The European Federation of Corrosion's Working Party on Surface Science and the Mechanisms of Corrosion and Protection (EFC WP6) has defined, as one of its objectives, the development of a reference material and reference guidelines for the application of electrochemical scanning tunnelling microscopy (EC-STM) in corrosion science. The use of EC-STM to study the relationship between surface structure and surface reactivity in situ on electrodes in contact with an electrolyte is of major importance in corrosion research. This report describes the reference material and procedural guidelines required to use this technique effectively. STM-users are instructed how to obtain high resolution data on a carefully prepared copper single-crystal surface. - Describes the reference material and procedural guidelines required to use this technique effectively - Discusses an area of major importance in corrosion research

Biocorrosion refers to corrosion influenced by bacteria adhering to surfaces in biofilms. Biocorrosion is a major problem in areas such as cooling systems and marine structures where biofilms can develop. This book summarises key recent research in this subject. Part one looks at theories of biocorrosion and measurement techniques. Part two discusses how bacteria and biofilms result in biocorrosion. The final part of the book includes case studies of biocorrosion in areas as diverse as buildings, fuels, marine environments and cooling systems. - Provides a detailed overview of biocorrosion and the different scientific and/or industrial problems related to microbially induced corrosion - Introduces a variety of investigative techniques and methodologies that are employed in diagnosing and evaluating microbially induced corrosion - Includes case studies on: biodeterioration of building materials; biocorrosion issues associated with diesel and biofuels; marine biocorrosion; corrosion of open recirculating cooling water systems and cooling system components; the effect of H2S on steel corrosion

In the different disposal concepts for high-level nuclear waste, corrosion of the metallic barriers and in particular the overpack/container is a major issue. It is imperative for performance assessment to predict the lifetime of these containers. In the lifetime prediction of metallic barriers for the disposal of high level nuclear waste (HLW) or of spent fuel, the presence of (reduced) sulphur species is an issue of growing importance, as the sulphur species are involved in localised corrosion phenomena. The international workshop on Sulphur-Assisted Corrosion in Nuclear Waste Disposal Systems (SACNUC2008) aimed to provide an exchange of information on the influence of sulphur species on the corrosion of metallic barriers. This workshop was a co-organisation of the Belgian Nuclear Research Centre, SCK*CEN, and the Belgian Agency for the Management of Radioactive Waste and Enriched Fissile Materials, ONDRAF/NIRAS, under the auspices of the European Federation of Corrosion (EFC event N 311). The proceedings are divided into five chapters: Chapter 1 provides a general overview of the disposal concepts of nuclear waste and the role of corrosion. Chapter 2 explains the mechanism of sulphur-induced corrosion processes. This chapter also contains information from outside the nuclear disposal field in which sulphur is known to act as a detrimental factor (e.g. oil and gas industry). Chapter 3 addresses the role of microbial processes in sulphur-assisted corrosion. Chapter 4 covers the modelling of sulphide-assisted corrosion. Chapter 5 is devoted to a panel discussion aiming to identify open issues in the investigation of sulphur-assisted corrosion phenomena and how to incorporate these in robust lifetime prediction of metallic barriers.

Corrosion remains one of the key issues affecting the performance and availability of nuclear power plants. Therefore, reliable in-plant corrosion monitoring methods are essential both for the future operation of existing plants and to ensure the safety of future nuclear waste disposal systems. In two parts, this book was stimulated by a workshop organised by EFC Working Party 4 on Nuclear Corrosion and the European Cooperative Group on Corrosion Monitoring of Nuclear Materials (EGC-COMON). The first part deals mainly with research into the detection of stress corrosion crack initiation in nuclear power plant environments (essentially high temperature water at around 300 °C) by various methods, particularly the electrochemical noise technique but also including the electrochemical impedance, acoustic emission and direct current potential drop methods. The second part addresses the goal to develop in-situ techniques and includes examples of the application of electrochemical corrosion potential monitoring. This book will be of particular interest to scientists and engineers concerned with the mitigation of corrosion in nuclear systems.

