This comprehensive contributed volume presents an account of current research and applications of chemical processes occurring at the interfaces of water with naturally occuring solids. Interactions of solutes with the solid surfaces are looked at from a mechanistic and dynamic point of view rather than a descriptive one. Processes discussed and concepts presented are applicable to all natural waters (oceans and fresh waters as well as soil and sediment water systems) and to the surfaces of natural solids such as minerals, soils, sediments, biota, and humus. Chapters progress from theoretical models and laboratory studies to applications in natural water, soil, and geochemical systems, emphasizing those processes that regulate the distribution and concentration of elements and compounds. Topics covered include adsorption mechanisms in aquatic surface chemistry, the electric double layer at the solid-solution interface, aspects of molecular structure in surface complexes: spectroscopic investigations, interpretation of metal complexation by heterogeneous complexants, the role of colloids in the partitioning of solutes in natural waters, and 'from molecules to planetary environments': understanding global change.

Borne out of the current widespread interest in the pollution of water bodies, this book explores the latest research concerning the photochemical fate of organic pollutants in surface water. The main objective is to give insight into both the functioning of ecosystems and the behaviour of emerging pollutants in those ecosystems. Particular importance is dedicated to techniques that can be used in the field and in the laboratory for the detection of pollutants and of their transformation intermediates. The inclusion of photochemical processes that have not gained previous coverage will afford the reader novel insights, whilst the focus on modelling and transformation intermediates will ensure the title's relevance to academics, the chemical manufacturing industries and environmental assessment experts alike.

Aquatic Chemistry Concepts, Second Edition, is a fully revised and updated textbook that fills the need for a comprehensive treatment of aquatic chemistry and covers the many complicated equations and principles of aquatic chemistry. It presents the established science of equilibrium water chemistry using the uniquely recognizable, step-by-step Pankow format, which allows a broad and deep understanding of aquatic chemistry. The text is appropriate for a wide audience, including undergraduate and graduate students, industry professionals, consultants, and regulators. Every professional using water chemistry will want this text within close reach, and students and professionals alike will expect to find at least one copy on their library shelves. Key Features Extremely thorough, one-of-a-kind treatment of aquatic chemistry which considers: a) chemical thermodynamics fundamentals; b) acid/base, titration, and buffer calculations; c) CO2 chemistry and alkalinity; d) complexation of metal ions by ligands and chelates; e) mineral solubility processes; f) redox chemistry, including the chemistry of chlorine (as in disinfection), oxygen, CO2 and methane, nitrogen, sulfur, iron, and lead, including the story of lead in the drinking water of Flint, Michigan; and g) electrical effects in aqueous solutions including the Debye-Hückel Law (and related equations for activity corrections), double layers, and colloid stability Discussions of how to carry out complex calculations regarding the chemistry of lakes, rivers, groundwater, and seawater Numerous example problems worked in complete detail Special foreword by Jerry L. Schnoor 'There’s a lot to like about a book on water chemistry that lays it out simply. Einstein said that everything should be as simple as it can be, but not simpler. Wise advice. And that is what James F. Pankow has accomplished in the second edition of his textbook, Aquatic Chemistry Concepts. It covers the “waterfront” of essential inorganic chemistry topics, and it supplies enough examples to lead the student toward problem solving.' -From the Foreword, Jerry L. Schnoor

Aquatic and Surface Photochemistry provides a broad overview of current research in the emerging field of environmental aquatic and surface photochemistry. Selected reviews and current research articles are blended to provide an in-depth treatment of various aspects of this research area. The first part of the text deals with photochemistry in the environment, covering recent research on the following topics: aquatic photochemistry of organic pollutants and agrochemicals, photochemical cycling of carbon and transition metals (especially iron), photochemical formation of reactive oxygen species in natural waters, photoreaction in cloud and rain droplets, and photoreactions on environmental surfaces (soil, ash, metal, oxide). The second part provides discussions and data on both heterogeneous photocatalytic and homogeneous processes, with topics ranging from applications to mechanistic studies. These chapters illustrate the wide diversity of pollutant classes that are degradable by photochemical techniques and the effects of various reaction conditions on the rates and efficiency of the techniques. Current kinetic studies are presented, which provide new information about the role of adsorption and the nature of the reactive oxidizing species that mediate these photoremediation processes.This book will interest civil, chemical, and environmental engineers, as well as chemists, soil scientists, geochemists, and atmospheric chemists.

