The Chemistry of Electrode Processes discusses "electrodics" or the science dealing with the transfer of an electric charge between a solid and liquid phase. This book reviews the applications of electrodics, the history of electrochemistry, and the basic definitions and concepts of the galvanic cell. This text also deals with the rate expressions associated with the different types of electrode reaction mechanism including the passing of Faradaic current, the current-voltage curve, mass transport overpotential, and the influence of surface structure on electrode processes. This book describes the electrode-solution interphase at equilibrium, the properties of such interphase, and the ways it can influence electrode kinetics. Any electrode reaction involves several steps and can be influenced by diffusion, adsorption and other parameters. The techniques to study electrode reactions and the electrode-solution interphase consists of equilibrium measurements, steady state measurement, and transient measurement. This text also describes the significant and potential uses of electrodics in technology which need less expensive equipment compared to using spectrophotometric techniques. This book is suitable chemists, for advanced students in analytical chemistry, physics, thermodynamics, and related subjects.

This user friendly introduction highlights the importance of electrochemistry and its applications to the modern world and the future. In contrast to other texts currently available, it emphasises understanding and avoids using many pages of complex equations. It also describes the diverse applications of electrochemistry rather than focusing on analytical chemistry alone. Although the book follows a similar structure to the first edition, the earlier chapters have been extensively up-dated and the later chapters are entirely new. The text is supported by a large number of figures which illustrate key points. The book starts by describing the essential electrochemical techniques before moving on to cover experimental problems and applications. To reflect the present interest in fuel cells and the environment, these have become the focus of the final chapters. A useful appendix contains problems with fully worked answers to test the reader's understanding.

Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)

This book has been planned and written by Dr. Hine with his knowledge and experience in electrochemical science and engineering for over thirty years since he joined with me at Kyoto University in 1948. This book is unique and is useful for engineers as well as scientists who are going to work in any interdisciplinary field connected with elec trochemistry. Science is sure to clarify the truth of nature as well as bring prosperity and an improvement to the welfare of human beings. The origin of the word "science" is the same as of "conscience," which means the truth of our heart. When we consider a scientific and technological subject, first we classify it into the components and/or factors involved, and then we clarify them individually. Second, we combine them to grasp the whole meaning and feature of the subject under discussion. Computers may help us greatly, but how to establish the software that will be most desirable for our purposes is of great importance. We need to make these efforts ourselves, and not decorate with borrowed plumes. With this concept in mind, this book is attractive because the author describes the basic science in electrochemistry and practice, and discusses the electrochemical engineering applications as a combination of science and technology.

Fundamentals of Electrochemistry provides the basic outline of most topics of theoretical and applied electrochemistry for students not yet familiar with this field, as well as an outline of recent and advanced developments in electrochemistry for people who are already dealing with electrochemical problems. The content of this edition is arranged so that all basic information is contained in the first part of the book, which is now rewritten and simplified in order to make it more accessible and used as a textbook for undergraduate students. More advanced topics, of interest for postgraduate levels, come in the subsequent parts. This updated second edition focuses on experimental techniques, including a comprehensive chapter on physical methods for the investigation of electrode surfaces. New chapters deal with recent trends in electrochemistry, including nano- and micro-electrochemistry, solid-state electrochemistry, and electrocatalysis. In addition, the authors take into account the worldwide renewal of interest for the problem of fuel cells and include chapters on batteries, fuel cells, and double layer capacitors.

Electrochemisty at Metal and Semiconductor Electrodes covers the structure of the electrical double layer and charge transfer reactions across the electrode/electrolyte interface. The purpose of the book is to integrate modern electrochemistry and semiconductor physics, thereby, providing a quantitative basis for understanding electrochemistry at metal and semiconductor electrodes. Electrons and ions are the principal particles which play the main role in electrochemistry. This text, therefore, emphasizes the energy level concepts of electrons and ions rather than the phenomenological thermodynamic and kinetic concepts on which most of the classical electrochemistry texts are based. This rationalization of the phenomenological concepts in terms of the physics of semiconductors should enable readers to develop more atomistic and quantitative insights into processes that occur at electrodes. The book incorporates many traditional disciplines of science and engineering such as interfacial chemistry, biochemistry, enzyme chemistry, membrane chemistry, metallurgy, modification of solid interfaces, and materials' corrosion. The text is intended to serve as an introduction for the study of advanced electrochemistry at electrodes and is aimed towards graduates and senior undergraduates studying materials and interfacial chemistry or those beginning research work in the field of electrochemistry.

This book introduces the principles of electrochemistry with a special emphasis on materials science. This book is clearly organized around the main topic areas comprising electrolytes, electrodes, development of the potential differences in combining electrolytes with electrodes, the electrochemical double layer, mass transport, and charge transfer, making the subject matter more accessible.In the second part, several important areas for materials science are described in more detail. These chapters bridge the gap between the introductory textbooks and the more specialized literature. They feature the electrodeposition of metals and alloys, electrochemistry of oxides and semiconductors, intrinsically conducting polymers, and aspects of nanotechnology with an emphasis on the codeposition of nanoparticles.This book provides a good introduction into electrochemistry for the graduate student. For the research student as well as for the advanced reader there is sufficient information on the basic problems in special chapters. The book is suitable for students and researchers in chemistry, physics, engineering, as well as materials science.- Introduction into electrochemistry- Metal and alloy electrodeposition- Oxides and semiconductors, corrosion- Intrinsically conducting polymers- Codeposition of nanoparticles, multilayers

Using 372 references and 211 illustrations, this book underlines the fundamentals of electrochemistry essential to the understanding of laboratory experiments. It treats not only the fundamental concepts of electrode reactions, but also covers the methodology and practical application of the many versatile electrochemical techniques available. - Underlines the fundamentals of electrochemistry essential to the understanding of laboratory experiments - Treats the fundamental concepts of electrode reactions - Covers the methodology and practical application of the many versatile electrochemical techniques available

Offering a thorough explanation of electrode kinetics, this textbook emphasizes physical phenomena - rather than mathematical formalism - and elucidates the underlying principles of the different experimental techniques. Assuming an elementary knowledge of thermodynamics and chemical kinetics and minimal mathematical skills, coverage explores the arguments of two primary schools of thought: electrode kinetics and interfacial electrochemistry viewed as a branch of physical chemistry and from the perspective of analytical chemistry.

The critically acclaimed guide to the principles, techniques, and instruments of electroanalytical chemistry-now expanded and revised Joseph Wang, internationally renowned authority on electroanalytical techniques, thoroughly revises his acclaimed book to reflect the rapid growth the field has experienced in recent years. He substantially expands the theoretical discussion while providing comprehensive coverage of the latest advances through late 1999, introducing such exciting new topics as self-assembled monolayers, DNA biosensors, lab-on-a-chip, detection for capillary electrophoresis, single molecule detection, and sol-gel surface modification. Along with numerous references from the current literature and new worked-out examples, Analytical Electrochemistry, Second Edition offers clear, reader-friendly explanations of the fundamental principles of electrochemical processes as well as important insight into the potential of electroanalysis for problem solving in a wide range of fields, from clinical diagnostics to environmental science. Key topics include: The basics of electrode reactions and the structure of the interfacial region Tools for elucidating electrode reactions and high-resolution surface characterization An overview of finite-current controlled potential techniques Electrochemical instrumentation and electrode materials Principles of potentiometric measurements and ion-selective electrodes Chemical sensors, including biosensors, gas sensors, solid-state devices, and sensor arrays