This text provides a detailed introduction to aquatic equilibrium chemistry, calculation methods for systems at equilibrium, applications of aquatic chemistry, and chemical kinetics. Software designed especially for the text allows the reader to build complex models by applying equilibrium calculation principles. Important features include material-specific and integrated case studies, thought-provoking questions, key ideas, and historical sketches.

A Problem-Solving Approach to Aquatic Chemistry Enables civil and environmental engineers to understand the theory and application of aquatic equilibrium chemistry The second edition of A Problem-Solving Approach to Aquatic Chemistry provides a detailed introduction to aquatic equilibrium chemistry, calculation methods for systems at equilibrium, applications of aquatic chemistry, and chemical kinetics. The text directly addresses two required ABET program outcomes in environmental engineering: “… chemistry (including stoichiometry, equilibrium, and kinetics)” and “material and energy balances, fate and transport of substances in and between air, water, and soil phases.” The book is very student-centered, with each chapter beginning with an introduction and ending with a summary that reviews the chapter’s main points. To aid in reader comprehension, important terms are defined in context and key ideas are summarized. Many thought-provoking discussion questions, worked examples, and end of chapter problems are also included. Each part of the text begins with a case study, a portion of which is addressed in each subsequent chapter, illustrating the principles of that chapter. In addition, each chapter has an Historical Note exploring connections with the people and cultures connected to topics in the text. A Problem-Solving Approach to Aquatic Chemistry includes: Fundamental concepts, such as concentration units, thermodynamic basis of equilibrium, and manipulating equilibria Solutions of chemical equilibrium problems, including setting up the problems and algebraic, graphical, and computer solution techniques Acid–base equilibria, including the concepts of acids and bases, titrations, and alkalinity and acidity Complexation, including metals, ligands, equilibrium calculations with complexes, and applications of complexation chemistry Oxidation-reduction equilibria, including equilibrium calculations, graphical approaches, and applications Gas–liquid and solid–liquid equilibrium, with expanded coverage of the effects of global climate change Other topics, including chemical kinetics of aquatic systems, surface chemistry, and integrative case studies For advanced/senior undergraduates and first-year graduate students in environmental engineering courses, A Problem-Solving Approach to Aquatic Chemistry serves as an invaluable learning resource on the topic, with a variety of helpful learning elements included throughout to ensure information retention and the ability to apply covered concepts in practical settings.

Chemical kinetics; Chemical equilibrium; Acid-base chemistry; Coordination chemistry; Precipitation and dissolution; Oxidation - reduction reactions.

Aquatic chemistry students need a solid foundation in fundamental concepts as well as numerical techniques for solving the variety of problems they will encounter as practicing engineers. For over a decade, Mark Benjamin’s Water Chemistry has brought to the classroom a balanced coverage of fundamentals and analytical algorithms in a student-friendly, accessible way. The text distinguishes itself with longer and more detailed explanations of the relevant chemistry and mathematics, allowing students to understand not only which techniques work best for a given application, but also why those techniques should be applied and what their limitations are. The end result is a solid, thorough framework for comprehending equilibrium in complex aquatic systems. The second edition includes a thorough introductory explanation of chemical reactivity and a new chapter on reaction kinetics, providing much-needed context, as well as full treatments of the tableau method and TOTH equation. The discussion of the thermodynamic perspective on chemical reactivity has been extensively revised. The entire book now integrates Visual Minteq—the most popular software for analyzing chemical equilibria—into the problem-solving approach. Additional exercises range more widely in difficulty, giving instructors more flexibility and diversity in their assignments.

Professionals and students who come from disciplines other than chemistry need a concise yet reliable guide that explains key concepts in environmental chemistry, from the fundamental science to the necessary calculations for applying them. Updated and reorganized, Applications of Environmental Aquatic Chemistry: A Practical Guide, Third Edition provides the essential background for understanding and solving the most frequent environmental chemistry problems. Diverse and self-contained chapters offer a centralized and easily navigable framework for finding useful data tables that are ordinarily scattered throughout the literature. Worked examples provide step-by-step details for frequently used calculations, drawing on case histories from real-world environmental applications. Chapters also offer tools for calculating quick estimates of important quantities and practice problems that apply the principles to different conditions. This practical guide provides an ideal basis for self-study, as well as short courses involving the movement and fate of contaminants in the environment. In addition to extensive reorganization and updating, the Third Edition includes a new chapter, Nutrients and Odors: Nitrogen, Phosphorus, and Sulfur, two new appendices, Solubility of Slightly Soluble Metal Salts and Glossary of Acronyms and Abbreviations Used in this Book, and new material and case studies on remediation, stormwater management, algae growth and treatment, odor control, and radioisotopes.

