This technical reference covers information about modern nanocatalysts and their applications in organic syntheses, electrochemistry and nanotechnology. The objective of this book is to present a review of the development of nanocatalysts in the fields of organic synthesis and electroanalysis over the last few decades. It provides readers comprehensive, systematic and updated information about the relevant topics. The reader is introduced to nanocatalysts, with the following chapters delving into the different chemical reactions in which they are involved. The topics covered include: carbon-carbon coupling reactions, aryl and organic carbon hetero atom coupling reactions, oxidation-reduction reactions, photocatalysis, heterocyclic reactions and multicomponent catalysis. The concluding chapters cover applications of nanocatalysts in electrochemical synthesis and sensing. The thirteen chapters demonstrate the value of a variety of catalysts that are important in chemical engineering processes. Advanced Nanocatalysis for Organic Synthesis and Electroanalysis delivers a quick and accessible reference on advanced nanocatalysis for a broad range of readers which includes graduate, postgraduate and Ph. D. students of chemical engineering as well as faculty members, research and development (R&D) personnel working in the industrial chemistry sector.

This volume discusses the great potential of metal nanoparticle catalysts for complicated molecular synthesis and reviews the current progress of this field. The development of highly active and stable heterogeneous catalysts is a crucial subject in modern science. However, development of heterogeneous catalysts for fine chemical synthesis has lagged far behind those for bulk chemical process. In recent years metal nanoparticle catalysts have been of great interest in this area due to their unique activity, ease of heterogenization, and robustness. Therefore, metal nanoparticle catalysts are an excellent candidate for the above-mentioned active and robust heterogeneous catalysts and this book provides an overview of this area. The present volume summarizes recent progress on nanoparticle catalysis for various organic transformations from simple redox reactions to complex asymmetric C–C bond forming reactions and also presents seminal studies on new technologies. It comprehensively summarizes advances in metal nanoparticle catalysis across several aspects including reaction manners, mechanistic investigations and new synthetic methodologies to encourage the use of metal nanoparticle catalysts for future organic synthesis. This volume will be of interest to students, researchers and professionals focused on the next-generation of fine chemical synthesis.

C-H, C-O, C-C, and C-Heteroatom bond forming processes by using metal-ligand approaches for the synthesis of organic compounds of biological, pharmacological and organic nanotechnological utility are the key areas addressed in this book. Authored by a European team of leaders in the field, it brings together innovative approaches for a variety of catalysis reactions and processes frequently applied in organic synthesis into a handy reference work. It covers all major types of catalysis, including homogeneous, heterogeneous, and organocatalysis, as well as mechanistic and computational studies. Special attention is paid to the improvements in efficiency and sustainability of important catalytic processes, such as selective oxidations, hydrogenation, and cross-coupling reactions, and to their utilization in industry. The result is a valuable resource for advanced researchers in both academia and industry, as well as graduate students in organic chemistry aiming for chemo-, regio- or stereoselective synthesis of organic compounds by using novel catalytic systems.

This book demonstrates that solar energy, the most abundant and clean renewable energy, can be utilized to drive methane activation and conversion under mild conditions. The book reports that coupling solar energy and thermal energy can significantly enhance methane conversion at mild temperatures using plasmonic nanometal-based catalysts, with a substantial decrease in apparent activation energy of methane conversion. Furthermore, this book, for the first time, reports the direct photocatalytic methane oxidation into liquid oxygenates (methanol and formaldehyde) with only molecular oxygen in pure water at room temperature with high yield and selectivity over nanometals and semiconductors (zinc oxide and titanium dioxide). These findings are a big stride toward methane conversion and inspire researchers to develop strategies for efficient and selective conversion of methane to high-value-added chemicals under mild conditions.

