Describes general mathematical modeling of viscoelastic materials as systems with fading memory. Discusses the interrelation between topics such as existence, uniqueness, and stability of initial boundary value problems, variational and extremum principles, and wave propagation. Demonstrates the deep connection between the properties of the solution to initial boundary value problems and the requirements of the general physical principles. Discusses special techniques and new methods, including Fourier and Laplace transforms, extremum principles via weight functions, and singular surfaces and discontinuity waves.

Viscoelasticity and Rheology covers the proceedings of a symposium by the same title, conducted by the Mathematics Research Center held at the University of Wisconsin-Madison on October 16-18, 1984. The contributions to the symposium are divided into four broad categories, namely, experimental results, constitutive theories, mathematical analysis, and computation. This 16-chapter work begins with experimental topics, including the motion of bubbles in viscoelastic fluids, wave propagation in viscoelastic solids, flows through contractions, and cold-drawing of polymers. The next chapters covering constitutive theories explore the molecular theories for polymer solutions and melts based on statistical mechanics, the use and limitations of approximate constitutive theories, a comparison of constitutive laws based on various molecular theories, network theories and some of their advantages in relation to experiments, and models for viscoplasticity. These topics are followed by discussions of the existence, regularity, and development of singularities, change of type, interface problems in viscoelasticity, existence for initial value problems and steady flows, and propagation and development of singularities. The remaining chapters deal with the numerical simulation of flow between eccentric cylinders, flow around spheres and bubbles, the hole pressure problem, and a review of computational problems related to various constitutive laws. This book will prove useful to chemical engineers, researchers, and students.

This graduate text on viscoelastic materials addresses design applications as diverse as earplugs, computer disks and medical diagnostics.

Using a newly developed three dimensional, time dependent finite volume code designed to compute non-Newtonian flows over a large range of Reynolds number (Re), we performed simulations of viscoelastic flow past a circular cylinder. Our goal was to elucidate elastic effects during transition to turbulence in a bluff body wake. Based on its ability to capture essential physical processes in turbulent drag reduction studies, the FENE-P rheological model was employed in the calculation, and the numerical method utilized was such that a large range of rheological parameters (polymer length L, dimensionless Weissenberg number (Wi), and polymer concentration (beta) in the FENE-P model) could be probed. Simulations were performed for Reynolds numbers ranging from Re = 100 to Re = 3900. Within this range, the Newtonian cylinder wake first undergoes a series of secondary instabilities, transitioning the wake structure from a two-dimensional, laminar vortex shedding state to one exhibiting three-dimensional motion. This transition is characterized first by the mode A instability, which develops in the region of primary vortex development at a Reynolds number of Re = 190. The mode B instability then follows at Re = 260, resulting from unstable perturbation growth in the braid region between primary vortices. At still higher Reynolds numbers, Re = O(1000), the separated shear layer immediately behind the cylinder begins to transition prior to primary vortex shedding. Through nonlinear simulations as well as a Floquet linear stability analysis, viscoelasticity was observed to stabilize both regimes of three-dimensional transition. Full nonlinear simulations revealed that for high enough polymer extensibility L at Re = 300, where mode B instability structures dominate for Newtonian flow, the wake could be reverted back to a state resembling two-dimensional, laminar vortex shedding. This was then confirmed using a Floquet stability analysis, showing significantly suppressed growth rates for both the mode A and mode B instabilities in the linear regime of their development. Mechanisms of this stabilization are presented. At Re = 3900, viscoelasticity again stabilizes the flow, though at this point through a suppression of the Kelvin-Helmoltz rollup instability present in the separated shear layer for Newtonian flows. Once a primary Karman vortex is allowed to form without the influence of a transitioned shear layer, the wake then reverts back to one resembling the mode B instabilities. Confirming this, a study was then performed at the same Reynolds number but allowing for an inhomogeneous polymer concentration throughout the flow field. By injecting polymer additives on the upstream side of the cylinder, it was found that stabilization of the shear layer and of the subsequent wake could be achieved without the presence of polymeric stresses in all downstream locations of the flow.

