of functional groups. Other chapters explain the two distinctly different classes of aromatic halogen compounds. This text discusses as well the properties of an aromatic amine, which is characterized by having at least one aromatic system attached to the nitrogen atom and may be further categorized as primary, secondary, or tertiary according to the degree of substitution of the nitrogen. The final chapter examines the classical structure for thiophen. This book is a valuable resource for organic chemists and students.

This 1991 volume was the first to review the chemical properties of the carcinogenic polycyclic aromatic hydrocarbons.

This book provides material required by undergraduate students and is also ideal for industrial chemists seeking to update their knowledge of this important aspect of chemistry.