This book underscores the essential principles of photocatalysis and provides an update on its scientific foundations, research advances, and current opinions, and interpretations. It consists of an introduction to the concepts that form the backbone of photocatalysis, from the principles of solid-state chemistry and physics to the role of reactive oxidizing species. Having recognised the organic link with chemical kinetics, part of the book describes kinetic concepts as they apply to photocatalysis. The dependence of rate on the reaction conditions and parameters is detailed, the retrospective and prospective aspects of the mechanism of photocatalysis are highlighted, and the adsorption models, photocatalytic rate expressions, and kinetic disguises are examined. This book also discusses the structure, property, and activity relationship of prototypical semiconductor photocatalysts and reviews how to extend their spectral absorption to the visible region to enable the effective use of visible solar spectrum. Lastly, it presents strategies for deriving substantially improved photoactivity from semiconductor materials to support the latest applications and potential trends.

This critical volume examines the different methods used for the synthesis of a great number of photocatalysts, including TiO2, ZnO and other modified semiconductors, as well as characterization techniques used for determining the optical, structural and morphological properties of the semiconducting materials. Additionally, the authors discuss photoelectrochemical methods for determining the light activity of the photocatalytic semiconductors by means of measurement of properties such as band gap energy, flat band potential and kinetics of hole and electron transfer. Photocatalytic Semiconductors: Synthesis, Characterization and Environmental Applications provide an overview of the semiconductor materials from first- to third-generation photocatalysts and their applications in wastewater treatment and water disinfection. The book further presents economic and toxicological aspects in the production and application of photocatalytic materials.

Photocatalysis is a hot topic because it is an environmentally friendly approach toward the conversion of light energy into chemical energy at mild reaction environments. Also, it is well applied in several major areas such as water splitting, bacterial inactivation, and pollutants elimination, which is a possible solution to energy shortage and environmental issues. The fundamental knowledge and the frontier research progress in typical photocatalytic materials, such as TiO2-based and non-TiO2-based photocatalysts, are included in this book. Methods to improve the photocatalytic efficiency and to provide a hint for the rational design of the new photocatalysts are covered.

Focusing on the basic principles of semiconductor photocatalysis, this book also gives a brief introduction to photochemistry, photoelectrochemistry, and homogeneous photocatalysis. In addition, the author - one of the leading authorities in the field - presents important environmental and practical aspects. A valuable, one-stop source for all chemists, material scientists, and physicists working in this area, as well as novice researchers entering semiconductor photocatalysis.

Photocatalysis: Fundamental Processes and Applications, Volume 32 in the Interface Science and Technology Series, discusses the fundamental aspects of photocatalysis and its process and applications to the decontamination of wastewater, hydrogen production via water splitting, and photo reduction of carbon dioxide to hydrocarbon. The book discusses the fundamental aspects of all applications together with their proper mechanisms, thus providing essential information for deep research in the area of clean environment and green energy production. - Provides background on the fundamental and experimental processes of photocatalysis - Covers photocatalysis and its impact on creating a clean environment and energy sources - Applies photocatalysis to the decontamination of wastewater, hydrogen production via water splitting, and photo reduction of carbon dioxide to hydrocarbon - Edited by a world-leading researcher in interface science

Presenting the basic science of semiconductor photocatalysis together with the various practical applications, this textbook is ideal for graduate students. It covers fundamental principles and applicable techniques of light, solid state physics, electrochemistry, reaction kinetics, and materials processing. A solid understanding of semiconductor photoelectrochemistry is developed through discussing the basic properties of a representative photocatalytic material, TiO2; the basic science of the light absorption phenomenon and the application to the powder suspension useful for the photocatalytic research; and the electronic state of semiconductors. Following this, the textbook moves on to explore photoelectrochemistry; the mechanism and kinetic analysis of photocatalytic reactions; typical fabrication methods of common photocatalysts and the factors for improving photocatalytic activity; and evaluation methods of photocatalytic activity. The textbook concludes by looking at the future prospects of the applications of photocatalysis. This introductory textbook provides a foundation in photocatalysis to supplement graduate courses in catalysis, environmental science, materials science and chemical engineering.

This book "Concepts of Semiconductor Photocatalysis" contains recent research on the preparation, characterization, and potential applications of the semiconductor photocatalyst. This research is promising and has received a lot of interest in the last few decades. The book covers advanced topics on the optical, physical, structural, and electro-catalysis and photo-catalysis applications. Development of new and noble efficient technology is pointing researchers toward the safe, facile, non-toxic, eco-friendly route of synthesis-to-applications, which can be used for manufacture at a large scale. This book presents an overview of the current photocatalyst fundamental theory, substantial applications, and use of the research worldwide. It is an important book for research organizations, government research-centers, academic libraries, and R

Novel nanoscale materials are now an essential part of meeting the current and future needs for clean water, and are at the heart of the development of novel technologies to desalinate water. The unique properties of nanomaterials and their convergence with current treatment technologies present great opportunities to revolutionize water and wastewater treatment. Nanoscale Materials for Water Purification brings together sustainable solutions using novel nanomaterials to alleviate the physical effects of water scarcity. This book covers a wide range of nanomaterials, including noble metal nanoparticles, magnetic nanoparticles, dendrimers, bioactive nanoparticles, polysaccharidebased nanoparticles, nanocatalysts, and redox nanoparticles for water purification. Significant properties and characterization methods of nanomaterials such as surface morphology, mechanical properties, and adsorption capacities are also investigated - Explains how the unique properties of a range of nanomaterials makes them important water purification agents - Shows how the use of nanotechnology can help create cheaper, more reliable, less energy-intensive, more environmentally friendly water purification techniques - Includes case studies to show how nanotechnology has successfully been integrated into water purification system design

Nanostructured Photocatalysts: From Materials to Applications in Solar Fuels and Environmental Remediation addresses the different properties of nanomaterials-based heterogeneous photocatalysis. Heterogeneous nanostructured photocatalysis represents an interesting and viable technique to address issues of climate change and global energy supply. Sustainable hydrogen (H2) fuel production from water via semiconductor photocatalysis, driven by solar energy, is regarded as a viable and sustainable solution to address increasing energy and environmental issues. Similarly, photocatalytic reduction of CO2 with water for the production of hydrocarbons could also be a viable solution. Sections cover band gap tuning, high surface area, the short diffusion path of carriers, and more. - Introduces the utilization of nanostructured materials in heterogeneous photocatalysis for hydrogen fuel production via water splitting - Explains preparation techniques for different nanomaterials and hybrid nanocomposites, enabling improved sunlight absorption efficiency and enhanced charge separation - Assesses the challenges that need to be addressed before this technology can be practically implemented, particularly of identifying cost-effective nanophotocatalysts

This book comprises a detailed overview on the role of photocatalysts for environmental remediation, hydrogen production and carbon dioxide reduction. Effective ways to enhance the photocatalytic activity of the material via doping, hybrid material, laser light and nanocomposites have been discussed in this book. The book also further elaborates the role of metal nanoparticles, rare earth doping, sensitizers, surface oxygen vacancy, interface engineering and band gap engineering for enhancing the photocatalytic activity. An approach to recover the photocatalytic material via immobilization is also presented. This book brings to light much of the recent research in the development of such semiconductor photocatalytic systems. The book will thus be of relevance to researchers in the field of: material science, environmental science & technology, photocatalytic applications, newer methods of energy generation & conversion and industrial applications.