This book contains a wealth of useful information on current research on viscoelasticity. By covering a broad variety of rheology, non-Newtonian fluid mechanics and viscoelasticity-related topics, this book is addressed to a wide spectrum of academic and applied researchers and scientists but it could also prove useful to industry specialists. The subject areas include, theory, simulations, biological materials and food products among others.

The subject of stability problems for viscoelastic solids and elements of structures, with which this book is concerned, has been the focus of attention in the past three decades. This has been due to the wide inculcation of viscoelastic materials, especially polymers and plastics, in industry. Up-to-date studies in viscoelasticity are published partially in purely mathematical journals, partially in merely applied ones, and as a consequence, they remain unknown to many interested specialists. Stability in Viscoelasticity fills the gap between engineers and mathematicians and converges theoretical and applied directions of investigations.All chapters contain extensive bibliographies of both purely mathematical and engineering works on stability problems. The bibliography includes a number of works in Russian which are practically inaccessible to the Western reader.

The areas of suspension mechanics, stability and computational rheology have exploded in scope and substance in the last decade. The present book is one of the first of a comprehensive nature to treat these topics in detail. The aim of the authors has been to highlight the major discoveries and to present a number of them in sufficient breadth and depth so that the novice can learn from the examples chosen, and the expert can use them as a reference when necessary.The first two chapters, grouped under the category General Principles, deal with the kinematics of continuous media and the balance laws of mechanics, including the existence of the stress tensor and extensions of the laws of vector analysis to domains bounded by fractal curves or surfaces. The third and fourth chapters, under the heading Constitutive Modelling, present the tools necessary to formulate constitutive equations from the continuum or the microstructural approach. The last three chapters, under the caption Analytical and Numerical Techniques, contain most of the important results in the domain of the fluid mechanics of viscoelasticity, and form the core of the book.A number of topics of interest have not yet been developed to a theoretical level from which applications can be made in a routine manner. However, the authors have included these topics to make the reader aware of the state of affairs so that research into these matters can be carried out. For example, the sections which deal with domains bounded by fractal curves or surfaces show that the existence of a stress tensor in such regions is still open to question. Similarly, the constitutive modelling of suspensions, especially at high volume concentrations, with the corresponding particle migration from high to low shear regions is still very sketchy.

This book introduces numerous selected advanced topics in viscoelastic and viscoplastic materials. The book effectively blends theoretical, numerical, modeling and experimental aspects of viscoelastic and viscoplastic materials that are usually encountered in many research areas such as chemical, mechanical and petroleum engineering. The book consists of 14 chapters that can serve as an important reference for researchers and engineers working in the field of viscoelastic and viscoplastic materials.

This Brief provides an up-to-date overview of smart surfactants and describes a broad spectrum of triggers that induce the formation of wormlike micelles or reversibly tune the morphology of surfactant aggregates from wormlike micelles to another state, or vice versa. Combining the fields of chemistry, physics, polymer science, and nanotechnology, its primary focus is on the design, formulation, and processing of intelligent viscoelastic surfactant solutions, covering the scientific principles governing responsiveness to one or more particular triggers, down to the end-use-driven functions. The first chapter explains why and how surfactants self-assemble into viscoelastic wormlike micellar solutions reminiscent of polymer solutions, while the following chapters show how the response to a given trigger translates into macroscopic rheological changes, including temperature, light, pH, CO2, redox, hydrocarbon, etc. The last chapter demonstrates the applications of these viscoelastic assemblies in oil and gas production, drag reduction, biomaterials, cleaning processes, electrorheological and photorheological fluids. Comments and perspectives are provided at the end to conclude this Brief. This Brief is aimed at chemists, physicists, chemical engineers and nano-scientists who are involved in self-assemblies and applications of surfactants, as well as graduates in physical chemistry. Yujun Feng, Ph.D., is a professor at the State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, Sichuan Province, P. R. China. Zonglin Chu, Ph.D., is a post-doctoral fellow working at the Physical Chemistry Institute, University of Zürich, Switzerland. Cécile A. Dreiss, Ph.D., is a senior lecturer at the Institute of Pharmaceutical Science, King’s College London, UK.

This concise introduction to the concepts of viscoelasticity focuses on stress analysis. Three detailed sections present examples of stress-related problems, including sinusoidal oscillation problems, quasi-static problems, and dynamic problems. 1960 edition.