Corrosion under insulation (CUI) refers to the external corrosion of piping and vessels that occurs underneath externally clad/jacketed insulation as a result of the penetration of water. By its very nature CUI tends to remain undetected until the insulation and cladding/jacketing is removed to allow inspection or when leaks occur. CUI is a common problem shared by the refining, petrochemical, power, industrial, onshore and offshore industries. The European Federation of Corrosion (EFC) Working Parties WP13 and WP15 have worked to provide guidelines on managing CUI together with a number of major European refining, petrochemical and offshore companies including BP, Chevron-Texaco, Conoco-Phillips, ENI, Exxon-Mobil, IFP, MOL, Scanraff, Statoil, Shell, Total and Borealis. The guidelines within this document are intended for use on all plants and installations that contain insulated vessels, piping and equipment. The guidelines cover a risk-based inspection methodology for CUI, inspection techniques (including non-destructive evaluation methods) and recommended best practice for mitigating CUI, including design of plant and equipment, coatings and the use of thermal spray techniques, types of insulation, cladding/jacketing materials and protection guards. The guidelines also include case studies. Guidelines cover inspection methodology for CUI, inspection techniques, including non-destructive evaluation methods and recommended best practice Case studies are included illustrating key points in the book

High-temperature corrosion is a major problem affecting sectors such as the power generation, aerospace and metal-working industries. This important book summarises a wide range of research on ways of dealing with this important problem. The first part of the book reviews ways of modifying alloys to improve high-temperature corrosion resistance. The second part discusses surface treatments such as pre-treatments and coatings. The third part of the book summarises research on testing for high-temperature corrosion resistance and the development of common testing standards. It also reviews research on the behaviour of alloys in a wide range of service conditions such as furnace and boiler environments. The final part of the book discusses ways of modelling high-temperature corrosion processes to improve material performance and service life.With its distinguished editors and team of contributors drawn from some of the leading centres of research in the field, Novel approaches to improving high-temperature corrosion resistance is a standard reference for all those studying and dealing with high-temperature corrosion. - Summarises a wide range of research on ways of dealing with high-temperature corrosion - Discusses ways of modelling high-temperature corrosion processes to improve material performance and service life - A standard reference for all those studying and dealing with high-temperature corrosion

This book focuses on developments during the first fifty years of existence of the European Federation of Corrosion, and describes the contributions made by its working parties.

There has long been a need for effective pre-treatment techniques to prevent corrosion of metallic surfaces. This important volume discusses key research on the development of pre-treatment techniques for a range of metals. Chapters review various coatings and preparation methods for aluminium and aluminium alloys such as silane films, sol-gel coatings and magnesium-rich primers. Further chapters discuss the pre-treatment methods for steel, copper and magnesium alloys. The book also assesses methods for monitoring the effectiveness of pre-treatments, covering dissolution-precipitation mechanisms and their electrochemical behaviour.Innovative pre-treatment techniques to prevent corrosion of metallic surfaces is a valuable reference for all those concerned with corrosion problems and the use of pre-treatment techniques in the coatings industry. - Reviews coating and preparation methods for alluminium alloys - An authoritative overview of pre-treatments for steel, copper, zinc and magnesium alloys

Given the widespread use of reinforced concrete in infrastructure, understanding the corrosion of this material is of major importance. As a result there has been a wealth of research into catalysts, inhibitors and effective means of monitoring the rate of corrosion. Corrosion of reinforcement in concrete: mechanisms, monitoring, inhibitors and rehabilitation techniques summarises some of the most significant research and its implications.The book begins by reviewing findings from various experiments designed to test the corrosion rate of metals induced by a range of factors. Later chapters discuss techniques for monitoring and testing for corrosion. The book concludes by assessing important methods of prevention, including corrosion inhibitors, protective coatings and electrochemical methods for protection, together with rehabilitation procedures for susceptible structures.Filled with practical examples and written by a distinguished team of international contributors, Corrosion of reinforcement in concrete: mechanisms, monitoring, inhibitors and rehabilitation techniques is an essential reference for civil engineers using reinforced concrete. - Summarises research into catalysts, inhibitors and effective means of monitoring the rate of corrosion - Concludes by assessing important methods of prevention

Engineers with an interest in the marine environment can take advantage of many years of accumulated corrosion experience in a quick and concise manner with this publication. It covers the corrosion behavior in sea water of steel, stainless steel and cast iron as well as alloys of copper, aluminum, nickel and titanium. Applications, commonly-used alloy compositions and mechanical properties are also covered for each alloy system, plus a special section is devoted to galvanic corrosion and its avoidance.