Nanoparticles in Catalysis Discover an essential overview of recent advances and trends in nanoparticle catalysis Catalysis in the presence of metal nanoparticles is an important and rapidly developing research field at the frontier of homogeneous and heterogeneous catalysis. In Nanoparticles in Catalysis, accomplished chemists and authors Karine Philippot and Alain Roucoux deliver a comprehensive guide to the key aspects of nanoparticle catalysis, ranging from synthesis, activation methodology, characterization, and theoretical modeling, to application in important catalytic reactions, like hydrogen production and biomass conversion. The book offers readers a review of modern and efficient tools for the synthesis of nanoparticles in solution or onto supports. It emphasizes the application of metal nanoparticles in important catalytic reactions and includes chapters on activation methodology and supported nanoclusters. Written by an international team of leading voices in the field, Nanoparticles in Catalysis is an indispensable resource for researchers and professionals in academia and industry alike. Readers will also benefit from the inclusion of: A thorough introduction to New Trends in the Design of Metal Nanoparticles and Derived Nanomaterials for Catalysis An exploration of Dynamic Catalysis and the Interface Between Molecular and Heterogeneous Catalysts A practical discussion of Metal Nanoparticles in Water: A Relevant Toolbox for Green Catalysis Organometallic Metal Nanoparticles for Catalysis A concise treatment of the opportunities and challenges of CO2 Hydrogenation to Oxygenated Chemicals Over Supported Nanoparticle Catalysts Perfect for catalytic, organic, inorganic, and physical chemists, Nanoparticles in Catalysis will also earn a place in the libraries of chemists working with organometallics and materials scientists seeking a one-stop resource with expert knowledge on the synthesis and characterization of nanoparticle catalysis.

Edited and written by renowned experts in the field, this is the first book to reflect the state of the art of nanocatalysis in ionic liquids. Divided into two core areas, the first part of the book describes the different classes of metal nanoparticles as well as their synthesis in ionic liquids, while the second focuses on such emerging issues as the application of such systems to energy and biomass conversion.

New Materials for Catalytic Applications proposes the use of both new and existing materials for catalytic applications, such as zeolites, metal oxides, microporous and mesoporous materials, and monocrystals. In addition, metal-oxides are discussed from a new perspective, i.e. nano- and photocatalytic applications. The material presents these concepts with a new focus on strategies in synthesis, synthesis based on a rational design, the correlation between basic properties/potential applications, and new catalytic solutions for acid-base, redox, hydrogenation, photocatalytic reactions, etc. - Presents organometallic concepts for the synthesis of nanocatalysts - Provides a synthesis of new materials following the fluorolytic sol-gel concept - Covers electronic and photocatalytic properties via synthesis of nano-oxide materials - Details the nature of sites in MOFs generating catalytic properties immobilization of triflates in solid matrices for organic reactions

As a paradigm for the future, micro-scale technology seeks to fuse revolutionary concepts in science and engineering and then translate it into reality. Nanotechnology is an interdisciplinary field that aims to connect what is seen with the naked eye and what is unseen on the molecular level. The Handbook of Research on Diverse Applications of Nanotechnology in Biomedicine, Chemistry, and Engineering examines the strengths and future potential of micro-scale technologies in a variety of industries. Highlighting the benefits, shortcomings, and emerging perspectives in the application of nano-scale technologies, this book is a comprehensive reference source for synthetic chemists, engineers, graduate students, and researchers with an interest in the multidisciplinary applications, as well as the ongoing research in the field.

Nanoparticles in Green Organic Synthesis: Strategy towards Sustainability presents the fundamental and latest practical uses of metal nanoparticles (MNPs) in organic synthesis, as well as their promising multidimensional applications. The book examines the latest emerging research on MNP synthesis and their applications—from organic transformation to energy and the environment—allowing readers to critically analyze the role of different MNPs in seeking ideas for widespread application. The book covers the fundamentals while also providing a comprehensive account of MNPs and their modification for a variety of green platform-based derivatives, focusing on the multifunctional technological evolution. The book covers a wide range of applications in organic synthesis using a variety of transition-metal-based nanoparticles in both homo- and heterogeneous media. The text details the concept of catalyst design and recent developments in the preparation and characterization of nanomaterials, followed by several chapters on the design of catalysts for specific applications. This volume is a valuable resource for those working in green chemistry, sustainability, material science and engineering, nanotechnology, energy, and the environment. - Covers in depth the synthetic routes involved in nanoparticle synthesis in various organic transformations - Comprehensively describes the latest technology of MNPs - Illuminates key concepts with numerous visual elements such as illustrations or photographs of the featured nanoparticles, synthesis schemes, spider graphs of strengths and weaknesses of key preparations and synthesis, and flow charts and reaction mechanisms