This is the first book to cover actinide nano research. It is of interest both for fundamental research into the chemistry and physics of f-block elements as well as for applied researchers such as those studying the long-term safety of nuclear waste disposal and developing remediation strategies. The authors cover important issues of the formation of actinide nano-particles, their properties and structure, environmental behavior of colloids and nanoparticles related to the safe disposal of nuclear wastes, modeling and advanced methods of characterization at the nano-scale.

A review of contemporary actinide research that focuses on new advances in experiment and theory, and the interplay between these two realms Experimental and Theoretical Approaches to Actinide Chemistry offers a comprehensive review of the key aspects of actinide research. Written by noted experts in the field, the text includes information on new advances in experiment and theory and reveals the interplay between these two realms. The authors offer a multidisciplinary and multimodal approach to the nature of actinide chemistry, and explore the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry. The text covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques. The authors provide contemporary overviews of each topic area presented and describe the current and anticipated experimental approaches for the field, as well as the current and future computational chemistry and materials techniques. In addition, the authors explore the combination of experiment and theory. This important resource: Provides an essential resource the reviews the key aspects of contemporary actinide research Includes information on new advances in experiment and theory, and the interplay between the two Covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques Focuses on the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry Written for academics, students, professionals and researchers, this vital text contains a thorough review of the key aspects of actinide research and explores the most recent advances in experiment and theory.

To assess the relevance of colloidal influences on radionuclide transport for the long-term safety of a radioactive waste repository, the KOLLORADO-2 project integrates the results of geochemical and hydrogeological studies. The results may serve as a basis for an appraisal of the implications of colloid presence in the vicinity of radioactive waste repositories in different deep geological host-rock formations.

The 3-volume set highlights the behavior of radionuclides in the environment and focusing on the development of related fields of study, including microbiology and nanoscience. In this context, it discusses the behavior of radionuclides released in areas of Lake Karachai in Ural, and those released as a result of Chernobyl accident (1986), and in Fukushima (2011). Volume I presents the experiences gained in South Urals (“Mayak” plant, Lake Karachai), providing a scientific basis for more precise understanding of the behavior of radionuclides in complex subsurface environments. On the basis of monitoring data, it examines the pathways of radionuclide migration and the influence of the geological environment and groundwater on the migration, with a particular focus on particles from the nanoscale to microscale. It also discusses the function of microbes and microscale particles, from their direct interaction with radionuclides to their ecological role in changing the physic-chemical condition of a given environment. Lastly, the protective properties of geological media are also characterized, and mathematical modeling of contaminant migration in the area of Lake Karachai is used to provide information regarding the migration of radionuclides.

Structural Chemistry of Inorganic Actinide Compounds is a collection of 13 reviews on structural and coordination chemistry of actinide compounds. Within the last decade, these compounds have attracted considerable attention because of their importance for radioactive waste management, catalysis, ion-exchange and absorption applications, etc. Synthetic and natural actinide compounds are also of great environmental concern as they form as a result of alteration of spent nuclear fuel and radioactive waste under Earth surface conditions, during burn-up of nuclear fuel in reactors, represent oxidation products of uranium miles and mine tailings, etc. The actinide compounds are also of considerable interest to material scientists due to the unique electronic properties of actinides that give rise to interesting physical properties controlled by the structural architecture of respective compounds. The book provides both general overview and review of recent developments in the field, including such emergent topics as nanomaterials and nanoparticles and their relevance to the transfer of actinides under environmental conditions.* Covers over 2,000 actinide compounds including materials, minerals and coordination polymers* Summarizes recent achievements in the field* Some chapters reveal (secret) advances made by the Soviet Union during the 'Cold war'

Actinide elements and their chemistry have a significant number of applications. Bringing together contributions from the leading experts in the field, Recent Advances in Actinide Science covers six main topics: * Analysis, the environment and biotransformations * Coordination and organometallic chemistry * Heavy elements * Nuclear fuels, materials and waste forms * Separations and solution chemistry * Spectroscopy, magnetism and superconductivity Covering a wide range of research from pure academic studies to applied industrial science and technology, this book distils the knowledge and achievements gained in actinide science over the last four years. This high level book is aimed at researchers, both industrial and academic, and provides a comprehensive overview of the current status of actinide science.