Environmental Organic Chemistry focuses on environmental factors that govern the processes that determine the fate of organic chemicals in natural and engineered systems. The information discovered is then applied to quantitatively assessing the environmental behaviour of organic chemicals. Now in its 2nd edition this book takes a more holistic view on physical-chemical properties of organic compounds. It includes new topics that address aspects of gas/solid partitioning, bioaccumulation, and transformations in the atmosphere. Structures chapters into basic and sophisticated sections Contains illustrative examples, problems and case studies Examines the fundamental aspects of organic, physical and inorganic chemistry - applied to environmentally relevant problems Addresses problems and case studies in one volume

It emphasizes that both equilibrium and kinetic processes are important in aquatic systems.

Soil and Environmental Chemistry, Second Edition, presents key aspects of soil chemistry in environmental science, including dose responses, risk characterization, and practical applications of calculations using spreadsheets. The book offers a holistic, practical approach to the application of environmental chemistry to soil science and is designed to equip the reader with the chemistry knowledge and problem-solving skills necessary to validate and interpret data. This updated edition features significantly revised chapters, averaging almost a 50% revision overall, including some reordering of chapters. All new problem sets and solutions are found at the end of each chapter, and linked to a companion site that reflects advances in the field, including expanded coverage of such topics as sample collection, soil moisture, soil carbon cycle models, water chemistry simulation, alkalinity, and redox reactions. There is also additional pedagogy, including key term and real-world scenarios. This book is a must-have reference for researchers and practitioners in environmental and soil sciences, as well as intermediate and advanced students in soil science and/or environmental chemistry. - Includes additional pedagogy, such as key terms and real-world scenarios - Supplemented by over 100 spreadsheets to migrate readers from calculator-based to spreadsheet-based problem-solving that are directly linked from the text - Includes example problems and solutions to enhance understanding - Significantly revised chapters link to a companion site that reflects advances in the field, including expanded coverage of such topics as sample collection, soil moisture, soil carbon cycle models, water chemistry simulation, alkalinity, and redox reactions

This book offers thorough, up-to-date coverage of controls on the chemical quality of surface and subsurface waters, both pristine and polluted, with an emphasis on problem-solving and practical applications. The text is appropriate for courses in aqueous geochemistry or aquatic chemistry. Desirable prerequisites are introductory courses or the equivalent in thermodynamics and solution chemistry, and in physical geology including mineralogy.

This rigorous and comprehensive text provides fundamental information geared to students in either engineering or natural sciences courses dealing with groundwater. The first four chapters consider subsurface fluid flow, while the remaining twelve chapters cover subsurface contamination and pollutant transport. Charbeneau views the application of groundwater hydraulics and pollutant transport as a quantitative field. Although quantitative methods are exact, the fields of study are usually homogeneous; laboratory and field methods provide estimates for ideal (not real) fields. What impact does the use of ideal fields have on model predictions? The unknown answer places the study of subsurface flow of water and chemical mass transport in a prime position for continued researchand this readily accessible text opens the door to that research. Outstanding features include: Comprehensive, rigorous, and highly accessible coverageIncludes information on groundwater flow, well hydraulics, field methods for parameter estimation, hydrologic relationships between surface water and groundwater hydrology, mass transport of contaminants by advection, diffusion and dispersion, and special problems posed by nonaqueous phase liquids (oils). Strong focus on applicationsEmpowers readers with knowledge and methodologies that they can use in real, day-to-day practices. Includes 66 worked examples and 178 problems integrated throughout. Examination of standard software being used in the industry todayExposes readers to the USGS MODFLOW model (the most widely used numerical simulation model for groundwater flow) and the USGS MOC3D. These models, together with a user interface (MFI), can be downloaded from the Internet.