Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.

Oxidizing and Reducing Agents S. D. Burke University of Wisconsin at Madison, USA R. L. Danheiser Massachusetts Institute of Technology, Cambridge, USA Recognising the critical need for bringing a handy reference work that deals with the most popular reagents in synthesis to the laboratory of practising organic chemists, the Editors of the acclaimed Encyclopedia of Reagents for Organic Synthesis (EROS) have selected the most important and useful reagents employed in contemporary organic synthesis. Handbook of Reagents for Organic Synthesis: Oxidizing and Reducing Agents, provides the synthetic chemist with a convenient compendium of information concentrating on the most important and frequently employed reagents for the oxidation and reduction of organic compounds, extracted and updated from EROS. The inclusion of a bibliography of reviews and monographs, a compilation of Organic Syntheses procedures with tested experimental details and references to oxidizing and reducing agents will ensure that this handbook is both comprehensive and convenient.

Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more "green" chemical synthesis. Over recent years, modern investigations have clarified the mechanisms of important organic electrochemical reactions. Progress has also been made in controlling the reactivity of intermediates through either radical or ionic pathways. Now is the time to gather all the electrochemical work into a textbook.As an essential addition to the armory of synthetic organic chemists, electrochemical reactions give results not easily achieved by many other chemical routes. This book presents a logical development of reactions and mechanisms in organic electrochemistry at a level suited to research scientists and final year graduate students. It forms an excellent starting point from which synthetic organic chemists, in both academia and industry, can appreciate uses for electrochemical methods in their own work. The book is also a reference guide to the literature.

Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation–reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.

Around 30 years ago the transition metal chemistry received great impulses. In the focus have been reactions of nickel and cobalt and herein especially their carbonyls. Also industrial processes have been developed. When the technical oxidation of ethylene with palladium chloride had been discovered, and a great number oflaboratory reactions, many groups have turned towards this subject. Apart from two important industrial processes - acetaldehyde and vinylacetate from ethylene - a great number of conversions and catalytic reactions with palladium compounds have been researched. Their mechanisms have been cleared up and have con tributed to a better understanding of the complex chemistry of palladium. Last but not least these reactions have also served for more understanding of organic transition metal compounds and catalyses in general. Numerous conventional reactions appear today in a different light. The effects of co-

This book provides a comprehensive overview of innovative remediation techniques and strategies for soils contaminated by heavy metals or organic compounds (e.g. petroleum hydrocarbons, NAPLs and chlorinated organic compounds). It discusses various novel chemical remediation approaches (in-situ and ex-situ) used alone and in combination with physical and/or thermal treatment. Further, it addresses the recovery of NAPLs, reuse of leaching solutions, and in-situ chemical reduction and oxidation, and explores the chemical enhancement of physical NAPLs recovery from both practical and theoretical perspectives. Also presenting the state-of-the-art in waste-assisted bioremediation to improve soil quality and the remediation of petroleum hydrocarbons, the book is a valuable resource for students, researchers and R&D professionals in industry engaged in the treatment of contaminated soils.

This brilliantly innovative textbook constructs organic chemistry from the ground up. By focusing on the points of reactivities in organic molecules - showing why they are reactive, what kinds of moieties react at these points and how surroundings may alter the reactivity - this text allows students to approach more and more complex molecules with enhanced understanding.

Controlling the emission of volatile organic compounds (VOC) became a very prominent environmental issue with the passage of the 1990 Clean Air Act Amendments, and will continue to be an environmental priority through the next decade. No single technology has played as important a role in the control of VOC emissions as thermal oxidation. It has the ability to destroy VOCs in a one-step process that produces innocuous by-products. Design of Thermal Oxidation Systems for Volatile Organic Compounds provides all the information needed for developing a thermal oxidation design in a single reference. It covers design, operation, and maintenance as well as the principles behind the classification of volatile organic compounds as hazardous waste. The author explores the primary purpose of thermal oxidizers and discusses their limitations. The book provides: practical, complete, and concise thermal oxidizer design principles an outline of state-of-the-art design principles a practical rather than theoretical approach real industrial examples in each chapter With the new regulations that affect VOC emissions, engineers from such diverse fields as oil refining, chemical distillation and separation processes, and pharmaceutical industries will need to design and implement thermal oxidation systems. Design of Thermal Oxidation Systems for Volatile Organic Compounds provides a reference to the entire design process, from conceptualization to operation and maintenance.

Discusses structural and physiochemical effects of irradiation and presents techniques to model and monitor radiation events. Describes the use of radiation as a sterilization method in the biomedical, pharmaceutical, and food industries. Examines current topics in the stability and stabilization of polymers exposed to ionizing radiation. Reviews advances in the use of radiation with photosensitive metathesis polymers, chemical amplification, and dry-develop resist technology.