It has been long recognized that continuous-wave (CW) chemical lasers represent an extremely complex interaction between fluid mechanics, chemical kinetics, and optical physics. The chemical oxygen-iodine laser presents additional problems in that the energy storage medium, singlet oxygen, is generated by a liquid-gas phase reaction. The kinetics of chemical oxygen-iodine lasers can be divided into five categories: 1) the chemistry of singlet oxygen generators, 2) the chemistry of COIL in the presence of water aerosols, 3) transport of singlet oxygen in the absence of iodine, 4) the dissociation of molecular iodine by excited oxygen, and 5) the kinetics of iodine atoms and excited oxygen. Only the last three kinetics topics are covered in this review. This report presents the Air Force Weapons Laboratory Standard Chemical Oxygen-Iodine Laser Kinetics Package. A complete reaction scheme including recommended rate coefficients for modeling the gas phase kinetics of chemical oxygen-iodine lasers (COIL) was established to provide a common basis for the research and development of COIL devices. A review of the experimental kinetic data base from which the model was derived is also presented. However, the fully coupled, reactive mixing and optical physics problems inherent in supersonic chemical oxygen-iodine lasers are not addressed. (aw).

Lasers with a gaseous active medium offer high flexibility, wide tunability, and advantages in cost, beam quality, and power scalability. Gas lasers have tended to become overshadowed by the recent popularity and proliferation of semiconductor lasers. As a result of this shift in focus, details on modern developments in gas lasers are difficult to find. In addition, different types of gas lasers have unique properties that are not well-described in other references. Collecting expert contributions from authorities dealing with specific types of lasers, Gas Lasers examines the fundamentals, current research, and applications of this important class of laser. It is important to understand all types of lasers, from solid-state to gaseous, before making a decision for any application. This book fills in the gaps by discussing the definition and properties of gaseous media along with its fluid dynamics, electric excitation circuits, and optical resonators. From this foundation, the discussion launches into the basic physics, characteristics, applications, and current research efforts for specific types of gas lasers: CO lasers, CO2 lasers, HF/DF lasers, excimer lasers, iodine lasers, and metal vapor lasers. The final chapter discusses miscellaneous lasers not covered in the previous chapters. Collecting hard-to-find material into a single, convenient source, Gas Lasers offers an encyclopedic survey that helps you approach new applications with a more complete inventory of laser options.

As computing power increases, a growing number of macroscopic phenomena are modeled at the molecular level. Consequently, new requirements are generated for the understanding of molecular dynamics in exotic conditions. This book illustrates the importance of detailed chemical dynamics and the role it plays in the phenomenology of a number of extreme environments. Each chapter addresses one or more extreme environments, outlines the associated chemical mechanisms of relevance, and then covers the leading edge science that elucidates the chemical coupling. The chapters exhibit a balance between theory and experiment, gas phase, solid state, and surface dynamics, and geophysical and technical environments. Sample Chapter(s). Chapter 1.1: Introduction (203 KB). Chapter 1.2: Chemistry at High Temperatures and Pressures (99 KB). Chapter 1.3: High Temperature Chemistry in the Atmosphere (82 KB). Chapter 1.4: Low Temperature Chemistry (90 KB). Chapter 1.5: Conclusions (131 KB). Contents: Exploring Chemistry in Extreme Environments: A Driving Force for Innovation (M R Berman); Chemistry Under Extreme Conditions: Cluster Impact Activation (T Raz & R D Levine); Nonequilibrium Chemistry Modeling in Rarefied Hypersonic Flows (I D Boyd); Chemical Dynamics in Chemical Laser Media (M C Heaven); From Elementary Reactions to Complex Combustion Systems (C Schulz et al.); The Gas-Phase Chemical Dynamics Associated with Meteors (R A Dressler & E Murad); Dynamics of Hypervelocity Gas/Surface Collisions (D C Jacobs); Surface Chemistry in the Jovian Magnetosphere Radiation Environment (R E Johnson); Dynamics of Atomic Oxygen Induced Polymer Degradation in Low Earth Orbit (T K Minton & D J Garton); Atomic-Level Properties of Thermal Barrier Coatings: Characterization of MetalOCoCeramic Interface (A Christensen et al.); Molecular Dynamics Simulations of Detonations (C T White et al.). Readership: Scientists engaged in cross-disciplinary work and chemists studying multidisciplinary problems."

Semiannual, with semiannual and annual indexes. References to all scientific and technical literature coming from DOE, its laboratories, energy centers, and contractors. Includes all works deriving from DOE, other related government-sponsored information, and foreign nonnuclear information. Arranged under 39 categories, e.g., Biomedical sciences, basic studies; Biomedical sciences, applied studies; Health and safety; and Fusion energy. Entry gives bibliographical information and abstract. Corporate, author, subject, report number indexes.