This book provides an introduction to the use of algebraic methods and sym bolic computation for simple quantum systems with applications to large order perturbation theory. It is the first book to integrate Lie algebras, algebraic perturbation theory and symbolic computation in a form suitable for students and researchers in theoretical and computational chemistry and is conveniently divided into two parts. The first part, Chapters 1 to 6, provides a pedagogical introduction to the important Lie algebras so(3), so(2,1), so(4) and so(4,2) needed for the study of simple quantum systems such as the D-dimensional hydrogen atom and harmonic oscillator. This material is suitable for advanced undergraduate and beginning graduate students. Of particular importance is the use of so(2,1) in Chapter 4 as a spectrum generating algebra for several important systems such as the non-relativistic hydrogen atom and the relativistic Klein-Gordon and Dirac equations. This approach provides an interesting and important alternative to the usual textbook approach using series solutions of differential equations.

With this text, basic quantum mechanics becomes accessible to undergraduates with no background in mathematics beyond algebra. Includes more than 100 problems and 38 figures. 1986 edition.

Algebraic Methods in Quantum Chemistry and Physics provides straightforward presentations of selected topics in theoretical chemistry and physics, including Lie algebras and their applications, harmonic oscillators, bilinear oscillators, perturbation theory, numerical solutions of the Schrödinger equation, and parameterizations of the time-evolution operator. The mathematical tools described in this book are presented in a manner that clearly illustrates their application to problems arising in theoretical chemistry and physics. The application techniques are carefully explained with step-by-step instructions that are easy to follow, and the results are organized to facilitate both manual and numerical calculations. Algebraic Methods in Quantum Chemistry and Physics demonstrates how to obtain useful analytical results with elementary algebra and calculus and an understanding of basic quantum chemistry and physics.

This work has grown out of the lecture notes that were prepared for a series of seminars on some selected topics in quantum logic. The seminars were delivered during the first semester of the 1993/1994 academic year in the Unit for Foundations of Science of the Department of History and Foundations of Mathematics and Science, Faculty of Physics, Utrecht University, The Netherlands, while I was staying in that Unit on a European Community Research Grant, and in the Center for Philosophy of Science, University of Pittsburgh, U. S. A. , where I was staying during the 1994/1995 academic year as a Visiting Fellow on a Fulbright Research Grant, and where I also was supported by the Istvan Szechenyi Scholarship Foundation. The financial support provided by these foundations, by the Center for Philosophy of Science and by the European Community is greatly acknowledged, and I wish to thank D. Dieks, the professor of the Foundations Group in Utrecht and G. Massey, the director of the Center for Philosophy of Science in Pittsburgh for making my stay at the respective institutions possible. I also wish to thank both the members of the Foundations Group in Utrecht, especially D. Dieks, C. Lutz, F. Muller, J. Uffink and P. Vermaas and the participants in the seminars at the Center for Philosophy of Science in Pittsburgh, especially N. Belnap, J. Earman, A. Janis, J. Norton, and J.

The twentieth century has witnessed a striking transformation in the understanding of the theories of mathematical physics. There has emerged clearly the idea that physical theories are significantly characterized by their abstract mathematical structure. This is in opposition to the tradi tional opinion that one should look to the specific applications of a theory in orrter to understand it. One might with reason now espouse the view that to understand the deeper character of a theory one must know its abstract structure and understand the significance of that structure, while to understand how a theory might be modified in light of its experimental inadequacies one must be intimately acquainted with how it is applied. Quantum theory itself has gone through a development this century which illustrates strikingly the shifting perspective. From a collection of intuitive physical manoeuvers under Bohr, through a formative stage in which the mathematical framework was bifurcated (between Schrodinger and Heisenberg) to an elegant culmination in von Neumann's Hilbert space formulation, the elementary theory moved, flanked even at this later stage by the ill-understood formalisms for the relativistic version and for the field-theoretic alternative; after that we have a gradual, but constant, elaboration of all these quantal theories as abstract mathematical structures (their point of departure being von Neumann's formalism) until at the present time theoretical work is heavily preoccupied with the manipulation of purely abstract structures.

First Published in 2018. Routledge is an imprint of Taylor & Francis, an Informa company.

Algebraic Methods in Quantum Chemistry and Physics provides straightforward presentations of selected topics in theoretical chemistry and physics, including Lie algebras and their applications, harmonic oscillators, bilinear oscillators, perturbation theory, numerical solutions of the Schrödinger equation, and parameterizations of the time-evolution operator. The mathematical tools described in this book are presented in a manner that clearly illustrates their application to problems arising in theoretical chemistry and physics. The application techniques are carefully explained with step-by-step instructions that are easy to follow, and the results are organized to facilitate both manual and numerical calculations. Algebraic Methods in Quantum Chemistry and Physics demonstrates how to obtain useful analytical results with elementary algebra and calculus and an understanding of basic quantum chemistry and physics.

The authors present a rigorous treatment of the first principles of the algebraic and analytic core of quantum field theory. Their aim is to correlate modern mathematical theory with the explanation of the observed process of particle production and of particle-wave duality that heuristic quantum field theory provides. Many topics are treated here in book form for the first time, from the origins of complex structures to the quantization of tachyons and domains of dependence for quantized wave equations. This work begins with a comprehensive analysis, in a universal format, of the structure and characterization of free fields, which is illustrated by applications to specific fields. Nonlinear local functions of both free fields (or Wick products) and interacting fields are established mathematically in a way that is consistent with the basic physical constraints and practice. Among other topics discussed are functional integration, Fourier transforms in Hilbert space, and implementability of canonical transformations. The authors address readers interested in fundamental mathematical physics and who have at least the training of an entering graduate student. A series of lexicons connects the mathematical development with the underlying physical motivation or interpretation. The examples and problems illustrate the theory and relate it to the scientific literature. Originally published in 1992. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.

This book introduces the factorization method in quantum mechanics at an advanced level, with the aim of putting mathematical and physical concepts and techniques like the factorization method, Lie algebras, matrix elements and quantum control at the reader’s disposal. For this purpose, the text provides a comprehensive description of the factorization method and its wide applications in quantum mechanics which complements the traditional coverage found in quantum mechanics textbooks.

The standard model of subatomic particles and the periodic table of the atoms have the common goal to bring order in the bewildering chaos of the constituents of matter. Their success relies on the presence of fundamental symmetries in their core. The purpose of the book is to share the admiration for the power and the beauty of these symmetries. The reader is taken on a journey from the basic geometric symmetry group of a circle to the sublime dynamic symmetries that govern the motions of the particles. The trail follows the lines of parentage linking groups upstream to the unitary symmetry of the eightfold way of quarks, and to the four-dimensional symmetry of the hydrogen atom. Along the way the theory of symmetry groups is gradually introduced with special emphasis on graphical representations. The final challenge is to open up the structure of Mendeleev's table which goes beyond the symmetry of the hydrogen atom. Breaking this symmetry to accommodate the multi-electron atoms requires to leave the common ground of linear algebras and explore the potential of non-linearity.