Actinides in Perspective presents in proceedings of the Actinides-1981 Conference held in Pacific Grove, California, USA on September 10-15, 1981. The book contains papers on the different aspect of the physics and chemistry of the actinides. The text includes papers on the history of the discovery of the transplutonium elements; the photoemission techniques; and the neutron scattering studies of the actinides. The new elements in the transfermium region; the isotope identification in the transfermium region by ?-? correlation after in-flight-separation; and the fission properties of the actinides are also considered. The book further tackles papers on the status of superheavy element research; the single crystal preparation of actinides and actinide compounds; and the preparation of transplutonium metals and compounds, protactinium metal and compounds, and actinide metals. The text also includes papers on the complex oxide systems of the actinides; thermodynamic properties of the actinides; and the chemical and physicochemical properties of actinide organometallic compounds.

Understanding radionuclide behaviour in the natural environment is essential to the sustainable development of the nuclear industry and key to assessing potential environmental risks reliably. Minimising those risks is essential to enhancing public confidence in nuclear technology. Scientific knowledge in this field has developed greatly over the last decade.Radionuclide behaviour in the natural environment provides a comprehensive overview of the key processes and parameters affecting radionuclide mobility and migration.After an introductory chapter, part one explores radionuclide chemistry in the natural environment, including aquatic chemistry and the impact of natural organic matter and microorganisms. Part two discusses the migration and radioecological behavior of radionuclides. Topics include hydrogeology, sorption and colloidal reactions as well as in-situ investigations. Principles of modelling coupled geochemical, transport and radioecological properties are also discussed. Part three covers application issues: assessment of radionuclide behaviour in contaminated sites, taking Chernobyl as an example, estimation of radiological exposure to the population, performance assessment considerations related to deep geological repositories, and remediation concepts for contaminated sites.With its distinguished editors and international team of expert contributors, Radionuclide behaviour in the natural environment is an essential tool for all those interested or involved in nuclear energy, from researchers, designers and industrial operators to environmental scientists. It also provides a comprehensive guide for academics of all levels in this field. - Provides a comprehensive overview of the key processes and parameters affecting radionuclide mobility and migration - Explores radionuclide chemistry in the natural environment - Discusses the migration and radioecological behaviour of radionuclides

The authors' aim is to present a review of experimental and theoretical research that has been done to establish and to explain the physical properties of actinide compounds. The book is aimed at physicists and chemists. It was thought useful to collect a large selection of diagrams of experimental data scattered in the literature. Experiment and theory are presented separately, with cross references. Not all work has been included: rather, typical examples are discussed. We apologize to all researchers whose work has not been quoted. Since we report on an active field of research, clearly the data and their interpretation are subject to change. We benefitted greatly from discussions with many of our colleagues, particularly with Drs. G. H. Lander and W. Suski. The help of Mrs. C. Bovey and Ch. Lewis in the preparation of the manuscript, and the artwork and photo graphic work of Ms. Y. Magnenat and E. Spielmann of the Institute of Experi mental Physics of the University of Lausanne, are gratefully acknowledged. Our particular thanks are due to Ms. J. Ubby for her skillful and patient editorial work.

In the last 15 years, actinide research has presented unique challenges both for experimentalists and theorists. Their uniqueness stems not only from their nuclear properties, which since the early 1940's has led to their important role in nuclear energy and nuclear technology, but also from their unusual chemical and physical properties which have added new excitement and discoveries to both these disciplines. It is the purpose of the Handbook to describe in detail the present understanding of the actinides by means of comprehensive, critical, broad and up-to-date reviews covering both the physics and chemistry of these exotic elements. They are intended to serve as an introduction to the subject for the non-specialist, as a convenient reference work for the specialist, and as a guide for future research. The rapid accelerated pace of research in the last decade continues and carries with it new vigor and excitement to a field in a state of transition. The present sixth volume completes the series. Like volumes 3 and 4, the emphasis is on chemistry, though physical aspects, such as self-radiation effects and electron paramagnetic resonance are also treated. The main body of the volume is devoted to systematic and comprehensive studies of a variety of important actinide compounds. These include relatively simple salts as well as various complexes and organic compounds. The data accumulated on such materials are broadly scattered in the literature, due to the interdisciplinary nature of much of the underlying research. Prominent experts on the various substances have now reviewed this literature and bring it to the reader in a readily accesible form.