The authoritative introduction to natural water chemistry THIRD EDITION Now in its updated and expanded Third Edition, Aquatic Chemistry remains the classic resource on the essential concepts of natural water chemistry. Designed for both self-study and classroom use, this book builds a solid foundation in the general principles of natural water chemistry and then proceeds to a thorough treatment of more advanced topics. Key principles are illustrated with a wide range of quantitative models, examples, and problem-solving methods. Major subjects covered include: Chemical Thermodynamics Solid-Solution Interface and Kinetics Trace Metals Acids and Bases Kinetics of Redox Processes Dissolved Carbon Dioxide Photochemical Processes Atmosphere-Water Interactions Kinetics at the Solid-Water Metal Ions in Aqueous Solution Interface Precipitation and Dissolution Particle-Particle Interaction Oxidation and Reduction Regulation of the Chemical Equilibria and Microbial Mediation Composition of Natural Waters

There is need in environmental research for a book on fresh waters including rivers and lakes. Compared with other books on the topic, this book has a unique outline in that it follows pollution from sources to impact. Included in the text is the treatment of various tracers, ranging from pathogens to stable isotopes of elements and providing a comprehensive discussion which is lacking in many other books on pollution control of natural waters. Geophysical processes are discussed emphasizing mixing of water, interaction between water and the atmosphere, and sedimentation processes. Important geochemistry processes occurring in natural waters are described as are the processes specific to nutrients, organic pollutants, metals, and pathogens in subsequent chapters. Each of these chapters includes an introduction on the selected groups, followed by the physicochemical properties which are the most relevant to their behavior in natural waters, and the theories and models to describe their speciation, transport and transformation. The book also includes the most up to date information including a discussion on emerging pollutants such as brominated and phosphate flame retardants, perflurochemicals, and pharmaceutical and personal care products. Due to its importance an ecotoxicology chapter has been included featuring molecular biological methods, nanoparticles, and comparison of the basis of biotic ligand model with the Weibull dose-response model. Finally, the last chapter briefly summarizes the regulations on ambient water quality.

Aquatic systems play a salient role in the complex processes of energy and matter exchange between the geosphere and the atmosphere. For example, reactions taking place in cloud water droplets can substantially alter the atmospheric budget and chemistry of trace gases; pollution induced weathering reactions at water/soil interfaces can affect the availability of nutrients and increase the concentration of potentially toxic metals in groundwaters. Moreover, the inextricable links between the water cycle, the geosphere and the atmosphere ensure that apparently localized environmental problems have increasingly impacts in other parts of the world. To identify local-to-global scale variables associated with environmental changes, a focus must be placed on the recognition of processes, rather than a continued reliance on monitoring state variables. However, in heterogeneous aquatic systems, small scale aspects of a process under observation may not be summed directly to obtain regional estimates because of process nonlinearities with change in scale. To understand this, the integrated use of measurements across a range of scales is required.

This work aims to familiarize students with the fundamentals of colloid and surface science, from various types of colloids and colloidal phenomena, and classical and modern characterization/measurement techniques to applications of colloids and surface science in engineering, technology, chemistry, physics and biological and medical sciences. The Journal of Textile Studies proclaims "High praise from peers . . .contains valuable information on many topics of interest to food rheologists and polymer scientists ...[The book] should be in the libraries of academic and industrial food research organizations" and Chromatographia describes the book as "...an excellent textbook, excellently organised, clearly written and well laid out."

This book covers the development of both experiment and theory in natural surface particle chemistry. It emphasizes insights gained over the past few years, and concentrates on molecular spectroscopy, kinetics, and equilibrium as they apply to natural particle surface reactions in aqueous media. The discussion, divided among five chapters, is complemented by lengthy annotations, reading suggestions, and end-of-chapter problem sets that require a critical reading of important technical journal articles.