Recent years have witnessed tremendous progress in the theoretical treatment of surfaces and processes on surfaces. A variety of surface properties can now be described from first principles, i.e. without invoking any empirical parameters. In this book the theoretical concepts and computational tools necessary and relevant for a microscopic approach to the theoretical description of surface science is presented. Based on the fundamental theoretical entity, the Hamiltonian, a hierarchy of theoretical methods is introduced. Furthermore, a detailed discussion of surface phenomena is given and comparisons made to experimental results made, making the book suitable for both graduate students and for experimentalists seeking an overview of the theoretical concepts in surface science.

Physics at Surfaces is a unique graduate-level introduction to the physics and chemical physics of solid surfaces, and atoms and molecules that interact with solid surfaces. A subject of keen scientific inquiry since the last century, surface physics emerged as an independent discipline only in the late 1960s as a result of the development of ultra-high vacuum technology and high speed digital computers. With these tools, reliable experimental measurements and theoretical calculations could at last be compared. Progress in the last decade has been truly striking. This volume provides a synthesis of the entire field of surface physics from the perspective of a modern condensed matter physicist with a healthy interest in chemical physics. The exposition intertwines experiment and theory whenever possible, although there is little detailed discussion of technique. This much-needed text will be invaluable to graduate students and researchers in condensed matter physics, physical chemistry and materials science working in, or taking graduate courses in, surface science.

Revised and expanded second edition of the standard work on new techniques for studying solid surfaces.

The theory of surface states underlies our knowledge of the behavior of electrons at solid surfaces, which is of paramount importance in understanding the mechanisms by which solid-state devices operate and catalytic reactions proceed. In this work, the subject is viewed through the "theoretical eye" of a physicist, but the topics are treated in an elementary fashion. The main features of the presentation are its instructive, model-based approach; detailed step-by-step derivations of the equations; smooth progression through the simple wave-function matching techniques to the more sophisticated Green-function methods; and the historical theme, which traces the evolution of the subject from its founding by the Nobel Laureate Igor Tamm in 1932, through the invention of the transistor in 1947 by Schockley, Bardeen and Brattain, to recent developments. The book will appeal to both theoretical and experimental surface scientists from chemistry, materials science, and electronic engineering.

An updated fourth edition of the text that provides an understanding of chemical transformations and the formation of structures at surfaces The revised and enhanced fourth edition of Surface Science covers all the essential techniques and phenomena that are relevant to the field. The text elucidates the structural, dynamical, thermodynamic and kinetic principles concentrating on gas/solid and liquid/solid interfaces. These principles allow for an understanding of how and why chemical transformations occur at surfaces. The author (a noted expert on in the field) combines the required chemistry, physics and mathematics to create a text that is accessible and comprehensive. The fourth edition incorporates new end-of-chapter exercises, the solutions to which are available on-line to demonstrate how problem solving that is relevant to surface science should be performed. Each chapter begins with simple principles and builds to more advanced ones. The advanced topics provide material beyond the introductory level and highlight some frontier areas of study. This updated new edition: Contains an expanded treatment of STM and AFM as well as super-resolution microscopy Reviews advances in the theoretical basis of catalysis and the use of activity descriptors for rational catalyst design Extends the discussion of two-dimensional solids to reflect remarkable advances in their growth and characterization Delves deeper into the surface science of electrochemistry and charge transfer reactions Updates the “Frontiers and Challenges” sections at the end of each chapter as well as the list of references Written for students, researchers and professionals, the fourth edition of Surface Science offers a revitalized text that contains the tools and a set of principles for understanding the field. Instructor support material, solutions and PPTs of figures, are available at http://booksupport.wiley.com

Surface science emerged in the 1960s with the development of reliable ultrahigh vacuum apparatus, providing exact structures of surfaces of metal single crystals, information about their compositions, and relationships between surface structure and composition and catalytic reaction rates. Catalysis, the acceleration of a chemical reaction by a catalyst (substance), provided much of the driving force for the early development of surface science. As surface science continues its rapid development, this book illustrates how it is still driven by the challenges of catalysis and how both theory and scanning tunneling microscopy have forcefully emerged as essential tools. It is also evident how surface science continues to serve as the foundation of catalytic science. This is a compendium written by leading surface scientists presenting an incisive assessment of up-to-date theoretical and experimental results constituting the foundation of fundamental understanding of surface catalysis. This paperback.

Recent years have seen a tremendous progress in the microscopic theoretical treatment of surfaces and processes on surfaces. While some decades ago a phenomenological thermodynamic approach was dominant, a variety of surface properties can now be described from first principles, i.e. without invoking any empirical parameters. Consequently, the field of theoretical surface science is no longer limited to explanatory purposes only. It has reached such a level of sophistication and accuracy that reliable predictions for certain surface science problems have become possible. Hence both experiment and theory can contribute on an equal footing to the scientific progress. In this lecture, the theoretical concepts and computational tools necessary and relevant for theoretical surface science will be introduced. A microscopic approach towards the theoretical description of surface science will be presented. Based on the fundamental theoretical entity, the Hamiltonian, a hierarchy of theoretical methods will be introduced in order to describe surface structures and processes at different length and time scales. But even for the largest time and length scales, all necessary parameters will be derived from microscopic properties.

A comprehensive, authoritative introduction to the central issues in surface science. This volume takes a practical, experimental approach to modern surface science. Professor John B. Hudson promotes an intuitive understanding of the concepts of surface science by using physical examples to illustrate basic surface structures and phenomena. Accessible and easy to read throughout, Surface Science provides a solid foundation from which to develop a conceptual understanding of the field. Divided into four sections, Surface Science begins with descriptions of the structure, thermodynamics, and mobility of clean surfaces, then moves on to explore the interaction of gas molecules with solid surfaces. Next, Professor Hudson discusses the energetic particle interactions that are the basis for the majority of techniques developed to reveal the structure and chemistry of surfaces. The book concludes with a presentation of the background material involved in crystal nucleation and growth. The product of more than three decades of experience in introducing students to surface science, this book includes: * State-of-the-art surface analysis techniques * Examples of phenomena and structures from current and classical works * A comprehensive presentation that can be easily tailored to senior undergraduate and graduate courses in a variety of disciplines * Extensive references and course-proven end-of-chapter problems. Surface Science is an excellent textbook for advanced undergraduate and graduate students in engineering and the physical sciences who want a general overview of surface science. It also provides important background information for researchers just starting out in the field. JOHN B. HUDSON, PhD, is Professor of Materials Science in the Department of Materials Science and Engineering at Rensselaer Polytechnic Institute, Troy, New York.